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86-550: The medal is a disc of gilt and enamel, based on the seal of the president of the United States , with the eagle surrounded by a wreath of leaves. The medal is suspended on a ribbon, dark blue with a light blue central stripe and white edge stripes. Despite being a civilian award, it may be worn on some military uniforms. Hubert Dickey Ballantine and Martin Mathews were jointly awarded the 1981 Citizens Medal as founders of

172-408: A camel ) arranged in a single or double row along a flat ferrule made of wood or cardboard. In order to transfer the gold leaf, the hairs are first given a very light coating of adhesive by brushing them against a surface such as the back of the user's hand which has been coated with a thin layer of petroleum jelly (a common misconception is that static electricity causes the gold foil to attach to

258-400: A half-life of 444 years, and Hg with a half-life of 46.612 days. Most of the remaining radioisotopes have half-lives that are less than a day. Hg occurs naturally in tiny traces as an intermediate decay product of U . Hg and Hg are the most often studied NMR -active nuclei, having spins of 1 ⁄ 2 and 3 ⁄ 2 respectively. Hg is

344-442: A melting point of −38.83 °C and a boiling point of 356.73 °C, both the lowest of any stable metal, although preliminary experiments on copernicium and flerovium have indicated that they have even lower boiling points. This effect is due to lanthanide contraction and relativistic contraction reducing the orbit radius of the outermost electrons, and thus weakening the metallic bonding in mercury. Upon freezing,

430-434: A mercury-aluminium amalgam when the two pure metals come into contact. Since the amalgam destroys the aluminium oxide layer which protects metallic aluminium from oxidizing in-depth (as in iron rusting ), even small amounts of mercury can seriously corrode aluminium. For this reason, mercury is not allowed aboard an aircraft under most circumstances because of the risk of it forming an amalgam with exposed aluminium parts in

516-640: A soft metal , mercury forms very stable derivatives with the heavier chalcogens . Preeminent is mercury(II) sulfide , HgS, which occurs in nature as the ore cinnabar and is the brilliant pigment vermilion . Like ZnS , HgS crystallizes in two forms , the reddish cubic form and the black zinc blende form. The latter sometimes occurs naturally as metacinnabar . Mercury(II) selenide (HgSe) and mercury(II) telluride (HgTe) are known, these as well as various derivatives, e.g. mercury cadmium telluride and mercury zinc telluride being semiconductors useful as infrared detector materials. Mercury(II) salts form

602-593: A chamber 60 feet below the 1800-year-old pyramid known as the Temple of the Feathered Serpent , the third-largest pyramid of Teotihuacan , Mexico, along with "jade statues, jaguar remains, a box filled with carved shells and rubber balls". In Lamanai , once a major city of the Maya civilization , a pool of mercury was found under a marker in a Mesoamerican ballcourt . Aristotle recounts that Daedalus made

688-459: A digital display. Some transit telescopes use a basin of mercury to form a flat and absolutely horizontal mirror, useful in determining an absolute vertical or perpendicular reference. Concave horizontal parabolic mirrors may be formed by rotating liquid mercury on a disk, the parabolic form of the liquid thus formed reflecting and focusing incident light. Such liquid-mirror telescopes are cheaper than conventional large mirror telescopes by up to

774-401: A factor of 100, but the mirror cannot be tilted and always points straight up. Liquid mercury is part of a popular secondary reference electrode (called the calomel electrode ) in electrochemistry as an alternative to the standard hydrogen electrode . The calomel electrode is used to work out the electrode potential of half cells . The triple point of mercury, −38.8344 °C, is

860-487: A laxative and dewormer, and it was used in teething powders for infants. The mercury-containing organohalide merbromin (sometimes sold as Mercurochrome) is still widely used but has been banned in some countries, such as the U.S. Mercury is an ingredient in dental amalgams . Thiomersal (called Thimerosal in the United States) is an organic compound used as a preservative in vaccines , although this use

946-448: A positive charge. One example is Hg 3 (AsF 6 ) 2 containing the Hg 3 cation. Mercury(II) is the most common oxidation state and is the main one in nature as well. All four mercuric halides are known and have been demonstrated to form linear coordination geometry , despite mercury's tendency to form tetrahedral molecular geometry with other ligands. This behavior

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1032-455: A publication now in the public domain :  Chisholm, Hugh , ed. (1911). " Gilding ". Encyclopædia Britannica . Vol. 12 (11th ed.). Cambridge University Press. pp. 13–14. Mercury (element) Mercury is a chemical element ; it has symbol Hg and atomic number 80. It is also known as quicksilver and was formerly named hydrargyrum ( / h aɪ ˈ d r ɑːr dʒ ər ə m / hy- DRAR -jər-əm ) from

1118-507: A thin layer of bitumen underneath to help adhesion. The next advances involved two simple processes. The first involves gold leaf, which is gold that is hammered or cut into very thin sheets. Gold leaf is often thinner than standard paper today, and when held to the light is semi-transparent. In ancient times it was typically about ten times thicker than today, and perhaps half that in the Middle Ages . If gilding on canvas or on wood,

1204-459: A variety of complex derivatives with ammonia . These include Millon's base (Hg 2 N ), the one-dimensional polymer (salts of HgNH 2 ) n ), and "fusible white precipitate" or [Hg(NH 3 ) 2 ]Cl 2 . Known as Nessler's reagent , potassium tetraiodomercurate(II) ( K 2 HgI 4 ) is still occasionally used to test for ammonia owing to its tendency to form the deeply colored iodide salt of Millon's base. Mercury fulminate

1290-506: A wooden statue of Aphrodite move by pouring quicksilver in its interior. In Greek mythology Daedalus gave the appearance of voice in his statues using quicksilver. The ancient Greeks used cinnabar (mercury sulfide) in ointments; the ancient Egyptians and the Romans used it in cosmetics . By 500 BC mercury was used to make amalgams (Medieval Latin amalgama , "alloy of mercury") with other metals. Alchemists thought of mercury as

1376-474: Is a detonator widely used in explosives . Organic mercury compounds are historically important but are of little industrial value in the western world. Mercury(II) salts are a rare example of simple metal complexes that react directly with aromatic rings. Organomercury compounds are always divalent and usually two-coordinate and linear geometry. Unlike organocadmium and organozinc compounds, organomercury compounds do not react with water. They usually have

1462-562: Is a topical antiseptic used for minor cuts and scrapes in some countries. Today, the use of mercury in medicine has greatly declined in all respects, especially in developed countries. Mercury is still used in some diuretics , although substitutes such as thiazides now exist for most therapeutic uses. In 2003, mercury compounds were found in some over-the-counter drugs , including topical antiseptics , stimulant laxatives, diaper-rash ointment , eye drops , and nasal sprays . The FDA has "inadequate data to establish general recognition of

1548-439: Is a type of gilding brush used for transferring sheets of metal leaf to either a surface that has been prepared to accept the leaf or to a gilder's block where the leaf is then cut with a gilder's knife into smaller portions before being transferred to the prepared surface. The hairs on a gilder's tip are usually made of either blue squirrel hair or the hair of a badger (sometimes other hairs are also used, such as that of

1634-612: Is also described as "gilt". Where metal is gilded, the metal below was traditionally silver in the West, to make silver-gilt (or vermeil ) objects, but gilt-bronze is commonly used in China, and also called ormolu if it is Western. Methods of gilding include hand application and gluing, typically of gold leaf , chemical gilding, and electroplating , the last also called gold plating . Parcel-gilt (partial gilt) objects are only gilded over part of their surfaces. This may mean that all of

1720-409: Is also used in fluorescent lighting . Electricity passed through mercury vapor in a fluorescent lamp produces short-wave ultraviolet light , which then causes the phosphor in the tube to fluoresce , making visible light. Mercury is a heavy, silvery-white metal that is liquid at room temperature. Compared to other metals, it is a poor conductor of heat, but a fair conductor of electricity. It has

1806-480: Is an exception, and iron flasks have traditionally been used to transport the material. Several other first row transition metals with the exception of manganese , copper and zinc are also resistant in forming amalgams. Other elements that do not readily form amalgams with mercury include platinum . Sodium amalgam is a common reducing agent in organic synthesis , and is also used in high-pressure sodium lamps. Mercury readily combines with aluminium to form

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1892-401: Is applied to numerous and diverse surfaces and by various processes. More traditional techniques still form an important part of framemaking and are sometimes still employed in general woodworking , cabinet -work, decorative painting and interior decoration , bookbinding , and ornamental leather work, and in the decoration of pottery , porcelain, and glass . Herodotus mentions that

1978-432: Is in decline. Although it was widely speculated that this mercury-based preservative could cause or trigger autism in children, no evidence supports any such link. Nevertheless, thiomersal has been removed from, or reduced to trace amounts in, all U.S. vaccines recommended for children 6 years of age and under, with the exception of the inactivated influenza vaccine. Merbromin (Mercurochrome), another mercury compound,

2064-433: Is performed by a solution of gold in aqua regia , applied by dipping a linen rag into the solution, burning it, and rubbing the black and heavy ashes on the silver with the finger or a piece of leather or cork. Wet gilding is effected by means of a dilute solution of gold(III) chloride in aqua regia with twice its quantity of ether . The liquids are agitated and allowed to rest, to allow the ether to separate and float on

2150-597: Is similar to the Ag ion. The best known mercury halide is mercury(II) chloride , an easily sublimating white solid. Mercury(II) oxide , the main oxide of mercury, arises when the metal is exposed to air for long periods at elevated temperatures. It reverts to the elements upon heating near 400 °C, as was demonstrated by Joseph Priestley in an early synthesis of pure oxygen . Hydroxides of mercury are poorly characterized, as attempted isolation studies of mercury(II) hydroxide have yielded mercury oxide instead. Being

2236-405: Is then applied with a small brush, and as it evaporates it deposits the gold, which can now be heated and polished. For small delicate figures, a pen or a fine brush may be used for laying on the ether solution. The gold(III) chloride can also be dissolved in water in electroless plating wherein the gold is slowly reduced out of solution onto the surface to be gilded. When this technique is used on

2322-423: Is then exposed to heat, before being quenched in water. By this method, the color of the gilding is further improved and brought nearer to that of gold, probably by removing any particles of copper that may have been on the gilt surface. This process, when skillfully carried out, produces gilding of great solidity and beauty. This method of gilding metallic objects was formerly widespread, but fell into disuse as

2408-573: Is used as the ligand). Mercury(I) chloride , a colorless solid also known as calomel , is really the compound with the formula Hg 2 Cl 2 , with the connectivity Cl-Hg-Hg-Cl. It reacts with chlorine to give mercury(II) chloride , which resists further oxidation. Mercury(I) hydride , a colorless gas, has the formula HgH, containing no Hg-Hg bond; however, the gas has only ever been observed as isolated molecules. Indicative of its tendency to bond to itself, mercury forms mercury polycations , which consist of linear chains of mercury centers, capped with

2494-400: Is used in thermometers , barometers , manometers , sphygmomanometers , float valves , mercury switches , mercury relays , fluorescent lamps and other devices, although concerns about the element's toxicity have led to the phasing out of such mercury-containing instruments. It remains in use in scientific research applications and in amalgam for dental restoration in some locales. It

2580-518: Is used in some liquid-in-glass thermometers , especially those used to measure high temperatures. A still increasing amount is used as gaseous mercury in fluorescent lamps , while most of the other applications are slowly being phased out due to health and safety regulations. In some applications, mercury is replaced with less toxic but considerably more expensive Galinstan alloy . Mercury and its compounds have been used in medicine, although they are much less common today than they once were, now that

2666-435: Is wrought or chased, the application of mercury before the amalgam is applied allows for it to be more easily spread. When the surface of the metal is plain, the amalgam can be applied to it directly. When no such preparation is applied, the surface to be gilded is simply bitten and cleaned with nitric acid . A deposit of mercury is obtained on a metallic surface by means of quicksilver water, a solution of mercury(II) nitrate ,

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2752-456: The 2020 United States presidential election or their response to the subsequent January 6 United States Capitol attack in 2021. Due to the COVID-19 pandemic, their awards were delayed in 2021 and 2022. Gilding Gilding is a decorative technique for applying a very thin coating of gold over solid surfaces such as metal (most common), wood, porcelain , or stone. A gilded object

2838-581: The Egyptians gilded wood and metals, and many such objects have been excavated. Certain Ancient Greek statues of great prestige were chryselephantine , i.e., made of gold (for the clothing) and ivory (for the flesh); these however, were constructed with sheets of gold over a timber framework, not gilded. Extensive ornamental gilding was also used in the ceiling coffers of the Propylaea . Pliny

2924-591: The First Matter from which all metals were formed. They believed that different metals could be produced by varying the quality and quantity of sulfur contained within the mercury. The purest of these was gold, and mercury was called for in attempts at the transmutation of base (or impure) metals into gold, which was the goal of many alchemists. The mines in Almadén (Spain), Monte Amiata (Italy), and Idrija (now Slovenia) dominated mercury production from

3010-478: The Neolithic Age . In China and Tibet , mercury use was thought to prolong life, heal fractures, and maintain generally good health, although it is now known that exposure to mercury vapor leads to serious adverse health effects. The first emperor of a unified China, Qín Shǐ Huáng Dì —allegedly buried in a tomb that contained rivers of flowing mercury on a model of the land he ruled, representative of

3096-600: The Spaniards . The surface is etched with acids, resulting in a surface of porous gold. The porous surface is then burnished down, resulting in a shiny gold surface. The results fooled the conquistadors into thinking they had massive quantities of pure gold. The results startled modern archaeologists , because at first the pieces resemble electroplated articles. Keum-boo is a special Korean technique of silver-gilding, using depletion gilding . The gilding of decorative ceramics has been undertaken for centuries, with

3182-546: The 1650s. Fahrenheit's mercury thermometer was based on an earlier design that used alcohol rather than mercury; the mercury thermometer was significantly more accurate than those using alcohol. From the early 21st century onwards, the use of mercury thermometers has been declining, and mercury-containing instruments have been banned in many jurisdictions following the 1998 Protocol on Heavy Metals . Modern alternatives to mercury thermometers include resistance thermometers , thermocouples , and thermistor sensors that output to

3268-485: The 1960s onward, the majority of industrial plants moved away from mercury cell processes towards diaphragm cell technologies to produce chlorine, though 11% of the chlorine made in the United States was still produced with the mercury cell method as of 2005. Thermometers containing mercury were invented in the early 18th century by Daniel Gabriel Fahrenheit , though earlier attempts at making temperature-measuring instruments filled with quicksilver had been described in

3354-615: The Elder recorded that the first gilding seen at Rome was after the destruction of Carthage , under the censorship of Lucius Mummius , when the Romans began to gild the ceilings of their temples and palaces, the Capitol being the first place where this process was used. Gilding became a popular luxury within Rome soon after the introduction of the technique, with gilding soon being seen used on

3440-537: The Greek words hydor ' water ' and argyros ' silver ' , from which its chemical symbol is derived. A heavy , silvery d-block element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure ; the only other element that is liquid under these conditions is the halogen bromine , though metals such as caesium , gallium , and rubidium melt just above room temperature . Mercury occurs in deposits throughout

3526-567: The Mathews-Dickey Boy's Club. The teachers Rachel D'Avino, Anne Marie Murphy, Lauren Rousseau, and Victoria Soto and school administrators Mary Sherlach and Dawn Hochsprung, who perished in the Sandy Hook Elementary School shooting defending their students, were jointly awarded the 2012 Citizens Medal posthumously. Most of the recipients of the 2023 Citizens Medal were awarded for their respective roles in

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3612-399: The United States and Mexico, which once produced a large proportion of the world supply, have now been completely mined out or, in the case of Slovenia ( Idrija ) and Spain ( Almadén ), shut down due to the fall of the price of mercury. Nevada 's McDermitt Mine, the last mercury mine in the United States, closed in 1992. The price of mercury has been highly volatile over the years and in 2006

3698-405: The aircraft. Mercury embrittlement is the most common type of liquid metal embrittlement, as mercury is a natural component of some hydrocarbon reservoirs and will come into contact with petroleum processing equipment under normal conditions. There are seven stable isotopes of mercury, with Hg being the most abundant (29.86%). The longest-lived radioisotopes are Hg with

3784-434: The body; the mercury used in the process also evaporates into the atmosphere, thus polluting it. This process has generally been supplanted by the electroplating of gold over a nickel substrate , which is more economical and less dangerous. In depletion gilding, a subtractive process discovered in pre-Columbian Mesoamerica , articles are fabricated by various techniques from an alloy of copper and gold, named tumbaga by

3870-412: The brush, but this is not so) and then laying the edge of the brush along the edge of the piece of metal foil. The jelly will cause the metal to adhere very gently to the hairs and allow the piece to be floated from the paper surface on which had previously been stored. Because the leaf is so thin, this must be done in a room with extremely still air, and the user of the tip usually does not breathe until

3956-464: The crustal mass, mercury ores can be extraordinarily concentrated considering the element's abundance in ordinary rock. The richest mercury ores contain up to 2.5% mercury by mass, and even the leanest concentrated deposits are at least 0.1% mercury (12,000 times average crustal abundance). It is found either as a native metal (rare) or in cinnabar , metacinnabar , sphalerite , corderoite , livingstonite and other minerals , with cinnabar (HgS) being

4042-426: The dangers of mercury toxicity became known. Since fire-gilding requires that the mercury be volatilized to drive off the mercury and leave the gold behind on the surface, it is extremely dangerous. Breathing the fumes generated by this process can quickly result in serious health problems, such as neurological damage and endocrine disorders , since inhalation is a very efficient route for mercuric compounds to enter

4128-420: The decorated ware is fired in a kiln to fuse the gold to the glaze and hence ensure its permanence. The most important factors affecting coating quality are the composition of applied gold, the state of the surface before application, the thickness of the layer and the firing conditions. A number of different forms and compositions are available to apply gold to ceramic, and these include: A gilder's tip

4214-531: The dimeric cation, Hg 2 . Stable derivatives include the chloride and nitrate . In aqueous solution of a mercury(I) salt, slight disproportion of Hg 2 into Hg and Hg results in >0.5% of dissolved mercury existing as Hg . In these solutions, complexation of the Hg with addition of ligands such as cyanide causes disproportionation to go to completion, with all Hg 2 precipitating as elemental mercury and insoluble mercury(II) compounds (e.g. mercury(II) cyanide if cyanide

4300-405: The following substances: red ochre , verdigris , copper scales, alum , vitriol , and borax . By this operation the color of the gilding is heightened, as a result of the perfect dissipation of some of the remaining mercury. The gilt surface is then covered over with potassium nitrate , alum or other salts, ground together, and mixed into a paste with water or weak ammonia . The piece of metal

4386-539: The form of one of its common ores, cinnabar, is used in various traditional medicines, especially in traditional Chinese medicine . Review of its safety has found that cinnabar can lead to significant mercury intoxication when heated, consumed in overdose , or taken long term, and can have adverse effects at therapeutic doses, though effects from therapeutic doses are typically reversible. Although this form of mercury appears to be less toxic than other forms, its use in traditional Chinese medicine has not yet been justified, as

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4472-471: The formula HgR 2 , which are often volatile, or HgRX, which are often solids, where R is aryl or alkyl and X is usually halide or acetate. Methylmercury , a generic term for compounds with the formula CH 3 HgX, is a dangerous family of compounds that are often found in polluted water. They arise by a process known as biomethylation . Mercury is used primarily for the manufacture of industrial chemicals or for electrical and electronic applications. It

4558-446: The gold as pigment in paint: the artist ground the gold into a fine powder and mixed it with a binder such as gum arabic . The resulting gold paint, called shell gold , was applied in the same way as with any paint. Sometimes, after either gold-leafing or gold-painting, the artist would heat the piece enough to melt the gold slightly, ensuring an even coat. These techniques remained the only alternatives for materials like wood, leather,

4644-467: The gold leaf was layered on using a gilder's tip and left to dry before being burnished with a piece of polished agate . Those gilding on canvas and parchment also sometimes employed stiffly-beaten egg whites ("glair"), gum , and/or Armenian bole as sizing, though egg whites and gum both become brittle over time, causing the gold leaf to crack and detach, and so honey was sometimes added to make them more flexible. Other gilding processes involved using

4730-700: The historic Almaden Quicksilver Mine and created a county park on the site, after conducting extensive safety and environmental analysis of the property. All known mercury compounds exhibit one of two positive oxidation states: I and II. Experiments have failed to unequivocally demonstrate any higher oxidation states: both the claimed 1976 electrosynthesis of an unstable Hg(III) species and 2007 cryogenic isolation of HgF 4 have disputed interpretations and remain difficult (if not impossible) to reproduce. Unlike its lighter neighbors, cadmium and zinc, mercury usually forms simple stable compounds with metal-metal bonds. Most mercury(I) compounds are diamagnetic and feature

4816-431: The inside, and none of the outside, of a chalice or similar vessel is gilded, or that patterns or images are made up by using a combination of gilt and ungilted areas. Gilding gives an object a gold appearance at a fraction of the cost of creating a solid gold object. In addition, a solid gold piece would often be too soft or too heavy for practical use. A gilt surface also does not tarnish as silver does. Modern gilding

4902-490: The largest use of mercury in the late 20th century was in the mercury cell process (also called the Castner-Kellner process ) where metallic sodium is formed as an amalgam at a cathode made from mercury; this sodium is then reacted with water to produce sodium hydroxide. Many of the industrial mercury releases of the 20th century came from this process, although modern plants claim to be safe in this regard. From

4988-454: The leaf is in place. Once the leaf has settled, it is often burnished with polished piece of agate to achieve a high degree of brilliance. Gilder's tips are necessary because touching the metal leaf with the finger tips would immediately cause the leaf to lose its coherent flattened shape and crumble irretrievably into metallic dust which then cannot be used for any purpose. [REDACTED]   This article incorporates text from

5074-542: The mercury for the colonies. Mercury deposits were discovered in the New World, and more than 100,000 tons of mercury were mined from the region of Huancavelica , Peru, over the course of three centuries following the discovery of deposits there in 1563. The patio process and later pan amalgamation process continued to create great demand for mercury to treat silver ores until the late 19th century. Former mines in Italy,

5160-402: The mercury has evaporated, indicated by the surface taking on a dull yellow color, the metal must undergo further steps to exhibit its fine gold color. First, the gilded surface is rubbed with a scratch brush of brass wire, until its surface is smooth. It is then covered with gilding wax, and again exposed to fire until the wax is burnt off. Gilding wax is composed of beeswax mixed with some of

5246-569: The mercury required for CFL bulb manufacture. Environmental dangers have been a concern, particularly in the southern cities of Foshan and Guangzhou , and in Guizhou province in the southwest. Abandoned mercury mine processing sites often contain very hazardous waste piles of roasted cinnabar calcines . Water run-off from such sites is a recognized source of ecological damage. Former mercury mines may be suited for constructive re-use; for example, in 1976 Santa Clara County, California purchased

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5332-574: The metallic surface at a temperature just under red-hot, pressing the leaf on with a burnisher, then reheating when additional leaf may be laid on. The process is completed by cold burnishing. "Overlaying" or folding or hammering on gold foil or gold leaf is the simplest and most ancient method, and is mentioned in Homer 's Odyssey and the Old Testament . The Ram in a Thicket (2600–2400 BC) from Ur describes this technique used on wood, with

5418-606: The mining of cinnabar and refining for mercury are hazardous and historic causes of mercury poisoning. In China, prison labor was used by a private mining company as recently as the 1950s to develop new cinnabar mines. Thousands of prisoners were used by the Luo Xi mining company to establish new tunnels. Worker health in functioning mines is at high risk. A newspaper claimed that an unidentified European Union directive calling for energy-efficient lightbulbs to be made mandatory by 2012 encouraged China to re-open cinnabar mines to obtain

5504-404: The mixture is stirred with an iron rod, the gold is totally absorbed. The proportion of mercury to gold is generally six or eight to one. When the amalgam is cold, it is squeezed through chamois leather to separate the superfluous mercury; the gold, with about twice its weight of mercury, remains behind, forming a yellowish silvery mass with the consistency of butter. When the metal to be gilded

5590-501: The modern chemical symbol for mercury. It is an abbreviation of hydrargyrum , a romanized form of the ancient Greek name for mercury, ὑδράργυρος ( hydrargyros ). Hydrargyros is a Greek compound word meaning ' water-silver ' , from ὑδρ - ( hydr -), the root of ὕδωρ ( hydor ) ' water ' , and ἄργυρος ( argyros ) ' silver ' . Like the English name quicksilver ( ' living-silver ' ), this name

5676-691: The most common ore. Mercury ores often occur in hot springs or other volcanic regions. Beginning in 1558, with the invention of the patio process to extract silver from ore using mercury, mercury became an essential resource in the economy of Spain and its American colonies. Mercury was used to extract silver from the lucrative mines in New Spain and Peru . Initially, the Spanish Crown's mines in Almadén in Southern Spain supplied all

5762-414: The nitric acid attacking the metal to which it is applied, and thus leaving a film of free metallic mercury. After the amalgam is equally spread over the prepared surface of the metal, the mercury is then carefully volatilized with heat just sufficient to do so, as a temperature too high may cause part of the gold to be driven off, or otherwise run together, leaving some of the metal surface bare. When

5848-461: The opening of the mine in Almadén 2500 years ago, until new deposits were found at the end of the 19th century. Mercury is an extremely rare element in Earth's crust ; it has an average crustal abundance by mass of only 0.08 parts per million (ppm) and is the 66th most abundant element in the Earth's crust. Because it does not blend geochemically with those elements that constitute the majority of

5934-419: The operations in which gold leaf is prepared, and the processes to mechanically attach the gold onto surfaces. The techniques include burnishing , water gilding and oil-gilding used by wood carvers and gilders; and the gilding operations of the house decorator, sign painter, bookbinder , the paper stainer and several others. Polished iron, steel and other metals are gilded mechanically by applying gold leaf to

6020-427: The permanence and brightness of gold appealing to designers. Both porcelain and earthenware are commonly decorated with gold, and in the late 1970s it was reported that 5 tonnes of gold were used annually for the decoration of these products. Some wall tiles also have gold decoration. Application techniques include spraying , brushing , banding machines, and direct or indirect screen-printing . After application

6106-468: The planet became one of the alchemical symbols for the metal, and Mercury became an alternative name for the metal. Mercury is the only metal for which the alchemical planetary name survives, as it was decided it was preferable to quicksilver as a chemical name. Mercury was found in Egyptian tombs that date from 1500 BC; cinnabar , the most common natural source of mercury, has been in use since

6192-483: The rivers of China—was reportedly killed by drinking a mercury and powdered jade mixture formulated by Qin alchemists intended as an elixir of immortality. Khumarawayh ibn Ahmad ibn Tulun , the second Tulunid ruler of Egypt (r. 884–896), known for his extravagance and profligacy , reportedly built a basin filled with mercury, on which he would lie on top of air-filled cushions and be rocked to sleep. In November 2014 "large quantities" of mercury were discovered in

6278-423: The safety and effectiveness" of the mercury ingredients in these products. Chlorine is produced from sodium chloride (common salt, NaCl) using electrolysis to separate metallic sodium from chlorine gas. Usually salt is dissolved in water to produce a brine. By-products of any such chloralkali process are hydrogen (H 2 ) and sodium hydroxide (NaOH), which is commonly called caustic soda or lye . By far

6364-499: The second surface of glass and backed with silver, it is known as " Angel gilding ". Fire-gilding or wash-gilding is a process by which an amalgam of gold is applied to metallic surfaces, the mercury being subsequently volatilized , leaving a film of gold or an amalgam containing 13 to 16% mercury. In the preparation of the amalgam, the gold must first be reduced to thin plates or grains, which are heated red-hot, and thrown into previously heated mercury, until it begins to smoke. When

6450-420: The surface of the acid. The whole mixture is then poured into a separating funnel with a small aperture, and allowed to rest for some time, when the acid is run off from below and the gold dissolved in ether separated. The ether will be found to have taken up all the gold from the acid, and may be used for gilding iron or steel, for which purpose the metal is polished with fine emery and spirits of wine . The ether

6536-448: The surface was often first coated with gesso . "Gesso" is a substance made of finely ground gypsum or chalk mixed with glue. Once the coating of gesso had been applied, allowed to dry, and smoothed, it was re-wet with a sizing made of rabbit-skin glue and water ("water gilding", which allows the surface to be subsequently burnished to a mirror-like finish) or boiled linseed oil mixed with litharge ("oil gilding", which does not) and

6622-409: The symptoms of its toxicity were confused with those of the syphilis it was believed to treat. It is also used as a disinfectant. Blue mass , a pill or syrup in which mercury is the main ingredient, was prescribed throughout the 19th century for numerous conditions including constipation, depression, child-bearing and toothaches. In the early 20th century, mercury was administered to children yearly as

6708-418: The therapeutic basis for the use of cinnabar is not clear. Mercury(I) chloride (also known as calomel or mercurous chloride) has been used in traditional medicine as a diuretic , topical disinfectant , and laxative . Mercury(II) chloride (also known as mercuric chloride or corrosive sublimate) was once used to treat syphilis (along with other mercury compounds), although it is so toxic that sometimes

6794-415: The toxic effects of mercury and its compounds are more widely understood. An example of the early therapeutic application of mercury was published in 1787 by James Lind . The first edition of The Merck Manuals (1899) featured many then-medically relevant mercuric compounds, such as mercury-ammonium chloride , yellow mercury proto-iodide , calomel , and mercuric chloride , among others. Mercury in

6880-422: The vellum pages of illuminated manuscripts , and gilt-edged stock. Chemical gilding embraces those processes in which the gold is at some stage of chemical combination. These include cold gilding, wet gilding, fire gilding and depletion gilding. In cold gilding, the gold is obtained in a state of extremely fine division (i.e. atomized or finely powdered), and applied by mechanical means. Cold gilding on silver

6966-941: The volume of mercury decreases by 3.59% and its density changes from 13.69 g/cm when liquid to 14.184 g/cm when solid. The coefficient of volume expansion is 181.59 × 10 at 0 °C, 181.71 × 10 at 20 °C and 182.50 × 10 at 100 °C (per °C). Solid mercury is malleable and ductile, and can be cut with a knife. Table of thermal and physical properties of liquid mercury: Mercury does not react with most acids, such as dilute sulfuric acid , although oxidizing acids such as concentrated sulfuric acid and nitric acid or aqua regia dissolve it to give sulfate , nitrate , and chloride . Like silver, mercury reacts with atmospheric hydrogen sulfide . Mercury reacts with solid sulfur flakes, which are used in mercury spill kits to absorb mercury (spill kits also use activated carbon and powdered zinc). Mercury dissolves many metals such as gold and silver to form amalgams . Iron

7052-425: The walls, vaults and inside the houses of anyone who could afford it, including the poor. Owing to the comparative thickness of the gold leaf used in ancient gilding, the traces of it that remain are remarkably brilliant and solid. Fire-gilding of metal goes back at least to the 4th century BC. Mercury -gilding was invented by Chinese Daoists in the 4th century CE and was used for the gilding of bronze plaques. It

7138-507: The world mostly as cinnabar ( mercuric sulfide ). The red pigment vermilion is obtained by grinding natural cinnabar or synthetic mercuric sulfide. Exposure to mercury and mercury-containing organic compounds is toxic to the nervous system , immune system and kidneys of humans and other animals; mercury poisoning can result from exposure to water-soluble forms of mercury (such as mercuric chloride or methylmercury ) either directly or through mechanisms of biomagnification . Mercury

7224-400: Was $ 650 per 76-pound (34.46 kg) flask . Mercury is extracted by heating cinnabar in a current of air and condensing the vapor. The equation for this extraction is: In 2020, China was the top producer of mercury, providing 88% of the world output (2200 out of 2500 tonnes), followed by Tajikistan (178 t), Russia (50 t) and Mexico (32 t). Because of the high toxicity of mercury, both

7310-500: Was due to mercury's liquid and shiny properties. The modern English name mercury comes from the planet Mercury . In medieval alchemy , the seven known metals—quicksilver, gold , silver , copper , iron , lead , and tin —were associated with the seven planets. Quicksilver was associated with the fastest planet, which had been named after the Roman god Mercury , who was associated with speed and mobility. The astrological symbol for

7396-531: Was known to Pliny (33,20,64–5), Vitruvius (8,8,4) and in the Early Medieval period to Theophilus (De Diversis Artibus Book III). In Europe, silver-gilt has always been more common than gilt-bronze, but in China the opposite has been the case. The ancient Chinese also developed the gilding of porcelain , which was later taken up by the French and other European potters. Mechanical gilding includes all

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