An ampere-hour or amp-hour (symbol: A⋅h or A h ; often simplified as Ah ) is a unit of electric charge , having dimensions of electric current multiplied by time, equal to the charge transferred by a steady current of one ampere flowing for one hour, or 3,600 coulombs .
111-525: The commonly seen milliampere-hour (symbol: mA⋅h , mA h , often simplified as mAh ) is one-thousandth of an ampere-hour (3.6 coulombs). The ampere-hour is frequently used in measurements of electrochemical systems such as electroplating and for battery capacity where the commonly known nominal voltage is understood. A milliampere second (mA⋅s) is a unit of measurement used in X-ray imaging , diagnostic imaging, and radiation therapy . It
222-748: A general armistice ended the fighting. In the German Revolution (November 1918), Wilhelm II and the ruling princes abdicated their positions, and Germany was declared a federal republic . Germany's new leadership signed the Treaty of Versailles in 1919, accepting defeat by the Allies . Germans perceived the treaty as humiliating, which was seen by historians as influential in the rise of Adolf Hitler . Germany lost around 13% of its European territory and ceded all of its colonial possessions in Africa and
333-567: A great power with a strong economy ; it has the largest economy in Europe by nominal GDP . As a global power in industrial, scientific and technological sectors, it is both the world's third-largest exporter and importer . As a developed country , it offers social security , a universal health care system , and tuition-free university education . Germany is a member of the United Nations , Council of Europe , NATO and OECD , and
444-411: A solution ). When a chemical reaction is driven by an electrical potential difference , as in electrolysis , or if a potential difference results from a chemical reaction as in an electric battery or fuel cell , it is called an electrochemical reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via
555-460: A sustainable energy supply, the debt brake for balanced budgets, measures to increase the fertility rate ( pronatalism ), and high-tech strategies for the transition of the German economy, summarised as Industry 4.0 . During the 2015 European migrant crisis , the country took in over a million refugees and migrants. Germany is the seventh-largest country in Europe . It borders Denmark to
666-567: A temperate climate, ranging from oceanic in the north and west to continental in the east and southeast. Winters range from the cold in the Southern Alps to cool and are generally overcast with limited precipitation, while summers can vary from hot and dry to cool and rainy. The northern regions have prevailing westerly winds that bring in moist air from the North Sea, moderating the temperature and increasing precipitation. Conversely,
777-460: A NATO effort to provide security in that country after the ousting of the Taliban . In the 2005 elections , Angela Merkel became the first female chancellor. In 2009, the German government approved a €50 billion stimulus plan. Among the major German political projects of the early 21st century are the advancement of European integration , the energy transition ( Energiewende ) for
888-658: A centralised totalitarian state , withdrew from the League of Nations , and dramatically increased the country's rearmament . A government-sponsored programme for economic renewal focused on public works, the most famous of which was the Autobahn . In 1935, the regime withdrew from the Treaty of Versailles and introduced the Nuremberg Laws which targeted Jews and other minorities. Germany also reacquired control of
999-582: A founding member of the European Union, G7 and G20 . It has the third-highest number of UNESCO World Heritage Sites , 54 , of which 51 are cultural. The English word Germany derives from the Latin Germania , which came into use after Julius Caesar adopted it for the peoples east of the Rhine . The German term Deutschland , originally diutisciu land ('the German lands'),
1110-615: A framework laid out in the 1949 constitution known as the Grundgesetz (Basic Law). Amendments generally require a two-thirds majority of both the Bundestag and the Bundesrat ; the fundamental principles of the constitution, as expressed in the articles guaranteeing human dignity, the separation of powers, the federal structure, and the rule of law , are valid in perpetuity. The president , currently Frank-Walter Steinmeier ,
1221-493: A here-to-fore neglected innate, vital force, which he termed "animal electricity," which activated nerves and muscles spanned by metal probes. He believed that this new force was a form of electricity in addition to the "natural" form produced by lightning or by the electric eel and torpedo ray as well as the "artificial" form produced by friction (i.e., static electricity). Galvani's scientific colleagues generally accepted his views, but Alessandro Volta rejected
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#17327650131081332-680: A joint responsibility of the international community. It was the world's second-biggest aid donor in 2019 after the United States. Germany's military, the Bundeswehr (Federal Defence), is organised into the Heer (Army and special forces KSK ), Marine (Navy), Luftwaffe (Air Force) and Cyber- und Informationsraum (Cyber and Information Domain Service) branches. In absolute terms, German military spending in 2023
1443-420: A motor or power a light. A galvanic cell whose electrodes are zinc and copper submerged in zinc sulfate and copper sulfate , respectively, is known as a Daniell cell . The half reactions in a Daniell cell are as follows: In this example, the anode is the zinc metal which is oxidized (loses electrons) to form zinc ions in solution, and copper ions accept electrons from the copper metal electrode and
1554-414: A primary cell which solved the problem of polarization by introducing copper ions into the solution near the positive electrode and thus eliminating hydrogen gas generation. Later results revealed that at the other electrode, amalgamated zinc (i.e., zinc alloyed with mercury ) would produce a higher voltage. William Grove produced the first fuel cell in 1839. In 1846, Wilhelm Weber developed
1665-547: A provisional capital, to emphasise its stance that the two-state solution was temporary. West Germany was established as a federal parliamentary republic with a " social market economy ". Starting in 1948 West Germany became a major recipient of reconstruction aid under the American Marshall Plan . Konrad Adenauer was elected the first federal chancellor of Germany in 1949. The country enjoyed prolonged economic growth ( Wirtschaftswunder ) beginning in
1776-541: A series of experiments (see oil drop experiment ) to determine the electric charge carried by a single electron . In 1911, Harvey Fletcher, working with Millikan, was successful in measuring the charge on the electron, by replacing the water droplets used by Millikan, which quickly evaporated, with oil droplets. Within one day Fletcher measured the charge of an electron within several decimal places. In 1923, Johannes Nicolaus Brønsted and Martin Lowry published essentially
1887-424: A simple ampere-hour rating is often insufficient. For example, at 3.2 V for a lithium iron phosphate battery cell ( LiFePO 4 ), the perceived energy capacity of a small UPS product that has multiple DC outputs at different voltages but is simply listed with a single ampere-hour rating, e.g., 8800 mAh, would be exaggerated by a factor of 3.75 compared to that of a sealed 12-volt lead-acid battery where
1998-621: A specification of the watt-hour rating instead (or additionally). One ampere-hour is equal to (up to 4 significant figures): Electrochemistry Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change . These reactions involve electrons moving via an electronically conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating ) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in
2109-638: A state, the East German authorities eased border restrictions, but this actually led to an acceleration of the Wende reform process culminating in the Two Plus Four Treaty under which Germany regained full sovereignty. This permitted German reunification on 3 October 1990, with the accession of the five re-established states of the former GDR. The fall of the Wall in 1989 became a symbol of
2220-712: A symbol of the Cold War . Tensions between East and West Germany were reduced in the late 1960s by Chancellor Willy Brandt 's Ostpolitik . In 1989, Hungary decided to dismantle the Iron Curtain and open its border with Austria , causing the emigration of thousands of East Germans to West Germany via Hungary and Austria. This had devastating effects on the GDR, where regular mass demonstrations received increasing support. In an effort to help retain East Germany as
2331-419: Is a common oxidizing agent, but not the only one. Despite the name, an oxidation reaction does not necessarily need to involve oxygen. In fact, a fire can be fed by an oxidant other than oxygen; fluorine fires are often unquenchable, as fluorine is an even stronger oxidant (it has a weaker bond and higher electronegativity , and thus accepts electrons even better) than oxygen. For reactions involving oxygen,
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#17327650131082442-559: Is derived from deutsch ( cf. Dutch ), descended from Old High German diutisc 'of the people' (from diot or diota 'people'), originally used to distinguish the language of the common people from Latin and its Romance descendants . This in turn descends from Proto-Germanic * þiudiskaz 'of the people' (see also the Latinised form Theodiscus ), derived from * þeudō , descended from Proto-Indo-European * tewtéh₂- 'people', from which
2553-648: Is devoted to agriculture, while 30% is forested and 14% is covered by settlements or infrastructure. Plants and animals include those generally common to Central Europe. According to the National Forest Inventory, beeches , oaks , and other deciduous trees constitute just over 40% of the forests; roughly 60% are conifers , particularly spruce and pine . There are many species of ferns , flowers , fungi , and mosses . Wild animals include roe deer , wild boar , mouflon (a subspecies of wild sheep), fox , badger , hare , and small numbers of
2664-473: Is equivalent to a millicoulomb . This quantity is proportional to the total X-ray energy produced by a given X-ray tube operated at a particular voltage. The same total dose can be delivered in different time periods depending on the X-ray tube current. To help express energy , computation over charge values in ampere-hour requires precise data of voltage: in a battery system, for example, accurate calculation of
2775-608: Is largely autonomous in regard to its internal organisation. As of 2017 , Germany is divided into 401 districts ( Kreise ) at a municipal level; these consist of 294 rural districts and 107 urban districts . Germany has a civil law system based on Roman law with some references to Germanic law . The Bundesverfassungsgericht (Federal Constitutional Court) is the German Supreme Court responsible for constitutional matters, with power of judicial review . Germany's specialized supreme court system includes
2886-479: Is lost. Conversely, loss of oxygen or gain of hydrogen implies reduction. Electrochemical reactions in water are better analyzed by using the ion-electron method , where H , OH ion, H 2 O and electrons (to compensate the oxidation changes) are added to the cell's half-reactions for oxidation and reduction. In acidic medium, H ions and water are added to balance each half-reaction . For example, when manganese reacts with sodium bismuthate . Finally,
2997-653: Is the head of state and invested primarily with representative responsibilities and powers. He is elected by the Bundesversammlung (federal convention), an institution consisting of the members of the Bundestag and an equal number of state delegates. The second-highest official in the German order of precedence is the Bundestagspräsident ( President of the Bundestag ), who is elected by
3108-488: Is vested in the parliament consisting of the Bundestag (Federal Diet) and Bundesrat (Federal Council), which together form the legislative body. The Bundestag is elected through direct elections using the mixed-member proportional representation system. The members of the Bundesrat represent and are appointed by the governments of the sixteen federated states. The German political system operates under
3219-463: The Gründerzeit period following the unification of Germany, Bismarck's foreign policy as chancellor of Germany secured Germany's position as a great nation by forging alliances and avoiding war. However, under Wilhelm II , Germany took an imperialistic course, leading to friction with neighbouring countries. A dual alliance was created with the multinational realm of Austria-Hungary ;
3330-491: The Bundestag and responsible for overseeing the daily sessions of the body. The third-highest official and the head of government is the chancellor, who is appointed by the Bundespräsident after being elected by the party or coalition with the most seats in the Bundestag . The chancellor, currently Olaf Scholz , is the head of government and exercises executive power through his Cabinet . Since 1949,
3441-426: The "Father of Magnetism." He discovered various methods for producing and strengthening magnets. In 1663, the German physicist Otto von Guericke created the first electric generator, which produced static electricity by applying friction in the machine. The generator was made of a large sulfur ball cast inside a glass globe, mounted on a shaft. The ball was rotated by means of a crank and an electric spark
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3552-955: The Allies de jure abolished the German state and partitioned Berlin and Germany's remaining territory into four occupation zones. The western sectors, controlled by France, the United Kingdom , and the United States , were merged on 23 May 1949 to form the Federal Republic of Germany ( German : Bundesrepublik Deutschland ); on 7 October 1949, the Soviet Zone became the German Democratic Republic (GDR) ( German : Deutsche Demokratische Republik ; DDR). They were informally known as West Germany and East Germany. East Germany selected East Berlin as its capital, while West Germany chose Bonn as
3663-625: The Battle of Britain in the same year. In 1941, German troops invaded Yugoslavia , Greece and the Soviet Union . By 1942, Germany and its allies controlled most of continental Europe and North Africa , but following the Soviet victory at the Battle of Stalingrad , the Allied reconquest of North Africa and invasion of Italy in 1943, German forces suffered repeated military defeats. In 1944,
3774-798: The Battle of the Teutoburg Forest . The outcome of this battle dissuaded the Romans from their ambition of conquering Germania and is thus considered one of the most important events in European history . By 100 AD, when Tacitus wrote Germania , Germanic tribes had settled along the Rhine and the Danube (the Limes Germanicus ), occupying most of modern Germany. However, Baden-Württemberg , southern Bavaria , southern Hesse and
3885-597: The Berchtesgaden National Park . In addition, there are 17 Biosphere Reserves , and 105 nature parks . More than 400 zoos and animal parks operate in Germany. The Berlin Zoo , which opened in 1844, is the oldest in Germany, and claims the most comprehensive collection of species in the world. Germany is a federal , parliamentary , representative democratic republic. Federal legislative power
3996-706: The Black Death of 1348–1350. The Golden Bull issued in 1356 provided the constitutional structure of the Empire and codified the election of the emperor by seven prince-electors . Johannes Gutenberg introduced moveable-type printing to Europe, laying the basis for the democratization of knowledge . In 1517, Martin Luther incited the Protestant Reformation and his translation of the Bible began
4107-831: The Carolingian Empire in 800; it was divided in 843 . The eastern successor kingdom of East Francia stretched from the Rhine in the west to the Elbe river in the east and from the North Sea to the Alps. Subsequently, the Holy Roman Empire emerged from it. The Ottonian rulers (919–1024) consolidated several major duchies . In 996, Gregory V became the first German Pope, appointed by his cousin Otto III , whom he shortly after crowned Holy Roman Emperor. The Holy Roman Empire absorbed northern Italy and Burgundy under
4218-639: The Celtic , Iranian , Baltic , and Slavic tribes. Southern Germany was inhabited by Celtic-speaking peoples, who belonged to the wider La Tène culture . They were later assimilated by the Germanic conquerors. Under Augustus , the Roman Empire began to invade lands inhabited by the Germanic tribes, creating a short-lived Roman province of Germania between the Rhine and Elbe rivers. In 9 AD, three Roman legions were defeated by Arminius in
4329-653: The Czech Republic to the east, Austria and Switzerland to the south, and France , Luxembourg , Belgium , and the Netherlands to the west. The nation's capital and most populous city is Berlin and its main financial centre is Frankfurt ; the largest urban area is the Ruhr . Settlement in the territory of modern Germany began in the Lower Paleolithic , with various tribes inhabiting it from
4440-1186: The Eurasian beaver . The blue cornflower was once a German national symbol . The 16 national parks in Germany include the Jasmund National Park , the Vorpommern Lagoon Area National Park , the Müritz National Park , the Wadden Sea National Parks , the Harz National Park , the Hainich National Park , the Black Forest National Park , the Saxon Switzerland National Park , the Bavarian Forest National Park and
4551-660: The Fall of Communism , the dissolution of the Soviet Union , German reunification and Die Wende ("the turning point"). United Germany was considered the enlarged continuation of West Germany so it retained its memberships in international organisations. Based on the Berlin/Bonn Act (1994), Berlin again became the capital of Germany, while Bonn obtained the unique status of a Bundesstadt (federal city) retaining some federal ministries. The relocation of
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4662-569: The Federal Republic of Germany , is a country in Central Europe . It lies between the Baltic and North Sea to the north and the Alps to the south. Its sixteen constituent states have a total population of over 82 million in an area of 357,596 km (138,069 sq mi), making it the most populous member state of the European Union . It borders Denmark to the north, Poland and
4773-698: The Imperial Estates . The legal system initiated by a series of Imperial Reforms (approximately 1495–1555) provided for considerable local autonomy and a stronger Imperial Diet . The House of Habsburg held the imperial crown from 1438 until the death of Charles VI in 1740. Following the War of the Austrian Succession and the Treaty of Aix-la-Chapelle , Charles VI's daughter Maria Theresa ruled as empress consort when her husband, Francis I , became emperor. From 1740, dualism between
4884-455: The Latin for "glass" ), or positive, electricity; and "resinous," or negative, electricity. This was the two-fluid theory of electricity , which was to be opposed by Benjamin Franklin 's one-fluid theory later in the century. In 1785, Charles-Augustin de Coulomb developed the law of electrostatic attraction as an outgrowth of his attempt to investigate the law of electrical repulsions as stated by Joseph Priestley in England. In
4995-467: The Molotov–Ribbentrop Pact that divided Eastern Europe into German and Soviet spheres of influence. On 1 September 1939, Germany invaded Poland , beginning World War II in Europe ; Britain and France declared war on Germany on 3 September. In the spring of 1940, Germany conquered Denmark and Norway , the Netherlands , Belgium , Luxembourg , and France , forcing the French government to sign an armistice . The British repelled German air attacks in
5106-424: The Neolithic onward, chiefly the Celts . Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity . A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire . During the 16th century, northern German regions became the centre of the Protestant Reformation . Following the Napoleonic Wars and
5217-430: The Saarland in 1935, remilitarised the Rhineland in 1936, annexed Austria in 1938, annexed the Sudetenland in 1938 with the Munich Agreement , and in violation of the agreement occupied Czechoslovakia in March 1939. Kristallnacht (Night of Broken Glass) saw the burning of synagogues, the destruction of Jewish businesses, and mass arrests of Jewish people. In August 1939, Hitler's government negotiated
5328-423: The Salian emperors (1024–1125), although the emperors lost power through the Investiture controversy . Under the Hohenstaufen emperors (1138–1254), German princes encouraged German settlement to the south and east ( Ostsiedlung ). Members of the Hanseatic League , mostly north German towns, prospered in the expansion of trade. The population declined starting with the Great Famine in 1315, followed by
5439-543: The Swabian Jura , including 42,000-year-old flutes which are the oldest musical instruments ever found, the 40,000-year-old Lion Man , and the 41,000-year-old Venus of Hohle Fels . The Nebra sky disk , created during the European Bronze Age , has been attributed to a German site. The Germanic peoples are thought to have emerged from the Jastorf culture during the Nordic Bronze Age or early Iron Age . From southern Scandinavia and northern Germany , they expanded south, east, and west, coming into contact with
5550-450: The Triple Alliance of 1882 included Italy. Britain, France and Russia also concluded alliances to protect against Habsburg interference with Russian interests in the Balkans or German interference against France. At the Berlin Conference in 1884, Germany claimed several colonies including German East Africa , German South West Africa , Togoland , and Kamerun . Later, Germany further expanded its colonial empire to include holdings in
5661-412: The conductivity and electrolytic dissociation of organic acids . Walther Hermann Nernst developed the theory of the electromotive force of the voltaic cell in 1888. In 1889, he showed how the characteristics of the voltage produced could be used to calculate the free energy change in the chemical reaction producing the voltage. He constructed an equation, known as Nernst equation , which related
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#17327650131085772-776: The electrodynamometer . In 1868, Georges Leclanché patented a new cell which eventually became the forerunner to the world's first widely used battery, the zinc–carbon cell . Svante Arrhenius published his thesis in 1884 on Recherches sur la conductibilité galvanique des électrolytes (Investigations on the galvanic conductivity of electrolytes). From his results the author concluded that electrolytes , when dissolved in water, become to varying degrees split or dissociated into electrically opposite positive and negative ions. In 1886, Paul Héroult and Charles M. Hall developed an efficient method (the Hall–Héroult process ) to obtain aluminium using electrolysis of molten alumina. In 1894, Friedrich Ostwald concluded important studies of
5883-417: The inquisitorial Federal Court of Justice for civil and criminal cases, along with the Federal Labour Court , Federal Social Court , Federal Fiscal Court , and Federal Administrative Court for other matters. Criminal and private laws are codified on the national level in the Strafgesetzbuch and the Bürgerliches Gesetzbuch respectively. The German penal system seeks the rehabilitation of
5994-428: The revolutions of 1848 in the German states , raising the German question. King Frederick William IV of Prussia was offered the title of emperor, but with a loss of power; he rejected the crown and the proposed constitution, a temporary setback for the movement. King William I appointed Otto von Bismarck as the Minister President of Prussia in 1862. Bismarck successfully concluded the war with Denmark in 1864 ;
6105-411: The Austrian Habsburg monarchy and the Kingdom of Prussia dominated German history. In 1772, 1793, and 1795, Prussia and Austria, along with the Russian Empire , agreed to the Partitions of Poland . During the period of the French Revolutionary Wars , the Napoleonic era and the subsequent final meeting of the Imperial Diet , most of the Free Imperial Cities were annexed by dynastic territories;
6216-510: The Empire was replaced by the Weimar Republic . The Nazi rise to power in 1933 led to the establishment of a totalitarian dictatorship , World War II , and the Holocaust . In 1949, after the war and a period of Allied occupation , Germany was organized into two separate polities with limited sovereignty: the Federal Republic of Germany, or West Germany , and the German Democratic Republic, or East Germany . Berlin continued its de jure Four Power status . The Federal Republic of Germany
6327-437: The German Bundestag , though they have never been part of the federal government. In the 2017 German federal election , the right-wing populist Alternative for Germany gained enough votes to attain representation in the parliament for the first time. Germany is a federation and comprises sixteen constituent states which are collectively referred to as Länder . Each state ( Land ) has its own constitution, and
6438-428: The Holocaust , the German government persecuted minorities , including interning them in concentration and death camps across Europe. The regime systematically murdered 6 million Jews, at least 130,000 Romani , 275,000 disabled , thousands of Jehovah's Witnesses , thousands of homosexuals , and hundreds of thousands of political and religious opponents . Nazi policies in German-occupied countries resulted in
6549-507: The Pacific and China. The colonial government in South West Africa (present-day Namibia ), from 1904 to 1907, carried out the annihilation of the local Herero and Namaqua peoples as punishment for an uprising; this was the 20th century's first genocide . The assassination of Austria's crown prince on 28 June 1914 provided the pretext for Austria-Hungary to attack Serbia and trigger World War I . After four years of warfare, in which approximately two million German soldiers were killed,
6660-464: The Pacific. On 11 August 1919, President Friedrich Ebert signed the democratic Weimar Constitution . In the subsequent struggle for power, communists seized power in Bavaria , but conservative elements elsewhere attempted to overthrow the Republic in the Kapp Putsch . Street fighting in the major industrial centres, the occupation of the Ruhr by Belgian and French troops, and a period of hyperinflation followed. A debt restructuring plan and
6771-426: The Reichstag after a special election in 1932 and Hindenburg appointed Hitler as chancellor of Germany on 30 January 1933. After the Reichstag fire , a decree abrogated basic civil rights and the first Nazi concentration camp opened. On 23 March 1933, the Enabling Act gave Hitler unrestricted legislative power, overriding the constitution, and marked the beginning of Nazi Germany. His government established
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#17327650131086882-453: The Soviets pushed into Eastern Europe ; the Western allies landed in France and entered Germany despite a final German counteroffensive . Following Hitler's suicide during the Battle of Berlin , Germany signed the surrender document on 8 May 1945, ending World War II in Europe and Nazi Germany. Following the end of the war, surviving Nazi officials were tried for war crimes at the Nuremberg trials . In what later became known as
6993-423: The aforementioned electronically conducting circuit. This phenomenon is what distinguishes an electrochemical reaction from a conventional chemical reaction. Understanding of electrical matters began in the sixteenth century. During this century, the English scientist William Gilbert spent 17 years experimenting with magnetism and, to a lesser extent, electricity. For his work on magnets, Gilbert became known as
7104-617: The ampere-hour rating, e.g., 7 Ah, is based on the total output voltage rather than the internal cell voltage, so the 12-volt output of the example UPS product can actually deliver only about a third of the energy of the example battery, not a quarter more energy. But a direct replacement product for the example battery, in the same form factor and comparable output voltage and energy capacity but based on LiFePO 4 , might also be specified as 7 Ah, here based on output voltage rather than cell chemistry. For consumers without an engineering background, these difficulties would be avoided by
7215-458: The anode and cathode electrolytes in addition to the electron conduction path. The simplest ionic conduction path is to provide a liquid junction. To avoid mixing between the two electrolytes, the liquid junction can be provided through a porous plug that allows ion flow while minimizing electrolyte mixing. To further minimize mixing of the electrolytes, a salt bridge can be used which consists of an electrolyte saturated gel in an inverted U-tube. As
7326-546: The atoms, ions or molecules involved in an electrochemical reaction. Formally, oxidation state is the hypothetical charge that an atom would have if all bonds to atoms of different elements were 100% ionic . An atom or ion that gives up an electron to another atom or ion has its oxidation state increase, and the recipient of the negatively charged electron has its oxidation state decrease. For example, when atomic sodium reacts with atomic chlorine , sodium donates one electron and attains an oxidation state of +1. Chlorine accepts
7437-463: The balanced equation is obtained: An electrochemical cell is a device that produces an electric current from energy released by a spontaneous redox reaction. This kind of cell includes the Galvanic cell or Voltaic cell, named after Luigi Galvani and Alessandro Volta , both scientists who conducted experiments on chemical reactions and electric current during the late 18th century. Electrochemical cells have two conductive electrodes (the anode and
7548-463: The cathode). The anode is defined as the electrode where oxidation occurs and the cathode is the electrode where the reduction takes place. Electrodes can be made from any sufficiently conductive materials, such as metals, semiconductors, graphite, and even conductive polymers . In between these electrodes is the electrolyte , which contains ions that can freely move. The galvanic cell uses two different metal electrodes, each in an electrolyte where
7659-429: The communist-controlled Socialist Unity Party of Germany , supported by the Stasi , an immense secret service. While East German propaganda was based on the benefits of the GDR's social programmes and the alleged threat of a West German invasion, many of its citizens looked to the West for freedom and prosperity. The Berlin Wall , built in 1961, prevented East German citizens from escaping to West Germany, becoming
7770-405: The creation of a new currency in 1924 ushered in the Golden Twenties , an era of artistic innovation and liberal cultural life. The worldwide Great Depression hit Germany in 1929. Chancellor Heinrich Brüning 's government pursued a policy of fiscal austerity and deflation which caused unemployment of nearly 30% by 1932. The Nazi Party led by Adolf Hitler became the largest party in
7881-413: The creation of a more unified European political, economic and security apparatus. The governments of Germany and the United States are close political allies . Cultural ties and economic interests have crafted a bond between the two countries resulting in Atlanticism . After 1990, Germany and Russia worked together to establish a "strategic partnership" in which energy development became one of
7992-536: The criminal and the protection of the public. With the exceptions of petty crimes, tried by a single professional judge, and of serious political crimes, all charges are adjudicated by mixed tribunals where lay judges ( Schöffen ) and professional judges preside together. As of 2016, Germany's murder rate stood at a low of 1.18 murders per 100,000. In 2018, the overall crime rate fell to its lowest since 1992. Same-sex marriage has been legal in Germany since 2017, and LGBT rights are generally protected in
8103-461: The deaths of an estimated 2.7 million Poles , 1.3 million Ukrainians , 1 million Belarusians and 3.5 million Soviet prisoners of war . German military casualties have been estimated at 5.3 million, and around 900,000 German civilians died. Around 12 million ethnic Germans were expelled from across Eastern Europe, and Germany lost roughly one-quarter of its pre-war territory. After Nazi Germany surrendered,
8214-412: The discovery of thermoelectricity by Thomas Johann Seebeck . By the 1810s, William Hyde Wollaston made improvements to the galvanic cell . Sir Humphry Davy 's work with electrolysis led to the conclusion that the production of electricity in simple electrolytic cells resulted from chemical action and that chemical combination occurred between substances of opposite charge. This work led directly to
8325-674: The dissolution of the Holy Roman Empire in 1806, the German Confederation was formed in 1815. Formal unification of Germany into the modern nation-state commenced on 18 August 1866 with the North German Confederation Treaty establishing the Prussia -led North German Confederation , which became the German Empire in 1871. After World War I and the German Revolution of 1918–1919 ,
8436-641: The early 1950s. West Germany joined NATO in 1955 and was a founding member of the European Economic Community . On 1 January 1957, the Saarland joined West Germany. East Germany was an Eastern Bloc state under political and military control by the Soviet Union via occupation forces and the Warsaw Pact . Although East Germany claimed to be a democracy, political power was exercised solely by leading members ( Politbüro ) of
8547-712: The ecclesiastical territories were secularised and annexed. In 1806 the Imperium was dissolved; France, Russia, Prussia, and the Habsburgs (Austria) competed for hegemony in the German states during the Napoleonic Wars . Following the fall of Napoleon , the Congress of Vienna founded the German Confederation, a loose league of 39 sovereign states . The appointment of the emperor of Austria as
8658-504: The electrical potential between the juncture points of two dissimilar metals when there is a temperature difference between the joints. In 1827, the German scientist Georg Ohm expressed his law in this famous book "Die galvanische Kette, mathematisch bearbeitet" (The Galvanic Circuit Investigated Mathematically) in which he gave his complete theory of electricity. In 1832, Michael Faraday 's experiments led him to state his two laws of electrochemistry. In 1836, John Daniell invented
8769-434: The electron and its oxidation state is reduced to −1. The sign of the oxidation state (positive/negative) actually corresponds to the value of each ion's electronic charge. The attraction of the differently charged sodium and chlorine ions is the reason they then form an ionic bond . The loss of electrons from an atom or molecule is called oxidation, and the gain of electrons is reduction. This can be easily remembered through
8880-416: The electron is assigned to the atom with the largest electronegativity in determining the oxidation state. The atom or molecule which loses electrons is known as the reducing agent , or reductant , and the substance which accepts the electrons is called the oxidizing agent , or oxidant . Thus, the oxidizing agent is always being reduced in a reaction; the reducing agent is always being oxidized. Oxygen
8991-438: The energy delivered requires integration of the power delivered (product of instantaneous voltage and instantaneous current) over the discharge interval. Generally, the battery voltage varies during discharge; an average value or nominal value may be used to approximate the integration of power. When comparing the energy capacities of battery-based products that might have different internal cell chemistries or cell configurations,
9102-412: The gain of oxygen implies the oxidation of the atom or molecule to which the oxygen is added (and the oxygen is reduced). In organic compounds, such as butane or ethanol , the loss of hydrogen implies oxidation of the molecule from which it is lost (and the hydrogen is reduced). This follows because the hydrogen donates its electron in covalent bonds with non-metals but it takes the electron along when it
9213-680: The government was completed in 1999, and modernisation of the East German economy was scheduled to last until 2019. Since reunification, Germany has taken a more active role in the European Union , signing the Maastricht Treaty in 1992 and the Lisbon Treaty in 2007, and co-founding the eurozone . Germany sent a peacekeeping force to secure stability in the Balkans and sent German troops to Afghanistan as part of
9324-400: The half-reactions. By multiplying the stoichiometric coefficients so the numbers of electrons in both half reaction match: the balanced overall reaction is obtained: The same procedure as used in acidic medium can be applied, for example, to balance the complete combustion of propane : By multiplying the stoichiometric coefficients so the numbers of electrons in both half reaction match:
9435-477: The idea of an "animal electric fluid," replying that the frog's legs responded to differences in metal temper , composition, and bulk. Galvani refuted this by obtaining muscular action with two pieces of the same material. Nevertheless, Volta's experimentation led him to develop the first practical battery , which took advantage of the relatively high energy (weak bonding) of zinc and could deliver an electrical current for much longer than any other device known at
9546-402: The ion's oxidation state is reduced to 0. This forms a solid metal that electrodeposits on the cathode. The two electrodes must be electrically connected to each other, allowing for a flow of electrons that leave the metal of the anode and flow through this connection to the ions at the surface of the cathode. This flow of electrons is an electric current that can be used to do work, such as turn
9657-474: The ions deposit at the copper cathode as an electrodeposit. This cell forms a simple battery as it will spontaneously generate a flow of electric current from the anode to the cathode through the external connection. This reaction can be driven in reverse by applying a voltage, resulting in the deposition of zinc metal at the anode and formation of copper ions at the cathode. To provide a complete electric circuit, there must also be an ionic conduction path between
9768-527: The isolation of metallic sodium and potassium by electrolysis of their molten salts, and of the alkaline earth metals from theirs, in 1808. Hans Christian Ørsted 's discovery of the magnetic effect of electric currents in 1820 was immediately recognized as an epoch-making advance, although he left further work on electromagnetism to others. André-Marie Ampère quickly repeated Ørsted's experiment, and formulated them mathematically. In 1821, Estonian-German physicist Thomas Johann Seebeck demonstrated
9879-666: The late 18th century the Italian physician and anatomist Luigi Galvani marked the birth of electrochemistry by establishing a bridge between chemical reactions and electricity on his essay "De Viribus Electricitatis in Motu Musculari Commentarius" (Latin for Commentary on the Effect of Electricity on Muscular Motion) in 1791 where he proposed a "nerveo-electrical substance" on biological life forms. In his essay Galvani concluded that animal tissue contained
9990-477: The most important factors. As a result of the cooperation, Germany imported most of its natural gas and crude oil from Russia. Germany's development policy functions as a distinct sector within its foreign policy framework. It is formulated by the Federal Ministry for Economic Cooperation and Development and carried out by the implementing organisations. The German government sees development policy as
10101-660: The nation. Germany has a network of 227 diplomatic missions abroad and maintains relations with more than 190 countries. Germany is a member of NATO , the OECD , the G7 , the G20 , the World Bank and the IMF . It has played an influential role in the European Union since its inception and has maintained a strong alliance with France and all neighbouring countries since 1990. Germany promotes
10212-483: The negatively charged electrons flow in one direction around this circuit, the positively charged metal ions flow in the opposite direction in the electrolyte. A voltmeter is capable of measuring the change of electrical potential between the anode and the cathode. Germany – in Europe (light green & dark grey) – in the European Union (light green) Germany , officially
10323-550: The north, Poland and Czechia to the east, Austria and Switzerland to the south, and France , Luxembourg , Belgium , and the Netherlands to the west. Germany is also bordered by the North Sea and, at the north-northeast, by the Baltic Sea. German territory covers 357,596 km (138,069 sq mi). Elevation ranges from the mountains of the Alps (highest point: the Zugspitze at 2,963 metres or 9,721 feet) in
10434-613: The party system has been dominated by the Christian Democratic Union and the Social Democratic Party of Germany . So far every chancellor has been a member of one of these parties. However, the smaller liberal Free Democratic Party and the Alliance 90/The Greens have also been junior partners in coalition governments . Since 2007, the democratic socialist party The Left has been a staple in
10545-477: The permanent president reflected the Congress's rejection of Prussia 's rising influence. Disagreement within restoration politics partly led to the rise of liberal movements, followed by new measures of repression by Austrian statesman Klemens von Metternich . The Zollverein , a tariff union, furthered economic unity. In light of revolutionary movements in Europe , intellectuals and commoners started
10656-412: The positively charged ions are the oxidized form of the electrode metal. One electrode will undergo oxidation (the anode) and the other will undergo reduction (the cathode). The metal of the anode will oxidize, going from an oxidation state of 0 (in the solid form) to a positive oxidation state and become an ion. At the cathode, the metal ion in solution will accept one or more electrons from the cathode and
10767-419: The reaction is balanced by multiplying the stoichiometric coefficients so the numbers of electrons in both half reactions match and adding the resulting half reactions to give the balanced reaction: In basic medium, OH ions and water are added to balance each half-reaction. For example, in a reaction between potassium permanganate and sodium sulfite : Here, 'spectator ions' (K , Na ) were omitted from
10878-485: The same theory about how acids and bases behave, using an electrochemical basis. In 1937, Arne Tiselius developed the first sophisticated electrophoretic apparatus. Some years later, he was awarded the 1948 Nobel Prize for his work in protein electrophoresis . A year later, in 1949, the International Society of Electrochemistry (ISE) was founded. By the 1960s–1970s quantum electrochemistry
10989-607: The south to the shores of the North Sea ( Nordsee ) in the northwest and the Baltic Sea ( Ostsee ) in the northeast. The forested uplands of central Germany and the lowlands of northern Germany (lowest point: in the municipality Neuendorf-Sachsenbande , Wilstermarsch at 3.54 metres or 11.6 feet below sea level ) are traversed by such major rivers as the Rhine, Danube and Elbe. Significant natural resources include iron ore, coal, potash , timber, lignite , uranium , copper, natural gas, salt, and nickel. Most of Germany has
11100-974: The southeast regions have more extreme temperatures. From February 2019 – 2020, average monthly temperatures in Germany ranged from a low of 3.3 °C (37.9 °F) in January 2020 to a high of 19.8 °C (67.6 °F) in June 2019. Average monthly precipitation ranged from 30 litres per square metre in February and April 2019 to 125 litres per square metre in February 2020. Average monthly hours of sunshine ranged from 45 in November 2019 to 300 in June 2019. The territory of Germany can be divided into five terrestrial ecoregions : Atlantic mixed forests , Baltic mixed forests , Central European mixed forests , Western European broadleaf forests , and Alps conifer and mixed forests . As of 2016 , 51% of Germany's land area
11211-568: The standardization of the language; the 1555 Peace of Augsburg tolerated the "Evangelical" faith ( Lutheranism ), but also decreed that the faith of the prince was to be the faith of his subjects ( cuius regio, eius religio ). From the Cologne War through the Thirty Years' Wars (1618–1648), religious conflict devastated German lands and significantly reduced the population. The Peace of Westphalia ended religious warfare among
11322-762: The subsequent decisive Prussian victory in the Austro-Prussian War of 1866 enabled him to create the North German Confederation which excluded Austria . After the defeat of France in the Franco-Prussian War , the German princes proclaimed the founding of the German Empire in 1871. Prussia was the dominant constituent state of the new empire; the King of Prussia ruled as its Kaiser, and Berlin became its capital. In
11433-472: The time. In 1800, William Nicholson and Johann Wilhelm Ritter succeeded in decomposing water into hydrogen and oxygen by electrolysis using Volta's battery. Soon thereafter Ritter discovered the process of electroplating . He also observed that the amount of metal deposited and the amount of oxygen produced during an electrolytic process depended on the distance between the electrodes . By 1801, Ritter observed thermoelectric currents and anticipated
11544-503: The use of mnemonic devices. Two of the most popular are "OIL RIG" (Oxidation Is Loss, Reduction Is Gain) and "LEO" the lion says "GER" (Lose Electrons: Oxidation, Gain Electrons: Reduction). Oxidation and reduction always occur in a paired fashion such that one species is oxidized when another is reduced. For cases where electrons are shared (covalent bonds) between atoms with large differences in electronegativity ,
11655-446: The voltage of a cell to its properties. In 1898, Fritz Haber showed that definite reduction products can result from electrolytic processes if the potential at the cathode is kept constant. In 1898, he explained the reduction of nitrobenzene in stages at the cathode and this became the model for other similar reduction processes. In 1902, The Electrochemical Society (ECS) was founded. In 1909, Robert Andrews Millikan began
11766-637: The western Rhineland had been incorporated into Roman provinces . Around 260, Germanic peoples broke into Roman-controlled lands. After the invasion of the Huns in 375, and with the decline of Rome from 395, Germanic tribes moved farther southwest: the Franks established the Frankish Kingdom and pushed east to subjugate Saxony and Bavaria . Areas of what is today eastern Germany were inhabited by Western Slavic tribes. Charlemagne founded
11877-615: The word Teutons also originates. Pre-human ancestors, the Danuvius guggenmosi , who were present in Germany over 11 million years ago, are theorized to be among the earliest ones to walk on two legs. Ancient humans were present in Germany at least 600,000 years ago. The first non-modern human fossil (the Neanderthal ) was discovered in the Neander Valley . Similarly dated evidence of modern humans has been found in
11988-555: Was a founding member of the European Economic Community and the European Union , while the German Democratic Republic was a communist Eastern Bloc state and member of the Warsaw Pact . After the fall of the communist led-government in East Germany, German reunification saw the former East German states join the Federal Republic of Germany on 3 October 1990 . Germany has been described as
12099-441: Was developed by Revaz Dogonadze and his students. The term " redox " stands for reduction-oxidation . It refers to electrochemical processes involving electron transfer to or from a molecule or ion , changing its oxidation state . This reaction can occur through the application of an external voltage or through the release of chemical energy. Oxidation and reduction describe the change of oxidation state that takes place in
12210-484: Was produced when a pad was rubbed against the ball as it rotated. The globe could be removed and used as source for experiments with electricity. By the mid-18th century the French chemist Charles François de Cisternay du Fay had discovered two types of static electricity, and that like charges repel each other whilst unlike charges attract. Du Fay announced that electricity consisted of two fluids: "vitreous" (from
12321-495: Was the seventh-highest in the world . In response to the 2022 Russian invasion of Ukraine , Chancellor Olaf Scholz announced that German military expenditure would be increased past the NATO target of 2%, along with a one-time 2022 infusion of 100 billion euros, representing almost double the 53 billion euro military budget for 2021. In 2023, military spending according to NATO criteria amounted to $ 73.1 billion, or 1.64% of
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