Misplaced Pages

#458541

100-398: The tunnel is 1,765 metres (5,791 ft) long and has two tubes, one for each direction of travel and each accommodating two lanes of highway. The tunnels were opened for traffic on 30 October 2001. The rock which the tunnel is built through is frequently unstable. To compensate for this, the tunnel roof and walls were reinforced at places with bolts and concrete injections, however the tunnel

200-412: A bitumen binder, which is frequently used for road surfaces , and polymer concretes that use polymers as a binder. Concrete is distinct from mortar . Whereas concrete is itself a building material, mortar is a bonding agent that typically holds bricks , tiles and other masonry units together. Grout is another material associated with concrete and cement. It does not contain coarse aggregates and

300-554: A chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble. This allows setting in wet conditions or under water and further protects the hardened material from chemical attack. The chemical process for hydraulic cement was found by ancient Romans who used volcanic ash ( pozzolana ) with added lime (calcium oxide). Non-hydraulic cement (less common) does not set in wet conditions or under water. Rather, it sets as it dries and reacts with carbon dioxide in

400-558: A mortar made of sand and roughly burnt gypsum (CaSO 4 · 2H 2 O), which is plaster of Paris, which often contained calcium carbonate (CaCO 3 ), Lime (calcium oxide) was used on Crete and by the Ancient Greeks . There is evidence that the Minoans of Crete used crushed potsherds as an artificial pozzolan for hydraulic cement. Nobody knows who first discovered that a combination of hydrated non-hydraulic lime and

500-608: A work accident . The investigation uncovered serious shortcomings in the safety of tunnels throughout Vestfold, not only the Hanekleiv Tunnel. Several other tunnels near the Hanekleiv tunnel were deemed to be safety risks, and had to be closed for further investigations and securing. The Progress Party demanded that the director of the Norwegian Directorate of Public Roads , Olav Søfteland , resign as

600-433: A French structural and civil engineer . Concrete components or structures are compressed by tendon cables during, or after, their fabrication in order to strengthen them against tensile forces developing when put in service. Freyssinet patented the technique on 2 October 1928. Concrete is an artificial composite material , comprising a matrix of cementitious binder (typically Portland cement paste or asphalt ) and

700-452: A cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it, and makes it flow more freely. As stated by Abrams' law , a lower water-to-cement ratio yields a stronger, more durable concrete, whereas more water gives a freer-flowing concrete with a higher slump . The hydration of cement involves many concurrent reactions. The process involves polymerization ,

800-400: A concrete component—and become a part of the binder for the aggregate. Fly ash and slag can enhance some properties of concrete such as fresh properties and durability. Alternatively, other materials can also be used as a concrete binder: the most prevalent substitute is asphalt , which is used as the binder in asphalt concrete . Admixtures are added to modify the cure rate or properties of

900-434: A dispersed phase or "filler" of aggregate (typically a rocky material, loose stones, and sand). The binder "glues" the filler together to form a synthetic conglomerate . Many types of concrete are available, determined by the formulations of binders and the types of aggregate used to suit the application of the engineered material. These variables determine strength and density, as well as chemical and thermal resistance of

1000-432: A fine powder. This product, made into a mortar with sand, set in 5–15 minutes. The success of "Roman cement" led other manufacturers to develop rival products by burning artificial hydraulic lime cements of clay and chalk . Roman cement quickly became popular but was largely replaced by Portland cement in the 1850s. Apparently unaware of Smeaton's work, the same principle was identified by Frenchman Louis Vicat in

1100-432: A form of hydraulic cement, is by far the most common type of cement in general use around the world. This cement is made by heating limestone (calcium carbonate) with other materials (such as clay ) to 1,450 °C (2,640 °F) in a kiln , in a process known as calcination that liberates a molecule of carbon dioxide from the calcium carbonate to form calcium oxide , or quicklime, which then chemically combines with

SECTION 10

#1732793067459

1200-452: A greater degree of fracture resistance even in seismically active environments. Roman concrete is significantly more resistant to erosion by seawater than modern concrete; it used pyroclastic materials which react with seawater to form Al- tobermorite crystals over time. The use of hot mixing and the presence of lime clasts are thought to give the concrete a self-healing ability, where cracks that form become filled with calcite that prevents

1300-678: A half-century. Technologies of waste cementation have been developed and deployed at industrial scale in many countries. Cementitious wasteforms require a careful selection and design process adapted to each specific type of waste to satisfy the strict waste acceptance criteria for long-term storage and disposal. Modern development of hydraulic cement began with the start of the Industrial Revolution (around 1800), driven by three main needs: Modern cements are often Portland cement or Portland cement blends, but other cement blends are used in some industrial settings. Portland cement,

1400-559: A key event in the history of architecture termed the Roman architectural revolution , freed Roman construction from the restrictions of stone and brick materials. It enabled revolutionary new designs in terms of both structural complexity and dimension. The Colosseum in Rome was built largely of concrete, and the Pantheon has the world's largest unreinforced concrete dome. Concrete, as

1500-415: A large aggregate that is too large for the size of the formwork, or which has too few smaller aggregate grades to serve to fill the gaps between the larger grades, or using too little or too much sand for the same reason, or using too little water, or too much cement, or even using jagged crushed stone instead of smoother round aggregate such as pebbles. Any combination of these factors and others may result in

1600-461: A large type of industrial facility called a concrete plant , or often a batch plant. The usual method of placement is casting in formwork , which holds the mix in shape until it has set enough to hold its shape unaided. Concrete plants come in two main types, ready-mix plants and central mix plants. A ready-mix plant blends all of the solid ingredients, while a central mix does the same but adds water. A central-mix plant offers more precise control of

1700-787: A market for use in concrete. The use of concrete in construction grew rapidly from 1850 onward, and was soon the dominant use for cements. Thus Portland cement began its predominant role. Isaac Charles Johnson further refined the production of meso-Portland cement (middle stage of development) and claimed he was the real father of Portland cement. Setting time and "early strength" are important characteristics of cements. Hydraulic limes, "natural" cements, and "artificial" cements all rely on their belite (2 CaO · SiO 2 , abbreviated as C 2 S) content for strength development. Belite develops strength slowly. Because they were burned at temperatures below 1,250 °C (2,280 °F), they contained no alite (3 CaO · SiO 2 , abbreviated as C 3 S), which

1800-553: A mix which is too harsh, i.e., which does not flow or spread out smoothly, is difficult to get into the formwork, and which is difficult to surface finish. Hydraulic cement A cement is a binder , a chemical substance used for construction that sets , hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate ) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel , produces concrete . Concrete

1900-469: A mixture of calcium silicates ( alite , belite ), aluminates and ferrites —compounds, which will react with water. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay or shale (a source of silicon, aluminium and iron) and grinding this product (called clinker ) with a source of sulfate (most commonly gypsum ). Cement kilns are extremely large, complex, and inherently dusty industrial installations. Of

2000-413: A month for Rosendale cement made it unpopular for constructing highways and bridges, and many states and construction firms turned to Portland cement. Because of the switch to Portland cement, by the end of the 1920s only one of the 15 Rosendale cement companies had survived. But in the early 1930s, builders discovered that, while Portland cement set faster, it was not as durable, especially for highways—to

2100-405: A number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted. The size distribution of the aggregate determines how much binder is required. Aggregate with a very even size distribution has the biggest gaps whereas adding aggregate with smaller particles tends to fill these gaps. The binder must fill the gaps between the aggregate as well as paste

SECTION 20

#1732793067459

2200-695: A pozzolan produces a hydraulic mixture (see also: Pozzolanic reaction ), but such concrete was used by the Greeks, specifically the Ancient Macedonians , and three centuries later on a large scale by Roman engineers . There is... a kind of powder which from natural causes produces astonishing results. It is found in the neighborhood of Baiae and in the country belonging to the towns round about Mount Vesuvius . This substance when mixed with lime and rubble not only lends strength to buildings of other kinds but even when piers of it are constructed in

2300-595: A result. The cost of adequate reinforcement of the Vestfold E18 tunnels was estimated to be 200 million  kr , or about 33.2 million US dollars. The closure of the E18 highway for tunnel repairs during the summer of 2007 lead to major traffic jams. Proposals to mitigate the road troubles included providing more trains and cutting the train fares by 50% on the Vestfoldbanen railway to encourage people to avoid

2400-424: A semi-liquid slurry (paste) that can be shaped, typically by pouring it into a form. The concrete solidifies and hardens through a chemical process called hydration . The water reacts with the cement, which bonds the other components together, creating a robust, stone-like material. Other cementitious materials, such as fly ash and slag cement , are sometimes added—either pre-blended with the cement or directly as

2500-493: A simple, fast way of getting a basic idea of the properties of the finished concrete without having to perform testing in advance. Various governing bodies (such as British Standards ) define nominal mix ratios into a number of grades, usually ranging from lower compressive strength to higher compressive strength. The grades usually indicate the 28-day cure strength. Thorough mixing is essential to produce uniform, high-quality concrete. Separate paste mixing has shown that

2600-467: A small empire in the regions of southern Syria and northern Jordan from the 4th century BC. They discovered the advantages of hydraulic lime , with some self-cementing properties, by 700 BC. They built kilns to supply mortar for the construction of rubble masonry houses, concrete floors, and underground waterproof cisterns . They kept the cisterns secret as these enabled the Nabataeans to thrive in

2700-409: A variety of tooled processes performed. The hydration process is exothermic , which means ambient temperature plays a significant role in how long it takes concrete to set. Often, additives (such as pozzolans or superplasticizers ) are included in the mixture to improve the physical properties of the wet mix, delay or accelerate the curing time, or otherwise change the finished material. Most concrete

2800-741: A very advanced civilisation in El Tajin near Mexico City, in Mexico. A detailed study of the composition of the aggregate and binder show that the aggregate was pumice and the binder was a pozzolanic cement made with volcanic ash and lime. Any preservation of this knowledge in literature from the Middle Ages is unknown, but medieval masons and some military engineers actively used hydraulic cement in structures such as canals , fortresses, harbors , and shipbuilding facilities . A mixture of lime mortar and aggregate with brick or stone facing material

2900-422: Is hydraulic cement , which hardens by hydration of the clinker minerals when water is added. Hydraulic cements (such as Portland cement) are made of a mixture of silicates and oxides, the four main mineral phases of the clinker, abbreviated in the cement chemist notation , being: The silicates are responsible for the cement's mechanical properties — the tricalcium aluminate and brownmillerite are essential for

3000-512: Is pozzolanic , so that ultimate strength is maintained. Because fly ash addition allows a lower concrete water content, early strength can also be maintained. Where good quality cheap fly ash is available, this can be an economic alternative to ordinary Portland cement. Portland pozzolan cement includes fly ash cement, since fly ash is a pozzolan , but also includes cements made from other natural or artificial pozzolans. In countries where volcanic ashes are available (e.g., Italy, Chile, Mexico,

3100-520: Is a major emitter of global carbon dioxide emissions . The lime reacts with silicon dioxide to produce dicalcium silicate and tricalcium silicate. The lime also reacts with aluminium oxide to form tricalcium aluminate. In the last step, calcium oxide, aluminium oxide, and ferric oxide react together to form brownmillerite. A less common form of cement is non-hydraulic cement , such as slaked lime ( calcium oxide mixed with water), which hardens by carbonation in contact with carbon dioxide , which

Hanekleiv Tunnel - Misplaced Pages Continue

3200-573: Is about 4.4 billion tonnes per year (2021, estimation), of which about half is made in China, followed by India and Vietnam. The cement production process is responsible for nearly 8% (2018) of global CO 2 emissions, which includes heating raw materials in a cement kiln by fuel combustion and release of CO 2 stored in the calcium carbonate (calcination process). Its hydrated products, such as concrete, gradually reabsorb atmospheric CO 2 (carbonation process), compensating for approximately 30% of

3300-417: Is completely evaporated (this process is technically called setting ), the carbonation starts: This reaction is slow, because the partial pressure of carbon dioxide in the air is low (~ 0.4 millibar). The carbonation reaction requires that the dry cement be exposed to air, so the slaked lime is a non-hydraulic cement and cannot be used under water. This process is called the lime cycle . Perhaps

3400-566: Is constantly fed into a rotary kiln, it allowed a continuous manufacturing process to replace lower capacity batch production processes. Calcium aluminate cements were patented in 1908 in France by Jules Bied for better resistance to sulfates. Also in 1908, Thomas Edison experimented with pre-cast concrete in houses in Union, N.J. In the US, after World War One, the long curing time of at least

3500-473: Is flat and had been covered with cement". "The floors were cement, in some places hard, but, by long exposure, broken, and now crumbling under the feet." "But throughout the wall was solid, and consisting of large stones imbedded in mortar, almost as hard as rock." Small-scale production of concrete-like materials was pioneered by the Nabatean traders who occupied and controlled a series of oases and developed

3600-426: Is mixed with dry Portland cement and water , the mixture forms a fluid slurry that is easily poured and molded into shape. The cement reacts with the water through a process called concrete hydration that hardens it over several hours to form a hard matrix that binds the materials together into a durable stone-like material that has many uses. This time allows concrete to not only be cast in forms, but also to have

3700-674: Is more usually added to Portland cement at the concrete mixer. Masonry cements are used for preparing bricklaying mortars and stuccos , and must not be used in concrete. They are usually complex proprietary formulations containing Portland clinker and a number of other ingredients that may include limestone, hydrated lime, air entrainers, retarders, waterproofers, and coloring agents. They are formulated to yield workable mortars that allow rapid and consistent masonry work. Subtle variations of masonry cement in North America are plastic cements and stucco cements. These are designed to produce

3800-566: Is poured with reinforcing materials (such as steel rebar ) embedded to provide tensile strength , yielding reinforced concrete . In the past, lime -based cement binders, such as lime putty, were often used but sometimes with other hydraulic cements , (water resistant) such as a calcium aluminate cement or with Portland cement to form Portland cement concrete (named for its visual resemblance to Portland stone ). Many other non-cementitious types of concrete exist with other methods of binding aggregate together, including asphalt concrete with

3900-403: Is present in the air (~ 412 vol. ppm ≃ 0.04 vol. %). First calcium oxide (lime) is produced from calcium carbonate ( limestone or chalk ) by calcination at temperatures above 825 °C (1,517 °F) for about 10 hours at atmospheric pressure : The calcium oxide is then spent (slaked) by mixing it with water to make slaked lime ( calcium hydroxide ): Once the excess water

4000-483: Is responsible for early strength in modern cements. The first cement to consistently contain alite was made by William Aspdin in the early 1840s: This was what we call today "modern" Portland cement. Because of the air of mystery with which William Aspdin surrounded his product, others ( e.g., Vicat and Johnson) have claimed precedence in this invention, but recent analysis of both his concrete and raw cement have shown that William Aspdin's product made at Northfleet , Kent

4100-474: Is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic , often lime - or calcium silicate -based, and are either hydraulic or less commonly non-hydraulic , depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster ). Hydraulic cements (e.g., Portland cement ) set and become adhesive through

Hanekleiv Tunnel - Misplaced Pages Continue

4200-559: Is then blended with aggregates and any remaining batch water and final mixing is completed in conventional concrete mixing equipment. Workability is the ability of a fresh (plastic) concrete mix to fill the form/mold properly with the desired work (pouring, pumping, spreading, tamping, vibration) and without reducing the concrete's quality. Workability depends on water content, aggregate (shape and size distribution), cementitious content and age (level of hydration ) and can be modified by adding chemical admixtures, like superplasticizer. Raising

4300-438: Is to make concrete. Portland cement may be grey or white . Portland cement blends are often available as inter-ground mixtures from cement producers, but similar formulations are often also mixed from the ground components at the concrete mixing plant. Portland blast-furnace slag cement , or blast furnace cement (ASTM C595 and EN 197-1 nomenclature respectively), contains up to 95% ground granulated blast furnace slag , with

4400-566: Is usually either pourable or thixotropic , and is used to fill gaps between masonry components or coarse aggregate which has already been put in place. Some methods of concrete manufacture and repair involve pumping grout into the gaps to make up a solid mass in situ . The word concrete comes from the Latin word " concretus " (meaning compact or condensed), the perfect passive participle of " concrescere ", from " con -" (together) and " crescere " (to grow). Concrete floors were found in

4500-399: Is usually reinforced with materials that are strong in tension, typically steel rebar . The mix design depends on the type of structure being built, how the concrete is mixed and delivered, and how it is placed to form the structure. Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar , and many plasters . It consists of

4600-478: The Isle of Portland , Dorset, England. However, Aspdins' cement was nothing like modern Portland cement but was a first step in its development, called a proto-Portland cement . Joseph Aspdins' son William Aspdin had left his father's company and in his cement manufacturing apparently accidentally produced calcium silicates in the 1840s, a middle step in the development of Portland cement. William Aspdin's innovation

4700-480: The construction industry , whose demand is ever growing with greater impacts on raw material extraction, waste generation and landfill practices. Concrete production is the process of mixing together the various ingredients—water, aggregate, cement, and any additives—to produce concrete. Concrete production is time-sensitive. Once the ingredients are mixed, workers must put the concrete in place before it hardens. In modern usage, most concrete production takes place in

4800-523: The Art to Prepare a Good Mortar published in St. Petersburg . A few years later in 1825, he published another book, which described various methods of making cement and concrete, and the benefits of cement in the construction of buildings and embankments. Portland cement , the most common type of cement in general use around the world as a basic ingredient of concrete, mortar , stucco , and non-speciality grout ,

4900-543: The New York Commissioner of Highways to construct an experimental section of highway near New Paltz, New York , using one sack of Rosendale to six sacks of Portland cement. It was a success, and for decades the Rosendale-Portland cement blend was used in concrete highway and concrete bridge construction. Cementitious materials have been used as a nuclear waste immobilizing matrix for more than

5000-463: The Philippines), these cements are often the most common form in use. The maximum replacement ratios are generally defined as for Portland-fly ash cement. Portland silica fume cement. Addition of silica fume can yield exceptionally high strengths, and cements containing 5–20% silica fume are occasionally produced, with 10% being the maximum allowed addition under EN 197–1. However, silica fume

5100-508: The Romans knew it, was a new and revolutionary material. Laid in the shape of arches , vaults and domes , it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick. Modern tests show that opus caementicium had as much compressive strength as modern Portland-cement concrete (c. 200 kg/cm  [20 MPa; 2,800 psi]). However, due to

SECTION 50

#1732793067459

5200-457: The absence of pozzolanic ash, the Romans used powdered brick or pottery as a substitute and they may have used crushed tiles for this purpose before discovering natural sources near Rome. The huge dome of the Pantheon in Rome and the massive Baths of Caracalla are examples of ancient structures made from these concretes, many of which still stand. The vast system of Roman aqueducts also made extensive use of hydraulic cement. Roman concrete

5300-643: The absence of reinforcement, its tensile strength was far lower than modern reinforced concrete , and its mode of application also differed: Modern structural concrete differs from Roman concrete in two important details. First, its mix consistency is fluid and homogeneous, allowing it to be poured into forms rather than requiring hand-layering together with the placement of aggregate, which, in Roman practice, often consisted of rubble . Second, integral reinforcing steel gives modern concrete assemblies great strength in tension, whereas Roman concrete could depend only upon

5400-630: The air. It is resistant to attack by chemicals after setting. The word "cement" can be traced back to the Ancient Roman term opus caementicium , used to describe masonry resembling modern concrete that was made from crushed rock with burnt lime as binder. The volcanic ash and pulverized brick supplements that were added to the burnt lime, to obtain a hydraulic binder , were later referred to as cementum , cimentum , cäment , and cement . In modern times, organic polymers are sometimes used as cements in concrete. World production of cement

5500-530: The available hydraulic limes, visiting their production sites, and noted that the "hydraulicity" of the lime was directly related to the clay content of the limestone used to make it. Smeaton was a civil engineer by profession, and took the idea no further. In the South Atlantic seaboard of the United States, tabby relying on the oyster-shell middens of earlier Native American populations

5600-526: The concrete at the time of batching/mixing. (See § Production below.) The common types of admixtures are as follows: Inorganic materials that have pozzolanic or latent hydraulic properties, these very fine-grained materials are added to the concrete mix to improve the properties of concrete (mineral admixtures), or as a replacement for Portland cement (blended cements). Products which incorporate limestone , fly ash , blast furnace slag , and other useful materials with pozzolanic properties into

5700-399: The concrete can cause the initially placed material to begin to set before the next batch is added on top. This creates a horizontal plane of weakness called a cold joint between the two batches. Once the mix is where it should be, the curing process must be controlled to ensure that the concrete attains the desired attributes. During concrete preparation, various technical details may affect

5800-461: The concrete quality. Central mix plants must be close to the work site where the concrete will be used, since hydration begins at the plant. A concrete plant consists of large hoppers for storage of various ingredients like cement, storage for bulk ingredients like aggregate and water, mechanisms for the addition of various additives and amendments, machinery to accurately weigh, move, and mix some or all of those ingredients, and facilities to dispense

5900-483: The crack from spreading. The widespread use of concrete in many Roman structures ensured that many survive to the present day. The Baths of Caracalla in Rome are just one example. Many Roman aqueducts and bridges, such as the magnificent Pont du Gard in southern France, have masonry cladding on a concrete core, as does the dome of the Pantheon . After the Roman Empire, the use of burned lime and pozzolana

6000-562: The desert. Some of these structures survive to this day. In the Ancient Egyptian and later Roman eras, builders discovered that adding volcanic ash to lime allowed the mix to set underwater. They discovered the pozzolanic reaction . The Romans used concrete extensively from 300 BC to AD 476. During the Roman Empire, Roman concrete (or opus caementicium ) was made from quicklime , pozzolana and an aggregate of pumice . Its widespread use in many Roman structures ,

6100-420: The development of new cements. Most famous was Parker's " Roman cement ". This was developed by James Parker in the 1780s, and finally patented in 1796. It was, in fact, nothing like material used by the Romans, but was a "natural cement" made by burning septaria – nodules that are found in certain clay deposits, and that contain both clay minerals and calcium carbonate . The burnt nodules were ground to

SECTION 60

#1732793067459

6200-607: The earliest known occurrence of cement is from twelve million years ago. A deposit of cement was formed after an occurrence of oil shale located adjacent to a bed of limestone burned by natural causes. These ancient deposits were investigated in the 1960s and 1970s. Cement, chemically speaking, is a product that includes lime as the primary binding ingredient, but is far from the first material used for cementation. The Babylonians and Assyrians used bitumen (asphalt or pitch ) to bind together burnt brick or alabaster slabs. In Ancient Egypt , stone blocks were cemented together with

6300-431: The finished product. Construction aggregates consist of large chunks of material in a concrete mix, generally a coarse gravel or crushed rocks such as limestone , or granite , along with finer materials such as sand . Cement paste, most commonly made of Portland cement , is the most prevalent kind of concrete binder. For cementitious binders, water is mixed with the dry cement powder and aggregate, which produces

6400-461: The first decade of the nineteenth century. Vicat went on to devise a method of combining chalk and clay into an intimate mixture, and, burning this, produced an "artificial cement" in 1817 considered the "principal forerunner" of Portland cement and "...Edgar Dobbs of Southwark patented a cement of this kind in 1811." In Russia, Egor Cheliev created a new binder by mixing lime and clay. His results were published in 1822 in his book A Treatise on

6500-402: The formation of the liquid phase during the sintering ( firing ) process of clinker at high temperature in the kiln . The chemistry of these reactions is not completely clear and is still the object of research. First, the limestone (calcium carbonate) is burned to remove its carbon, producing lime (calcium oxide) in what is known as a calcination reaction. This single chemical reaction

6600-404: The highway. Concrete Concrete is a composite material composed of aggregate bonded together with a fluid cement that cures to a solid over time. Concrete is the second-most-used substance in the world after water , and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminium combined. When aggregate

6700-426: The initial CO 2 emissions. Cement materials can be classified into two distinct categories: hydraulic cements and non-hydraulic cements according to their respective setting and hardening mechanisms. Hydraulic cement setting and hardening involves hydration reactions and therefore requires water, while non-hydraulic cements only react with a gas and can directly set under air. By far the most common type of cement

6800-554: The interlinking of the silicates and aluminate components as well as their bonding to sand and gravel particles to form a solid mass. One illustrative conversion is the hydration of tricalcium silicate: The hydration (curing) of cement is irreversible. Fine and coarse aggregates make up the bulk of a concrete mixture. Sand , natural gravel, and crushed stone are used mainly for this purpose. Recycled aggregates (from construction, demolition, and excavation waste) are increasingly used as partial replacements for natural aggregates, while

6900-404: The low pH (8.5–9.5) of its pore water) limited its use as reinforced concrete for building construction. The next development in the manufacture of Portland cement was the introduction of the rotary kiln . It produced a clinker mixture that was both stronger, because more alite (C 3 S) is formed at the higher temperature it achieved (1450 °C), and more homogeneous. Because raw material

7000-406: The making of mortar. In an English translation from 1397, it reads "lyme ... is a stone brent; by medlynge thereof with sonde and water sement is made". From the 14th century, the quality of mortar was again excellent, but only from the 17th century was pozzolana commonly added. The Canal du Midi was built using concrete in 1670. Perhaps the greatest step forward in the modern use of concrete

7100-531: The material. Mineral admixtures use recycled materials as concrete ingredients. Conspicuous materials include fly ash , a by-product of coal-fired power plants ; ground granulated blast furnace slag , a by-product of steelmaking ; and silica fume , a by-product of industrial electric arc furnaces . Structures employing Portland cement concrete usually include steel reinforcement because this type of concrete can be formulated with high compressive strength , but always has lower tensile strength . Therefore, it

7200-419: The mix, are being tested and used. These developments are ever growing in relevance to minimize the impacts caused by cement use, notorious for being one of the largest producers (at about 5 to 10%) of global greenhouse gas emissions . The use of alternative materials also is capable of lowering costs, improving concrete properties, and recycling wastes, the latest being relevant for circular economy aspects of

7300-478: The mixed concrete, often to a concrete mixer truck. Modern concrete is usually prepared as a viscous fluid, so that it may be poured into forms. The forms are containers that define the desired shape. Concrete formwork can be prepared in several ways, such as slip forming and steel plate construction . Alternatively, concrete can be mixed into dryer, non-fluid forms and used in factory settings to manufacture precast concrete products. Interruption in pouring

7400-441: The mixing of cement and water into a paste before combining these materials with aggregates can increase the compressive strength of the resulting concrete. The paste is generally mixed in a high-speed , shear-type mixer at a w/c (water to cement ratio) of 0.30 to 0.45 by mass. The cement paste premix may include admixtures such as accelerators or retarders, superplasticizers , pigments , or silica fume . The premixed paste

7500-465: The other materials in the mix to form calcium silicates and other cementitious compounds. The resulting hard substance, called 'clinker', is then ground with a small amount of gypsum ( CaSO 4 ·2H 2 O ) into a powder to make ordinary Portland cement , the most commonly used type of cement (often referred to as OPC). Portland cement is a basic ingredient of concrete , mortar , and most non-specialty grout . The most common use for Portland cement

7600-474: The point that some states stopped building highways and roads with cement. Bertrain H. Wait, an engineer whose company had helped construct the New York City's Catskill Aqueduct , was impressed with the durability of Rosendale cement, and came up with a blend of both Rosendale and Portland cements that had the good attributes of both. It was highly durable and had a much faster setting time. Wait convinced

7700-506: The properties or increase the performance envelope of the mix. Design-mix concrete can have very broad specifications that cannot be met with more basic nominal mixes, but the involvement of the engineer often increases the cost of the concrete mix. Concrete mixes are primarily divided into nominal mix, standard mix and design mix. Nominal mix ratios are given in volume of Cement : Sand : Aggregate {\displaystyle {\text{Cement : Sand : Aggregate}}} . Nominal mixes are

7800-468: The quality and nature of the product. Design mix ratios are decided by an engineer after analyzing the properties of the specific ingredients being used. Instead of using a 'nominal mix' of 1 part cement, 2 parts sand, and 4 parts aggregate (the second example from above), a civil engineer will custom-design a concrete mix to exactly meet the requirements of the site and conditions, setting material ratios and often designing an admixture package to fine-tune

7900-447: The rest Portland clinker and a little gypsum. All compositions produce high ultimate strength, but as slag content is increased, early strength is reduced, while sulfate resistance increases and heat evolution diminishes. Used as an economic alternative to Portland sulfate-resisting and low-heat cements. Portland-fly ash cement contains up to 40% fly ash under ASTM standards (ASTM C595), or 35% under EN standards (EN 197–1). The fly ash

8000-650: The royal palace of Tiryns , Greece, which dates roughly to 1400 to 1200 BC. Lime mortars were used in Greece, such as in Crete and Cyprus, in 800 BC. The Assyrian Jerwan Aqueduct (688 BC) made use of waterproof concrete . Concrete was used for construction in many ancient structures. Mayan concrete at the ruins of Uxmal (AD 850–925) is referenced in Incidents of Travel in the Yucatán by John L. Stephens . "The roof

8100-407: The sea, they set hard underwater. The Greeks used volcanic tuff from the island of Thera as their pozzolan and the Romans used crushed volcanic ash (activated aluminium silicates ) with lime. This mixture could set under water, increasing its resistance to corrosion like rust. The material was called pozzolana from the town of Pozzuoli , west of Naples where volcanic ash was extracted. In

8200-411: The strength of the concrete bonding to resist tension. The long-term durability of Roman concrete structures has been found to be due to its use of pyroclastic (volcanic) rock and ash, whereby the crystallization of strätlingite (a specific and complex calcium aluminosilicate hydrate) and the coalescence of this and similar calcium–aluminium-silicate–hydrate cementing binders helped give the concrete

8300-497: The surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers. Admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. Admixtures are defined as additions "made as the concrete mix is being prepared". The most common admixtures are retarders and accelerators. In normal use, admixture dosages are less than 5% by mass of cement and are added to

8400-535: The surfaces of the aggregate together, and is typically the most expensive component. Thus, variation in sizes of the aggregate reduces the cost of concrete. The aggregate is nearly always stronger than the binder, so its use does not negatively affect the strength of the concrete. Redistribution of aggregates after compaction often creates non-homogeneity due to the influence of vibration. This can lead to strength gradients. Decorative stones such as quartzite , small river stones or crushed glass are sometimes added to

8500-463: The tunnel for up to three hours after the initial collapse. The debris covered a 25-metre (82 ft) long stretch of road, and at places the pile was almost as high as the tunnel ceiling. The Southern Buskerud Police District was tasked with investigating the collapse. Neighbors close to the tunnel reported having noticed slight tremors and rumbles. Worries about the tunnel's safety had surfaced already during construction in 1997, when construction on

8600-415: The tunnel was halted so that additional security measures could be implemented. During repair work on 28 May 2007, two workers who were repairing and securing the tunnel sustained light injuries in a second incident. An unknown amount of concrete from the original securing of the tunnel fell over on the workers. Statens Vegvesen rejects that this was a new collapse of the tunnel, declaring the episode to be

8700-655: The various ingredients used to produce a given quantity of concrete, the cement is the most energetically expensive. Even complex and efficient kilns require 3.3 to 3.6 gigajoules of energy to produce a ton of clinker and then grind it into cement . Many kilns can be fueled with difficult-to-dispose-of wastes, the most common being used tires. The extremely high temperatures and long periods of time at those temperatures allows cement kilns to efficiently and completely burn even difficult-to-use fuels. The five major compounds of calcium silicates and aluminates comprising Portland cement range from 5 to 50% in weight. Combining water with

8800-439: The water content or adding chemical admixtures increases concrete workability. Excessive water leads to increased bleeding or segregation of aggregates (when the cement and aggregates start to separate), with the resulting concrete having reduced quality. Changes in gradation can also affect workability of the concrete, although a wide range of gradation can be used for various applications. An undesirable gradation can mean using

8900-524: Was Smeaton's Tower , built by British engineer John Smeaton in Devon , England, between 1756 and 1759. This third Eddystone Lighthouse pioneered the use of hydraulic lime in concrete, using pebbles and powdered brick as aggregate. A method for producing Portland cement was developed in England and patented by Joseph Aspdin in 1824. Aspdin chose the name for its similarity to Portland stone , which

9000-444: Was a true alite-based cement. However, Aspdin's methods were "rule-of-thumb": Vicat is responsible for establishing the chemical basis of these cements, and Johnson established the importance of sintering the mix in the kiln . In the US the first large-scale use of cement was Rosendale cement , a natural cement mined from a massive deposit of dolomite discovered in the early 19th century near Rosendale, New York . Rosendale cement

9100-479: Was counterintuitive for manufacturers of "artificial cements", because they required more lime in the mix (a problem for his father), a much higher kiln temperature (and therefore more fuel), and the resulting clinker was very hard and rapidly wore down the millstones , which were the only available grinding technology of the time. Manufacturing costs were therefore considerably higher, but the product set reasonably slowly and developed strength quickly, thus opening up

9200-418: Was developed in England in the mid 19th century, and usually originates from limestone . James Frost produced what he called "British cement" in a similar manner around the same time, but did not obtain a patent until 1822. In 1824, Joseph Aspdin patented a similar material, which he called Portland cement , because the render made from it was in color similar to the prestigious Portland stone quarried on

9300-505: Was extremely popular for the foundation of buildings ( e.g. , Statue of Liberty , Capitol Building , Brooklyn Bridge ) and lining water pipes. Sorel cement , or magnesia-based cement, was patented in 1867 by the Frenchman Stanislas Sorel . It was stronger than Portland cement but its poor water resistance (leaching) and corrosive properties ( pitting corrosion due to the presence of leachable chloride anions and

9400-629: Was formalized by French and British engineers in the 18th century. John Smeaton made an important contribution to the development of cements while planning the construction of the third Eddystone Lighthouse (1755–59) in the English Channel now known as Smeaton's Tower . He needed a hydraulic mortar that would set and develop some strength in the twelve-hour period between successive high tides . He performed experiments with combinations of different limestones and additives including trass and pozzolanas and did exhaustive market research on

9500-602: Was greatly reduced. Low kiln temperatures in the burning of lime, lack of pozzolana, and poor mixing all contributed to a decline in the quality of concrete and mortar. From the 11th century, the increased use of stone in church and castle construction led to an increased demand for mortar. Quality began to improve in the 12th century through better grinding and sieving. Medieval lime mortars and concretes were non-hydraulic and were used for binding masonry, "hearting" (binding rubble masonry cores) and foundations. Bartholomaeus Anglicus in his De proprietatibus rerum (1240) describes

9600-476: Was not equipped with concrete walls throughout the length of the tunnel. The E18 tunnels in Vestfold had about 17,000 vehicles pass through them each day in 2007. Late on Christmas Day 2006, about 200 cubic metres (7,100 cu ft) of rock fell from the ceiling of the southbound tunnel, onto the highway below. No cars were in the tunnel at the time, and there were no injuries. Debris continued to fall in

9700-572: Was quarried on the Isle of Portland in Dorset , England. His son William continued developments into the 1840s, earning him recognition for the development of "modern" Portland cement. Reinforced concrete was invented in 1849 by Joseph Monier . and the first reinforced concrete house was built by François Coignet in 1853. The first concrete reinforced bridge was designed and built by Joseph Monier in 1875. Prestressed concrete and post-tensioned concrete were pioneered by Eugène Freyssinet ,

9800-405: Was rarely used on the outside of buildings. The normal technique was to use brick facing material as the formwork for an infill of mortar mixed with an aggregate of broken pieces of stone, brick, potsherds , recycled chunks of concrete, or other building rubble. Lightweight concrete was designed and used for the construction of structural elements by the pre-Columbian builders who lived in

9900-407: Was used in house construction from the 1730s to the 1860s. In Britain particularly, good quality building stone became ever more expensive during a period of rapid growth, and it became a common practice to construct prestige buildings from the new industrial bricks, and to finish them with a stucco to imitate stone. Hydraulic limes were favored for this, but the need for a fast set time encouraged

10000-748: Was used in the Eastern Roman Empire as well as in the West into the Gothic period . The German Rhineland continued to use hydraulic mortar throughout the Middle Ages, having local pozzolana deposits called trass . Tabby is a building material made from oyster shell lime, sand, and whole oyster shells to form a concrete. The Spanish introduced it to the Americas in the sixteenth century. The technical knowledge for making hydraulic cement

#458541