Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite , but deficient in quartz , which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a granitoid . Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition .
84-423: The extrusive equivalent of syenite is trachyte . The feldspar component of syenite is predominantly alkaline in character (usually orthoclase ). Plagioclase feldspars may be present in small proportions, between 10% and 35% of the feldspar content. Such feldspars often are interleaved as perthitic components of the rock. When ferromagnesian minerals are present in syenite at all, they usually occur in
168-420: A cumulate process as it cools. This leaves a drastically reduced concentration of silica in the remainder of the melt. The segregation of the silica from the melt leaves it in a state that may favour syenite formation. Some syenites are also theorized to be the product of the fractional crystallization of basaltic magmas. Syenite is not a common rock. Regions where it occurs in significant quantities include
252-431: A nuclear reactor . Another fissile isotope, uranium-233 , can be produced from natural thorium and is studied for future industrial use in nuclear technology. Uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons; uranium-235, and to a lesser degree uranium-233, have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain
336-419: A cooling intrusion . Because episyenitization usually takes place in granitoid rock and usually involves alkaline metasomatism (addition of alkali metal oxides to the rock) the result is a rock that has the mineral composition of an igneous syenite. In addition to rare earth elements, episyenites may be important sources of uranium and other valuable metals. Notable occurrences of episyenite are found in
420-528: A description of this process of reactor control). As little as 15 lb (6.8 kg) of uranium-235 can be used to make an atomic bomb. The nuclear weapon detonated over Hiroshima , called Little Boy , relied on uranium fission. However, the first nuclear bomb (the Gadget used at Trinity ) and the bomb that was detonated over Nagasaki ( Fat Man ) were both plutonium bombs. Uranium metal has three allotropic forms: The major application of uranium in
504-479: A distribution of uranium oxidation species in various forms ranging from most oxidized to least oxidized. Particles with short residence times in a calciner will generally be less oxidized than those with long retention times or particles recovered in the stack scrubber. Uranium content is usually referenced to U 3 O 8 , which dates to the days of the Manhattan Project when U 3 O 8
588-512: A dome shape. Domes typically solidify to form the rich in silica extrusive rock obsidian and sometimes dacite domes form the extrusive rock dacite, like in the case of Mount St. Helens . Calderas are volcanic depressions formed after an erupted volcano collapses. Resurgent calderas can refill with an eruption of rhyolitic magma to form the extrusive rock rhyolite like the Yellowstone Caldera . Submarine volcanoes erupt on
672-566: A form of invisible light or rays emitted by uranium had exposed the plate. During World War I when the Central Powers suffered a shortage of molybdenum to make artillery gun barrels and high speed tool steels, they routinely used ferrouranium alloy as a substitute, as it presents many of the same physical characteristics as molybdenum. When this practice became known in 1916 the US government requested several prominent universities to research
756-483: A higher concentration of aluminum relative to alkali (predominantly K and Na) and earth-alkali (predominantly Ca) elements. Syenites are products of alkaline igneous activity, generally formed in thick continental crustal areas, or in Cordilleran subduction zones. The formation of syenites can be theorized to be from the melt of granitic or igneous protolith to a fairly low degree of partial melting . This
840-745: A higher incidence of cancer . An excess risk of lung cancer among Navajo uranium miners, for example, has been documented and linked to their occupation. The Radiation Exposure Compensation Act , a 1990 law in the US, required $ 100,000 in "compassion payments" to uranium miners diagnosed with cancer or other respiratory ailments. During the Cold War between the Soviet Union and the United States, huge stockpiles of uranium were amassed and tens of thousands of nuclear weapons were created using enriched uranium and plutonium made from uranium. After
924-448: A much more complicated and far more powerful type of fission/fusion bomb ( thermonuclear weapon ) was built, that uses a plutonium-based device to cause a mixture of tritium and deuterium to undergo nuclear fusion . Such bombs are jacketed in a non-fissile (unenriched) uranium case, and they derive more than half their power from the fission of this material by fast neutrons from the nuclear fusion process. The main use of uranium in
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#17327939907731008-459: A plutonium-based device (see Trinity test and " Fat Man ") whose plutonium was derived from uranium-238. Little Boy became the first nuclear weapon used in war when it was detonated over Hiroshima , Japan , on 6 August 1945. Exploding with a yield equivalent to 12,500 tonnes of TNT , the blast and thermal wave of the bomb destroyed nearly 50,000 buildings and killed about 75,000 people (see Atomic bombings of Hiroshima and Nagasaki ). Initially it
1092-405: A reaction by piling together 360 tonnes of graphite , 53 tonnes of uranium oxide , and 5.5 tonnes of uranium metal, most of which was supplied by Westinghouse Lamp Plant in a makeshift production process. Two types of atomic bomb were developed by the United States during World War II : a uranium-based device (codenamed " Little Boy ") whose fissile material was highly enriched uranium , and
1176-413: A shielding material. Due to its high density, this material is found in inertial guidance systems and in gyroscopic compasses . Depleted uranium is preferred over similarly dense metals due to its ability to be easily machined and cast as well as its relatively low cost. The main risk of exposure to depleted uranium is chemical poisoning by uranium oxide rather than radioactivity (uranium being only
1260-525: A shorter half-life and so is an extinct radionuclide , having long since decayed completely to Th. Further uranium-236 was produced by the decay of Pu , accounting for the observed higher-than-expected abundance of thorium and lower-than-expected abundance of uranium. While the natural abundance of uranium has been supplemented by the decay of extinct Pu (half-life 375,000 years) and Cm (half-life 16 million years), producing U and U respectively, this occurred to an almost negligible extent due to
1344-502: A sustained nuclear chain reaction . This generates the heat in nuclear power reactors and produces the fissile material for nuclear weapons. The primary civilian use for uranium harnesses the heat energy to produce electricity. Depleted uranium ( U) is used in kinetic energy penetrators and armor plating . The 1789 discovery of uranium in the mineral pitchblende is credited to Martin Heinrich Klaproth , who named
1428-412: A weak alpha emitter ). During the later stages of World War II , the entire Cold War , and to a lesser extent afterwards, uranium-235 has been used as the fissile explosive material to produce nuclear weapons. Initially, two major types of fission bombs were built: a relatively simple device that uses uranium-235 and a more complicated mechanism that uses plutonium-239 derived from uranium-238. Later,
1512-535: A world total production of 48,332 tonnes. Most uranium was produced not by conventional underground mining of ores (29% of production), but by in situ leaching (66%). In the late 1960s, UN geologists discovered major uranium deposits and other rare mineral reserves in Somalia . The find was the largest of its kind, with industry experts estimating the deposits at over 25% of the world's then known uranium reserves of 800,000 tons. The ultimate available supply
1596-552: Is malleable , ductile , slightly paramagnetic , strongly electropositive and a poor electrical conductor . Uranium metal has a very high density of 19.1 g/cm , denser than lead (11.3 g/cm ), but slightly less dense than tungsten and gold (19.3 g/cm ). Uranium metal reacts with almost all non-metallic elements (except noble gases ) and their compounds , with reactivity increasing with temperature. Hydrochloric and nitric acids dissolve uranium, but non-oxidizing acids other than hydrochloric acid attack
1680-523: Is a naturally occurring element found in low levels in all rock, soil, and water. It is the highest-numbered element found naturally in significant quantities on Earth and is almost always found combined with other elements. Uranium is the 48th most abundant element in the Earth’s crust. The decay of uranium, thorium , and potassium-40 in Earth's mantle is thought to be the main source of heat that keeps
1764-530: Is also fissile by thermal neutrons. These discoveries led numerous countries to begin working on the development of nuclear weapons and nuclear power . Despite fission having been discovered in Germany, the Uranverein ("uranium club") Germany's wartime project to research nuclear power and/or weapons was hampered by limited resources, infighting, the exile or non-involvement of several prominent scientists in
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#17327939907731848-520: Is believed to be sufficient for at least the next 85 years, though some studies indicate underinvestment in the late twentieth century may produce supply problems in the 21st century. Uranium deposits seem to be log-normal distributed. There is a 300-fold increase in the amount of uranium recoverable for each tenfold decrease in ore grade. In other words, there is little high grade ore and proportionately much more low grade ore available. Calcined uranium yellowcake, as produced in many large mills, contains
1932-409: Is characterized by fine-grained crystals indistinguishable to the human eye, described as aphantic . Crystals in aphantic rocks are small in size due to their rapid formation during eruption. Any larger crystals visible to the human eye, called phenocrysts , form earlier while slowly cooling in the magma reservoir. When igneous rocks contain two distinct grain sizes, the texture is porphyritic , and
2016-785: Is difficult to precipitate uranium as phosphate in the presence of excess carbonate at alkaline pH. A Sphingomonas sp. strain BSAR-1 has been found to express a high activity alkaline phosphatase (PhoK) that has been applied for bioprecipitation of uranium as uranyl phosphate species from alkaline solutions. The precipitation ability was enhanced by overexpressing PhoK protein in E. coli . Plants absorb some uranium from soil. Dry weight concentrations of uranium in plants range from 5 to 60 parts per billion, and ash from burnt wood can have concentrations up to 4 parts per million. Dry weight concentrations of uranium in food plants are typically lower with one to two micrograms per day ingested through
2100-418: Is diluted with uranium-238 and reused as fuel for nuclear reactors. Spent nuclear fuel forms radioactive waste , which mostly consists of uranium-238 and poses a significant health threat and environmental impact . Uranium is a silvery white, weakly radioactive metal . It has a Mohs hardness of 6, sufficient to scratch glass and roughly equal to that of titanium , rhodium , manganese and niobium . It
2184-485: Is found in hundreds of minerals, including uraninite (the most common uranium ore ), carnotite , autunite , uranophane , torbernite , and coffinite . Significant concentrations of uranium occur in some substances such as phosphate rock deposits, and minerals such as lignite , and monazite sands in uranium-rich ores (it is recovered commercially from sources with as little as 0.1% uranium ). Like all elements with atomic weights higher than that of iron , uranium
2268-427: Is only naturally formed by the r-process (rapid neutron capture) in supernovae and neutron star mergers . Primordial thorium and uranium are only produced in the r-process, because the s-process (slow neutron capture) is too slow and cannot pass the gap of instability after bismuth. Besides the two extant primordial uranium isotopes, U and U, the r-process also produced significant quantities of U , which has
2352-407: Is produced through the thermal decomposition of uranium halides on a hot filament. It is estimated that 6.1 million tonnes of uranium exists in ores that are economically viable at US$ 130 per kg of uranium, while 35 million tonnes are classed as mineral resources (reasonable prospects for eventual economic extraction). Australia has 28% of the world's known uranium ore reserves and
2436-581: Is required because potassium is an incompatible element and tends to enter a melt first, whereas higher degrees of partial melting will liberate more calcium and sodium, which produce plagioclase , and hence a granite , adamellite or tonalite . At very low degrees of partial melting a silica undersaturated melt is produced, forming a nepheline syenite , where orthoclase is replaced by a feldspathoid such as leucite , nepheline or analcime . Conversely in certain conditions, large volumes of anorthite crystals may precipitate from thoroughly molten magma in
2520-448: Is the only naturally occurring fissile isotope , which makes it widely used in nuclear power plants and nuclear weapons . However, because of the low abundance of uranium-235 in natural uranium (which is, overwhelmingly, mostly uranium-238), uranium needs to undergo enrichment so that enough uranium-235 is present. Uranium-238 is fissionable by fast neutrons and is fertile , meaning it can be transmuted to fissile plutonium-239 in
2604-441: Is then calcined to remove impurities from the milling process before refining and conversion. Commercial-grade uranium can be produced through the reduction of uranium halides with alkali or alkaline earth metals . Uranium metal can also be prepared through electrolysis of KUF 5 or UF 4 , dissolved in molten calcium chloride ( CaCl 2 ) and sodium chloride ( Na Cl) solution. Very pure uranium
Syenite - Misplaced Pages Continue
2688-600: Is used for X-ray targets in the making of high-energy X-rays. The use of pitchblende , uranium in its natural oxide form, dates back to at least the year 79 AD, when it was used in the Roman Empire to add a yellow color to ceramic glazes. Yellow glass with 1% uranium oxide was found in a Roman villa on Cape Posillipo in the Bay of Naples , Italy, by R. T. Gunther of the University of Oxford in 1912. Starting in
2772-677: The Central Iberian Massif of Spain, in Cambrian to Ordovician beds of New Mexico and Colorado, Scandinavia, Brazil, and Ukraine. Extrusive rock Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff . In contrast, intrusive rock refers to rocks formed by magma which cools below
2856-402: The Manhattan Project , another team led by Enrico Fermi was able to initiate the first artificial self-sustained nuclear chain reaction , Chicago Pile-1 . An initial plan using enriched uranium-235 was abandoned as it was as yet unavailable in sufficient quantities. Working in a lab below the stands of Stagg Field at the University of Chicago , the team created the conditions needed for such
2940-497: The Megatons to Megawatts Program . An additional 4.6 billion tonnes of uranium are estimated to be dissolved in sea water ( Japanese scientists in the 1980s showed that extraction of uranium from sea water using ion exchangers was technically feasible). There have been experiments to extract uranium from sea water, but the yield has been low due to the carbonate present in the water. In 2012, ORNL researchers announced
3024-475: The Oklo Fossil Reactors . The ore deposit is 1.7 billion years old; then, uranium-235 constituted about 3% of uranium on Earth. This is high enough to permit a sustained chain reaction, if other supporting conditions exist. The capacity of the surrounding sediment to contain the health-threatening nuclear waste products has been cited by the U.S. federal government as supporting evidence for
3108-721: The Shippingport Atomic Power Station in Pennsylvania , which began on 26 May 1958. Nuclear power was used for the first time for propulsion by a submarine , the USS Nautilus , in 1954. In 1972, French physicist Francis Perrin discovered fifteen ancient and no longer active natural nuclear fission reactors in three separate ore deposits at the Oklo mine in Gabon , Africa, collectively known as
3192-527: The United States (2.5%), Argentina (2.1%) and Ukraine (1.9%). In 2008, Kazakhstan was forecast to increase production and become the world's largest supplier of uranium by 2009; Kazakhstan has dominated the world's uranium market since 2010. In 2021, its share was 45.1%, followed by Namibia (11.9%), Canada (9.7%), Australia (8.7%), Uzbekistan (7.2%), Niger (4.7%), Russia (5.5%), China (3.9%), India (1.3%), Ukraine (0.9%), and South Africa (0.8%), with
3276-560: The actinide series of the periodic table . A uranium atom has 92 protons and 92 electrons , of which 6 are valence electrons . Uranium radioactively decays , usually by emitting an alpha particle . The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes , making them useful for dating the age of the Earth . The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has
3360-604: The break-up of the Soviet Union in 1991, an estimated 600 short tons (540 metric tons) of highly enriched weapons grade uranium (enough to make 40,000 nuclear warheads) had been stored in often inadequately guarded facilities in the Russian Federation and several other former Soviet states. Police in Asia , Europe , and South America on at least 16 occasions from 1993 to 2005 have intercepted shipments of smuggled bomb-grade uranium or plutonium, most of which
3444-505: The first nuclear weapon used in war . An ensuing arms race during the Cold War between the United States and the Soviet Union produced tens of thousands of nuclear weapons that used uranium metal and uranium-derived plutonium-239 . Dismantling of these weapons and related nuclear facilities is carried out within various nuclear disarmament programs and costs billions of dollars. Weapon-grade uranium obtained from nuclear weapons
Syenite - Misplaced Pages Continue
3528-432: The oceans may contain 10 kg (2 × 10 lb). The concentration of uranium in soil ranges from 0.7 to 11 parts per million (up to 15 parts per million in farmland soil due to use of phosphate fertilizers ), and its concentration in sea water is 3 parts per billion. Uranium is more plentiful than antimony , tin , cadmium , mercury , or silver, and it is about as abundant as arsenic or molybdenum . Uranium
3612-640: The Dean of the Sapienza University of Rome , Orso Mario Corbino , named ausenium and hesperium , respectively. The experiments leading to the discovery of uranium's ability to fission (break apart) into lighter elements and release binding energy were conducted by Otto Hahn and Fritz Strassmann in Hahn's laboratory in Berlin. Lise Meitner and her nephew, physicist Otto Robert Frisch , published
3696-408: The Earth's outer core in the liquid state and drives mantle convection , which in turn drives plate tectonics . Uranium's concentration in the Earth's crust is (depending on the reference) 2 to 4 parts per million, or about 40 times as abundant as silver . The Earth's crust from the surface to 25 km (15 mi) down is calculated to contain 10 kg (2 × 10 lb) of uranium while
3780-691: The Russian government approved a federal program for nuclear and radiation safety for 2016 to 2030 with a budget of 562 billion rubles (ca. 8 billion USD ). Its key issue is "the deferred liabilities accumulated during the 70 years of the nuclear industry, particularly during the time of the Soviet Union". About 73% of the budget will be spent on decommissioning aged and obsolete nuclear reactors and nuclear facilities, especially those involved in state defense programs; 20% will go in processing and disposal of nuclear fuel and radioactive waste, and 5% into monitoring and ensuring of nuclear and radiation safety. Uranium
3864-509: The altered rock a distinctive brick red color, or by albitization (enrichment in sodium), leaving the altered rock a conspicuous white color. Episyenites are heterogenous in their properties, but all have experienced nearly complete disappearance of quartz at sub- solidus temperatures; that is, at temperatures below the melting point of the host rock. The formation of episyenites ( episyenitization ) typically takes place through leaching of quartz by mildly saline hydrothermal fluids, typically near
3948-566: The bulk of the use, including common bathroom and kitchen tiles which can be produced in green, yellow, mauve , black, blue, red and other colors. Uranium was also used in photographic chemicals (especially uranium nitrate as a toner ), in lamp filaments for stage lighting bulbs, to improve the appearance of dentures , and in the leather and wood industries for stains and dyes. Uranium salts are mordants of silk or wool. Uranyl acetate and uranyl formate are used as electron-dense "stains" in transmission electron microscopy , to increase
4032-409: The civilian sector is to fuel nuclear power plants . One kilogram of uranium-235 can theoretically produce about 20 terajoules of energy (2 × 10 joules ), assuming complete fission; as much energy as 1.5 million kilograms (1,500 tonnes ) of coal . Commercial nuclear power plants use fuel that is typically enriched to around 3% uranium-235. The CANDU and Magnox designs are
4116-549: The contrast of biological specimens in ultrathin sections and in negative staining of viruses , isolated cell organelles and macromolecules . The discovery of the radioactivity of uranium ushered in additional scientific and practical uses of the element. The long half-life of uranium-238 (4.47 × 10 years) makes it well-suited for use in estimating the age of the earliest igneous rocks and for other types of radiometric dating , including uranium–thorium dating , uranium–lead dating and uranium–uranium dating . Uranium metal
4200-442: The development of uranium mining to extract the radium, which was used to make glow-in-the-dark paints for clock and aircraft dials. This left a prodigious quantity of uranium as a waste product, since it takes three tonnes of uranium to extract one gram of radium. This waste product was diverted to the glazing industry, making uranium glazes very inexpensive and abundant. Besides the pottery glazes, uranium tile glazes accounted for
4284-465: The element very slowly. When finely divided, it can react with cold water; in air, uranium metal becomes coated with a dark layer of uranium oxide . Uranium in ores is extracted chemically and converted into uranium dioxide or other chemical forms usable in industry. Uranium-235 was the first isotope that was found to be fissile . Other naturally occurring isotopes are fissionable, but not fissile. On bombardment with slow neutrons, uranium-235 most of
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#17327939907734368-440: The extrusive rock basalt. Composite or stratovolcanoes often have andesitic magma and typically form the extrusive rock andesite. Andesitic magma is composed of many gases and melted mantle rocks. Cinder or scoria cones violently expel lava with high gas content, and due to the vapor bubbles in this mafic lava, the extrusive basalt scoria is formed. Lava domes are formed by high viscosity lava that piles up, forming
4452-493: The feasibility to store spent nuclear fuel at the Yucca Mountain nuclear waste repository . Above-ground nuclear tests by the Soviet Union and the United States in the 1950s and early 1960s and by France into the 1970s and 1980s spread a significant amount of fallout from uranium daughter isotopes around the world. Additional fallout and pollution occurred from several nuclear accidents . Uranium miners have
4536-503: The field and several crucial mistakes such as failing to account for impurities in available graphite samples which made it appear less suitable as a neutron moderator than it is in reality. Germany's attempts to build a natural uranium / heavy water reactor had not come close to reaching criticality by the time the Americans reached Haigerloch , the site of the last German wartime reactor experiment. On 2 December 1942, as part of
4620-520: The finer crystals are called the groundmass . The extrusive rocks scoria and pumice have a vesicular, bubble-like, texture due to the presence of vapor bubbles trapped in the magma. Shield volcanoes are large, slow forming volcanoes that erupt fluid basaltic magma that cools to form the extrusive rock basalt . Basalt is composed of minerals readily available in the planet's crust, including feldspars and pyroxenes . Fissure volcanoes pour out low viscosity basaltic magma from fissure vents to form
4704-468: The first sample of uranium metal by heating uranium tetrachloride with potassium . Henri Becquerel discovered radioactivity by using uranium in 1896. Becquerel made the discovery in Paris by leaving a sample of a uranium salt, K 2 UO 2 (SO 4 ) 2 (potassium uranyl sulfate), on top of an unexposed photographic plate in a drawer and noting that the plate had become "fogged". He determined that
4788-506: The fissile component, and on 29 February 1940, Nier used an instrument he built at the University of Minnesota to separate the world's first uranium-235 sample in the Tate Laboratory. Using Columbia University 's cyclotron , John Dunning confirmed the sample to be the isolated fissile material on 1 March. Further work found that the far more common uranium-238 isotope can be transmuted into plutonium, which, like uranium-235,
4872-504: The following. The term syenite was originally applied to hornblende granite like that of Syene (now Aswan) in Egypt , from which the name is derived. Episyenite (or epi-syenite ) is a term used in petrology to describe veins, pods, or lenses of rock originally rich in silicon dioxide (SiO 2 ) from which quartz has been severely depleted. This is often accompanied by strong enrichment in potassium and rare earth elements , leaving
4956-611: The food people eat. Worldwide production of uranium in 2021 was 48,332 tonnes , of which 21,819 t (45%) was mined in Kazakhstan . Other important uranium mining countries are Namibia (5,753 t), Canada (4,693 t), Australia (4,192 t), Uzbekistan (3,500 t), and Russia (2,635 t). Uranium ore is mined in several ways: open pit , underground , in-situ leaching , and borehole mining . Low-grade uranium ore mined typically contains 0.01 to 0.25% uranium oxides. Extensive measures must be employed to extract
5040-466: The form of amphibole (typically hornblende ) and clinopyroxene . Biotite is rare, because in a syenite magma the formation of feldspar consumes nearly all the aluminium. However less Al-rich phyllosilicates may be included, such as annite . Other common accessory minerals are apatite , titanite , zircon and other opaques. Most syenites are either peralkaline with high proportions of alkali elements relative to aluminum, or peraluminous with
5124-448: The highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten . It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite . Many contemporary uses of uranium exploit its unique nuclear properties. Uranium-235
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#17327939907735208-732: The late Middle Ages , pitchblende was extracted from the Habsburg silver mines in Joachimsthal , Bohemia (now Jáchymov in the Czech Republic) in the Ore Mountains , and was used as a coloring agent in the local glassmaking industry. In the early 19th century, the world's only known sources of uranium ore were these mines. The discovery of the element is credited to the German chemist Martin Heinrich Klaproth . While he
5292-601: The metal from its ore. High-grade ores found in Athabasca Basin deposits in Saskatchewan , Canada can contain up to 23% uranium oxides on average. Uranium ore is crushed and rendered into a fine powder and then leached with either an acid or alkali . The leachate is subjected to one of several sequences of precipitation, solvent extraction, and ion exchange. The resulting mixture, called yellowcake , contains at least 75% uranium oxides U 3 O 8 . Yellowcake
5376-491: The military sector is in high-density penetrators. This ammunition consists of depleted uranium (DU) alloyed with 1–2% other elements, such as titanium or molybdenum . At high impact speed, the density, hardness, and pyrophoricity of the projectile enable the destruction of heavily armored targets. Tank armor and other removable vehicle armor can also be hardened with depleted uranium plates. The use of depleted uranium became politically and environmentally contentious after
5460-462: The new element after the recently discovered planet Uranus . Eugène-Melchior Péligot was the first person to isolate the metal, and its radioactive properties were discovered in 1896 by Henri Becquerel . Research by Otto Hahn , Lise Meitner , Enrico Fermi and others, such as J. Robert Oppenheimer starting in 1934 led to its use as a fuel in the nuclear power industry and in Little Boy ,
5544-584: The newly discovered metal itself (in fact, that powder was an oxide of uranium ). He named the newly discovered element after the planet Uranus (named after the primordial Greek god of the sky ), which had been discovered eight years earlier by William Herschel . In 1841, Eugène-Melchior Péligot , Professor of Analytical Chemistry at the Conservatoire National des Arts et Métiers (Central School of Arts and Manufactures) in Paris , isolated
5628-422: The ocean floor and produce the extrusive rock pumice. Pumice is a light-weight glass with a vesicular texture that differs from scoria in its silicic composition and therefore floats. This article about igneous petrology is a stub . You can help Misplaced Pages by expanding it . Uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in
5712-656: The only commercial reactors capable of using unenriched uranium fuel. Fuel used for United States Navy reactors is typically highly enriched in uranium-235 (the exact values are classified ). In a breeder reactor , uranium-238 can also be converted into plutonium-239 through the following reaction: Before (and, occasionally, after) the discovery of radioactivity, uranium was primarily used in small amounts for yellow glass and pottery glazes, such as uranium glass and in Fiestaware . The discovery and isolation of radium in uranium ore (pitchblende) by Marie Curie sparked
5796-487: The physical explanation in February 1939 and named the process " nuclear fission ". Soon after, Fermi hypothesized that fission of uranium might release enough neutrons to sustain a fission reaction. Confirmation of this hypothesis came in 1939, and later work found that on average about 2.5 neutrons are released by each fission of uranium-235. Fermi urged Alfred O. C. Nier to separate uranium isotopes for determination of
5880-557: The possibility that these organisms could be used in bioremediation to decontaminate uranium-polluted water. The proteobacterium Geobacter has also been shown to bioremediate uranium in ground water. The mycorrhizal fungus Glomus intraradices increases uranium content in the roots of its symbiotic plant. In nature, uranium(VI) forms highly soluble carbonate complexes at alkaline pH. This leads to an increase in mobility and availability of uranium to groundwater and soil from nuclear wastes which leads to health hazards. However, it
5964-550: The shorter half-lives of these parents and their lower production than U and Pu, the parents of thorium: the Cm/ U ratio at the formation of the Solar System was (7.0 ± 1.6) × 10 . Some bacteria, such as Shewanella putrefaciens , Geobacter metallireducens and some strains of Burkholderia fungorum , use uranium for their growth and convert U(VI) to U(IV). Recent research suggests that this pathway includes reduction of
6048-509: The soluble U(VI) via an intermediate U(V) pentavalent state. Other organisms, such as the lichen Trapelia involuta or microorganisms such as the bacterium Citrobacter , can absorb concentrations of uranium that are up to 300 times the level of their environment. Citrobacter species absorb uranyl ions when given glycerol phosphate (or other similar organic phosphates). After one day, one gram of bacteria can encrust themselves with nine grams of uranyl phosphate crystals; this creates
6132-509: The stabilization of political and economical turmoil of the early 1990s. For example, in 1993 there were 29 incidents ranking above level 1 on the International Nuclear Event Scale , and this number dropped under four per year in 1995–2003. The number of employees receiving annual radiation doses above 20 mSv , which is equivalent to a single full-body CT scan , saw a strong decline around 2000. In November 2015,
6216-515: The successful development of a new absorbent material dubbed HiCap which performs surface retention of solid or gas molecules, atoms or ions and also effectively removes toxic metals from water, according to results verified by researchers at Pacific Northwest National Laboratory . In 2005, ten countries accounted for the majority of the world's concentrated uranium oxides: Canada (27.9%), Australia (22.8%), Kazakhstan (10.5%), Russia (8.0%), Namibia (7.5%), Niger (7.4%), Uzbekistan (5.5%),
6300-624: The surface. The main effect of extrusion is that the magma can cool much more quickly in the open air or under seawater , and there is little time for the growth of crystals . Sometimes, a residual portion of the matrix fails to crystallize at all, instead becoming a natural glass like obsidian . If the magma contains abundant volatile components which are released as free gas, then it may cool with large or small vesicles (bubble-shaped cavities) such as in pumice , scoria , or vesicular basalt . Other examples of extrusive rocks are rhyolite and andesite . The texture of extrusive rocks
6384-513: The time splits into two smaller nuclei , releasing nuclear binding energy and more neutrons. If too many of these neutrons are absorbed by other uranium-235 nuclei, a nuclear chain reaction occurs that results in a burst of heat or (in some circumstances) an explosion. In a nuclear reactor, such a chain reaction is slowed and controlled by a neutron poison , absorbing some of the free neutrons. Such neutron absorbent materials are often part of reactor control rods (see nuclear reactor physics for
6468-727: The use of such munitions by the US, UK and other countries during wars in the Persian Gulf and the Balkans raised questions concerning uranium compounds left in the soil (see Gulf War syndrome ). Depleted uranium is also used as a shielding material in some containers used to store and transport radioactive materials. While the metal itself is radioactive, its high density makes it more effective than lead in halting radiation from strong sources such as radium . Other uses of depleted uranium include counterweights for aircraft control surfaces, as ballast for missile re-entry vehicles and as
6552-528: The use of uranium in manufacturing and metalwork. Tools made with these formulas remained in use for several decades, until the Manhattan Project and the Cold War placed a large demand on uranium for fission research and weapon development. A team led by Enrico Fermi in 1934 found that bombarding uranium with neutrons produces beta rays ( electrons or positrons from the elements produced; see beta particle ). The fission products were at first mistaken for new elements with atomic numbers 93 and 94, which
6636-542: The whole facility (later, the town of Arco became the first in the world to have all its electricity come from nuclear power generated by BORAX-III , another reactor designed and operated by Argonne National Laboratory ). The world's first commercial scale nuclear power station, Obninsk in the Soviet Union , began generation with its reactor AM-1 on 27 June 1954. Other early nuclear power plants were Calder Hall in England, which began generation on 17 October 1956, and
6720-680: The world's largest single uranium deposit is located at the Olympic Dam Mine in South Australia . There is a significant reserve of uranium in Bakouma , a sub-prefecture in the prefecture of Mbomou in the Central African Republic . Some uranium also originates from dismantled nuclear weapons. For example, in 1993–2013 Russia supplied the United States with 15,000 tonnes of low-enriched uranium within
6804-588: Was believed that uranium was relatively rare, and that nuclear proliferation could be avoided by simply buying up all known uranium stocks, but within a decade large deposits of it were discovered in many places around the world. The X-10 Graphite Reactor at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, formerly known as the Clinton Pile and X-10 Pile, was the world's second artificial nuclear reactor (after Enrico Fermi's Chicago Pile) and
6888-556: Was from ex-Soviet sources. From 1993 to 2005 the Material Protection, Control, and Accounting Program , operated by the federal government of the United States , spent about US$ 550 million to help safeguard uranium and plutonium stockpiles in Russia. This money was used for improvements and security enhancements at research and storage facilities. Safety of nuclear facilities in Russia has been significantly improved since
6972-491: Was the first reactor designed and built for continuous operation. Argonne National Laboratory 's Experimental Breeder Reactor I , located at the Atomic Energy Commission's National Reactor Testing Station near Arco, Idaho , became the first nuclear reactor to create electricity on 20 December 1951. Initially, four 150-watt light bulbs were lit by the reactor, but improvements eventually enabled it to power
7056-454: Was working in his experimental laboratory in Berlin in 1789, Klaproth was able to precipitate a yellow compound (likely sodium diuranate ) by dissolving pitchblende in nitric acid and neutralizing the solution with sodium hydroxide . Klaproth assumed the yellow substance was the oxide of a yet-undiscovered element and heated it with charcoal to obtain a black powder, which he thought was
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