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Wolframite

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Wolframite is an iron , manganese , and tungstate mineral with a chemical formula of (Fe,Mn)WO 4 that is the intermediate mineral between ferberite ( Fe rich) and hübnerite ( Mn rich). Along with scheelite , the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives . Associated minerals include cassiterite , scheelite, bismuth , quartz, pyrite , galena , sphalerite , and arsenopyrite .

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103-793: This mineral was historically found in Europe in Bohemia , Saxony , and in the UK in Devon and Cornwall . China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Spain , Canada , Portugal , Russia , Australia , Thailand , South Korea , Rwanda , Bolivia , the United States , and the Democratic Republic of the Congo . The wolframite series

206-871: A German naturalist, Peter Simon Pallas , as a valley that once connected the Black Sea and the Caspian Sea, and subsequently was proposed as a natural boundary between continents. By the mid-19th century, there were three main conventions, one following the Don, the Volga–Don Canal and the Volga, the other following the Kuma–Manych Depression to the Caspian and then the Ural River, and the third abandoning

309-643: A Semitic term for west , this being either Akkadian erebu meaning 'to go down, set' (said of the sun) or Phoenician 'ereb 'evening, west', which is at the origin of Arabic maghreb and Hebrew ma'arav . Martin Litchfield West stated that "phonologically, the match between Europa's name and any form of the Semitic word is very poor", while Beekes considers a connection to Semitic languages improbable. Most major world languages use words derived from Eurṓpē or Europa to refer to

412-818: A boundary along the Terek and Kuban rivers, so southwards from the Kuma and the Manych, but still with the Caucasus entirely in Asia. However, most geographers in the Soviet Union favoured the boundary along the Caucasus crest, and this became the common convention in the later 20th century, although the Kuma–Manych boundary remained in use in some 20th-century maps. Some view the separation of Eurasia into Asia and Europe as

515-582: A common currency, the euro , and participate in the European single market and a customs union . A large bloc of countries, the Schengen Area , have also abolished internal border and immigration controls. Regular popular elections take place every five years within the EU; they are considered to be the second-largest democratic elections in the world after India's . The EU is the third-largest economy in

618-456: A desired location, or to generate new properties in the filler material which is confined within a nanometer-scale diameter. To this goal, non-carbon nanotube hybrids were made by filling WS 2 nanotubes with molten lead, antimony or bismuth iodide salt by a capillary wetting process, resulting in PbI 2 @WS 2 , SbI 3 @WS 2 or BiI 3 @WS 2 core–shell nanotubes. WS 2 can also exist in

721-406: A large land mass completely or almost completely surrounded by water at its borders. Prior to the adoption of the current convention that includes mountain divides, the border between Europe and Asia had been redefined several times since its first conception in classical antiquity , but always as a series of rivers, seas and straits that were believed to extend an unknown distance east and north from

824-442: A perfect cleavage of {010} and an iron black color. Wolframite in its crystalline form also displays lamellar and prismatic habit. The name "wolframite" is derived from German " wolf rahm ", the name given to tungsten by Johan Gottschalk Wallerius in 1747. This, in turn, derives from " Lupi spuma ", the name Georg Agricola used for the element in 1546, which translates into English as "wolf's froth" or "wolf's cream". The etymology

927-763: A precise eastern boundary of Europe arises in the Early Modern period, as the eastern extension of Muscovy began to include North Asia . Throughout the Middle Ages and into the 18th century, the traditional division of the landmass of Eurasia into two continents, Europe and Asia, followed Ptolemy, with the boundary following the Turkish Straits , the Black Sea , the Kerch Strait , the Sea of Azov and

1030-711: A residue of Eurocentrism : "In physical, cultural and historical diversity, China and India are comparable to the entire European landmass, not to a single European country. [...]." During the 2.5 million years of the Pleistocene , numerous cold phases called glacials ( Quaternary ice age ), or significant advances of continental ice sheets, in Europe and North America, occurred at intervals of approximately 40,000 to 100,000 years. The long glacial periods were separated by more temperate and shorter interglacials which lasted about 10,000–15,000 years. The last cold episode of

1133-685: A result, the Reconquista took the greater part of eight hundred years, in which period a long list of Alfonsos, Sanchos, Ordoños, Ramiros, Fernandos, and Bermudos would be fighting their Christian rivals as much as the Muslim invaders. During the Dark Ages, the Western Roman Empire fell under the control of various tribes. The Germanic and Slav tribes established their domains over Western and Eastern Europe, respectively. Eventually

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1236-423: A solid solution between the two endmembers. These two end members can be present in any proportion within wolframite, from 100% ferberite to 100% hübnerite. Wolframite Contains the following percentages of its components, 60.63% W, 9.21% Fe, 9.06% Mn, 21.10% O. Wolframite ore exhibits massive form with a dark grey to reddish black coloration. Wolframite in its pure crystal form exhibits a monoclinic crystal system with

1339-407: A thin sample of WS 2 in 1992. Bulk WS 2 forms dark gray hexagonal crystals with a layered structure. Like the closely related MoS 2 , it exhibits properties of a dry lubricant . Although it has long been thought that WS 2 is relatively stable in ambient air, recent reports on the ambient air oxidation of monolayer WS 2 have found this to not be the case. In the monolayer form, WS 2

1442-475: Is actively studied for potential applications, such as storage of hydrogen and lithium. WS 2 also catalyses hydrogenation of carbon dioxide : Tungsten disulfide is the first material which was found to form non-carbon nanotubes , in 1992. This ability is related to the layered structure of WS 2 , and macroscopic amounts of WS 2 have been produced by the methods mentioned above. WS 2 nanotubes have been investigated as reinforcing agents to improve

1545-628: Is affected by warm Atlantic currents, such as the Gulf Stream , which produce a temperate climate , tempering winters and summers, on much of the continent. Further from the sea, seasonal differences are more noticeable producing more continental climates . European culture consists of a range of national and regional cultures, which form the central roots of the wider Western civilisation , and together commonly reference ancient Greece and ancient Rome , particularly through their Christian successors , as crucial and shared roots. Beginning with

1648-401: Is also evidence that Homo sapiens arrived in Europe around 54,000 years ago, some 10,000 years earlier than previously thought. The earliest sites in Europe dated 48,000 years ago are Riparo Mochi (Italy), Geissenklösterle (Germany) and Isturitz (France). The European Neolithic period—marked by the cultivation of crops and the raising of livestock, increased numbers of settlements and

1751-648: Is an inorganic chemical compound composed of tungsten and sulfur with the chemical formula WS 2 . This compound is part of the group of materials called the transition metal dichalcogenides . It occurs naturally as the rare mineral tungstenite . This material is a component of certain catalysts used for hydrodesulfurization and hydrodenitrification . WS 2 adopts a layered structure similar, or isotypic with MoS 2 , instead with W atoms situated in trigonal prismatic coordination sphere (in place of Mo atoms). Owing to this layered structure, WS 2 forms non-carbon nanotubes , which were discovered after heating

1854-498: Is as a De-NO X catalyst which is used in the treatment of nitrogen oxide emissions to convert harmful nitrogen oxides into inert N 2 gas. Another modern day use of tungsten is as a lubricant. Tungsten disulfide (WS 2 ) is a lubricant with a dynamic coefficient of friction of ~0.03. Tungsten disulfide can be used at temperatures of 583 °C and 1316 °C in air and vacuum respectively. These characteristics allow this lubricant to operate in extreme conditions. Wolframite

1957-488: Is closest to Anatolia (or Asia Minor), but is considered part of Europe politically and it is a member state of the EU. Malta was considered an island of North-western Africa for centuries, but now it is considered to be part of Europe as well. "Europe", as used specifically in British English , may also refer to Continental Europe exclusively. The term "continent" usually implies the physical geography of

2060-442: Is converted rather rapidly (over the course of days in ambient light and atmosphere) to tungsten oxide via a photo-oxidation reaction involving visible wavelengths of light readily absorbed by monolayer WS 2 (< ~660 nm; > ~1.88 eV). In addition to light of suitable wavelength, the reaction likely requires both oxygen and water to proceed, with the water thought to act as a catalyst for oxidation. The products of

2163-510: Is deposited on a hydrophilic substrate, such as sapphire , and then coated with a polymer, such as polystyrene . After dipping the sample in water for a few minutes, the hydrophobic WS 2 film spontaneously peels off. WS 2 is used, in conjunction with other materials, as catalyst for hydrotreating of crude oil. In recent years it has also found applications as a saturable for passively mode locked fibre lasers resulting in femtosecond pulses being produced. Lamellar tungsten disulphide

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2266-571: Is dominated by China and Chinese exports. The next highest producers are Vietnam, Russia, Bolivia, and Rwanda with an estimated 4,800, 2,300, 1,400, and 1,100 respectively. As of 2022, the estimate world reserves of tungsten is 3,800,000 metric tons. Again China contains the greatest reserve at 1,800,000 metric tons of tungsten. The following countries have the next highest reserves: Russia, Vietnam, Spain, and Austria, with an estimated reserve of 400,000, 100,000, 56,000, and 10,000 respectively. Wolframite

2369-562: Is generally considered a transcontinental country divided entirely by water, while Russia and Kazakhstan are only partly divided by waterways. France, the Netherlands, Portugal and Spain are also transcontinental (or more properly, intercontinental, when oceans or large seas are involved) in that their main land areas are in Europe while pockets of their territories are located on other continents separated from Europe by large bodies of water. Spain, for example, has territories south of

2472-470: Is highly valued as the main source of the metal tungsten, a strong and very dense material with a high melting temperature used for electric filaments and armor-piercing ammunition , as well as hard tungsten carbide machine tools. During World War II , wolframite mines were a strategic asset, due to its use in munitions and tools. Tungsten salts were used in the 19th century to dye cotton and to make stage costumes which were fire retardant. Additionally in

2575-444: Is mainly formed through magmatic-hydrothermal processes associated with felsic magmas, namely skarns , or through metamorphic processes. In the more common granitic deposits, wolframite minerals can be found in both greisen and veins as its formation is tied to these two structures. The wolframite series consists of two endmembers, ferberite (Fe end member), hübnerite (Mn end member), with Wolframite, (Fe,Mn)WO 4 itself being

2678-473: Is not entirely certain but seems to be a reference to the large amounts of tin consumed by the mineral during its extraction, the phenomenon being likened to a wolf eating a sheep. Wolfram is the basis for the chemical symbol W for tungsten as a chemical element . As of 2022, estimated world mine production was 84,000 metric tons of tungsten. The foremost producer of tungsten is China, with an estimated 71,000 metric tons produced; as such world tungsten supply

2781-550: Is sometimes considered to mark the end of antiquity; alternatively antiquity is considered to end with the fall of the Western Roman Empire in 476 CE; the closure of the pagan Platonic Academy of Athens in 529 CE; or the rise of Islam in the early 7th century CE. During most of its existence, the Byzantine Empire was one of the most powerful economic, cultural, and military forces in Europe. During

2884-422: Is somewhat arbitrary and inconsistent compared to any clear-cut definition of the term "continent". The current division of Eurasia into two continents now reflects East-West cultural, linguistic and ethnic differences which vary on a spectrum rather than with a sharp dividing line. The geographic border between Europe and Asia does not follow any state boundaries and now only follows a few bodies of water. Turkey

2987-466: Is used as a dry lubricant for fasteners, bearings, and molds, as well as having significant use in aerospace and military industries. WS 2 can be applied to a metal surface without binders or curing, via high-velocity air impingement . The most recent official standard for this process is laid out in the SAE International specification AMS2530A. Like MoS 2 , nanostructured WS 2

3090-845: The Carolingian Renaissance of the 9th century. From that time, the term designated the sphere of influence of the Western Church , as opposed to both the Eastern Orthodox churches and to the Islamic world . A cultural definition of Europe as the lands of Latin Christendom coalesced in the 8th century, signifying the new cultural condominium created through the confluence of Germanic traditions and Christian-Latin culture, defined partly in contrast with Byzantium and Islam , and limited to northern Iberia ,

3193-517: The Don (ancient Tanais ). But maps produced during the 16th to 18th centuries tended to differ in how to continue the boundary beyond the Don bend at Kalach-na-Donu (where it is closest to the Volga, now joined with it by the Volga–Don Canal ), into territory not described in any detail by the ancient geographers. Around 1715, Herman Moll produced a map showing the northern part of the Ob River and

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3296-573: The European population at the time. The plague had a devastating effect on Europe's social structure; it induced people to live for the moment as illustrated by Giovanni Boccaccio in The Decameron (1353). It was a serious blow to the Roman Catholic Church and led to increased persecution of Jews , beggars and lepers . The plague is thought to have returned every generation with varying virulence and mortalities until

3399-512: The Greeks and Phoenicians gave rise to early Mediterranean cities. Early Iron Age Italy and Greece from around the 8th century BCE gradually gave rise to historical Classical antiquity, whose beginning is sometimes dated to 776 BCE, the year of the first Olympic Games . Ancient Greece was the founding culture of Western civilisation. Western democratic and rationalist culture are often attributed to Ancient Greece. The Greek city-state,

3502-636: The Inquisition against heretics. In the Iberian Peninsula , the Reconquista concluded with the fall of Granada in 1492 , ending over seven centuries of Islamic rule in the south-western peninsula. In the east, a resurgent Byzantine Empire recaptured Crete and Cyprus from the Muslims, and reconquered the Balkans. Constantinople was the largest and wealthiest city in Europe from the 9th to

3605-801: The Iron Curtain , with NATO in the West and the Warsaw Pact in the East . This divide ended with the Revolutions of 1989 , the fall of the Berlin Wall , and the dissolution of the Soviet Union , which allowed European integration to advance significantly. European integration is being advanced institutionally since 1948 with the founding of the Council of Europe , and significantly through

3708-733: The Irtysh River , a major tributary of the Ob, as components of a series of partly-joined waterways taking the boundary between Europe and Asia from the Turkish Straits, and the Don River all the way to the Arctic Ocean. In 1721, he produced a more up to date map that was easier to read. However, his proposal to adhere to major rivers as the line of demarcation was never taken up by other geographers who were beginning to move away from

3811-546: The Mediterranean Sea —namely, Ceuta and Melilla —which are parts of Africa and share a border with Morocco. According to the current convention, Georgia and Azerbaijan are transcontinental countries where waterways have been completely replaced by mountains as the divide between continents. The first recorded usage of Eurṓpē as a geographic term is in the Homeric Hymn to Delian Apollo , in reference to

3914-708: The Megalithic Temples of Malta and Stonehenge , were constructed throughout Western and Southern Europe. The modern native populations of Europe largely descend from three distinct lineages: Mesolithic hunter-gatherers , descended from populations associated with the Paleolithic Epigravettian culture; Neolithic Early European Farmers who migrated from Anatolia during the Neolithic Revolution 9,000 years ago; and Yamnaya Steppe herders who expanded into Europe from

4017-607: The Neandertal valley in Germany ) appeared in Europe 150,000 years ago (115,000 years ago it is found already in the territory of present-day Poland ) and disappeared from the fossil record about 40,000 years ago, with their final refuge being the Iberian Peninsula. The Neanderthals were supplanted by modern humans ( Cro-Magnons ), who seem to have appeared in Europe around 43,000 to 40,000 years ago. However, there

4120-655: The Pechenegs and the Cuman-Kipchaks , caused a massive migration of Slavic populations to the safer, heavily forested regions of the north, and temporarily halted the expansion of the Rus' state to the south and east. Like many other parts of Eurasia , these territories were overrun by the Mongols . The invaders, who became known as Tatars , were mostly Turkic-speaking peoples under Mongol suzerainty. They established

4223-693: The Pontic–Caspian steppe of Ukraine and southern Russia in the context of Indo-European migrations 5,000 years ago. The European Bronze Age began c. 3200 BCE in Greece with the Minoan civilisation on Crete , the first advanced civilisation in Europe. The Minoans were followed by the Myceneans , who collapsed suddenly around 1200 BCE, ushering the European Iron Age . Iron Age colonisation by

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4326-630: The Serbian Principality (later Kingdom and Empire ), and the Duchy of Croatia (later Kingdom of Croatia ). To the east, Kievan Rus' expanded from its capital in Kiev to become the largest state in Europe by the 10th century. In 988, Vladimir the Great adopted Orthodox Christianity as the religion of state. Further east, Volga Bulgaria became an Islamic state in the 10th century, but

4429-545: The decline of the Roman Empire , Europe entered a long period of change arising from what historians call the " Age of Migrations ". There were numerous invasions and migrations amongst the Ostrogoths , Visigoths , Goths , Vandals , Huns , Franks , Angles , Saxons , Slavs , Avars , Bulgars , Vikings , Pechenegs , Cumans , and Magyars . Renaissance thinkers such as Petrarch would later refer to this as

4532-635: The fall of the Western Roman Empire in 476 CE, Christian consolidation of Europe in the wake of the Migration Period marked the European post-classical Middle Ages . The Italian Renaissance spread in the continent a new humanist interest in art and science which led to the modern era . Since the Age of Discovery , led by Spain and Portugal , Europe played a predominant role in global affairs with multiple explorations and conquests around

4635-656: The last glacial period ended about 10,000 years ago. Earth is currently in an interglacial period of the Quaternary, called the Holocene . Homo erectus georgicus , which lived roughly 1.8 million years ago in Georgia , is the earliest hominin to have been discovered in Europe. Other hominin remains, dating back roughly 1 million years, have been discovered in Atapuerca , Spain . Neanderthal man (named after

4738-517: The polis , was the fundamental political unit of classical Greece. In 508 BCE, Cleisthenes instituted the world's first democratic system of government in Athens . The Greek political ideals were rediscovered in the late 18th century by European philosophers and idealists. Greece also generated many cultural contributions: in philosophy , humanism and rationalism under Aristotle , Socrates and Plato ; in history with Herodotus and Thucydides ; in dramatic and narrative verse, starting with

4841-402: The "Dark Ages". Isolated monastic communities were the only places to safeguard and compile written knowledge accumulated previously; apart from this, very few written records survive. Much literature, philosophy, mathematics, and other thinking from the classical period disappeared from Western Europe, though they were preserved in the east, in the Byzantine Empire. While the Roman empire in

4944-461: The 12th centuries, with a population of approximately 400,000. The Empire was weakened following the defeat at Manzikert , and was weakened considerably by the sack of Constantinople in 1204 , during the Fourth Crusade . Although it would recover Constantinople in 1261, Byzantium fell in 1453 when Constantinople was taken by the Ottoman Empire . In the 11th and 12th centuries, constant incursions by nomadic Turkic tribes, such as

5047-401: The 12th to the 15th centuries, the Grand Duchy of Moscow grew from a small principality under Mongol rule to the largest state in Europe, overthrowing the Mongols in 1480, and eventually becoming the Tsardom of Russia . The state was consolidated under Ivan III the Great and Ivan the Terrible , steadily expanding to the east and south over the next centuries. The Great Famine of 1315–1317

5150-487: The 14th and 16th centuries: it saw the flowering of art , philosophy , music , and the sciences , under the joint patronage of royalty , the nobility, the Roman Catholic Church and an emerging merchant class. Patrons in Italy, including the Medici family of Florentine bankers and the Popes in Rome , funded prolific quattrocento and cinquecento artists such as Raphael , Michelangelo and Leonardo da Vinci . Tungsten disulfide Tungsten disulfide

5253-444: The 18th century. During this period, more than 100 plague epidemics swept across Europe. The Renaissance was a period of cultural change originating in Florence , and later spreading to the rest of Europe. The rise of a new humanism was accompanied by the recovery of forgotten classical Greek and Arabic knowledge from monastic libraries, often translated from Arabic into Latin . The Renaissance spread across Europe between

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5356-516: The 19th century tungsten sulfides were sparingly used as lubrication for machining. Wolframite is also used to make tungstic acid which is used in the textile industry. A major modern day use of tungsten is as a catalyst for various chemical reactions. One such catalytic use of tungsten is as a hydrocracking catalyst which is used to improve the yield of organic components such as gasoline in hydrocarbon refinement as well as reducing harmful pollution and by products. Another catalytic use of tungsten

5459-400: The 50 years of peace that followed are known as Golden Age of Athens , the seminal period of ancient Greece that laid many of the foundations of Western civilisation. Greece was followed by Rome , which left its mark on law , politics , language , engineering , architecture , government , and many more key aspects in western civilisation. By 200 BCE, Rome had conquered Italy and over

5562-421: The British Isles, France, Christianised western Germany, the Alpine regions and northern and central Italy. The concept is one of the lasting legacies of the Carolingian Renaissance : Europa often figures in the letters of Charlemagne's court scholar, Alcuin . The transition of Europe to being a cultural term as well as a geographic one led to the borders of Europe being affected by cultural considerations in

5665-448: The Don altogether, following the Greater Caucasus watershed to the Caspian. The question was still treated as a "controversy" in geographical literature of the 1860s, with Douglas Freshfield advocating the Caucasus crest boundary as the "best possible", citing support from various "modern geographers". In Russia and the Soviet Union , the boundary along the Kuma–Manych Depression was the most commonly used as early as 1906. In 1958,

5768-427: The Early Middle Ages, and soon spread throughout Europe. A struggle for influence between the nobility and the monarchy in England led to the writing of Magna Carta and the establishment of a parliament . The primary source of culture in this period came from the Roman Catholic Church . Through monasteries and cathedral schools , the Church was responsible for education in much of Europe. The Papacy reached

5871-452: The East, especially relating to areas under Byzantine, Ottoman, and Russian influence. Such questions were affected by the positive connotations associated with the term Europe by its users. Such cultural considerations were not applied to the Americas, despite their conquest and settlement by European states. Instead, the concept of "Western civilization" emerged as a way of grouping together Europe and these colonies. The question of defining

5974-421: The Frankish tribes were united under Clovis I . Charlemagne , a Frankish king of the Carolingian dynasty who had conquered most of Western Europe, was anointed " Holy Roman Emperor " by the Pope in 800. This led in 962 to the founding of the Holy Roman Empire , which eventually became centred in the German principalities of central Europe. East Central Europe saw the creation of the first Slavic states and

6077-404: The Great 's efforts to make Russia more European, ignored the whole boundary question with his claim that neither Russia, Scandinavia, northern Germany, nor Poland were fully part of Europe. Since then, many modern analytical geographers like Halford Mackinder have declared that they see little validity in the Ural Mountains as a boundary between continents. The mapmakers continued to differ on

6180-427: The Levant and North Africa and making inroads into Asia Minor . In the mid-7th century, following the Muslim conquest of Persia , Islam penetrated into the Caucasus region. Over the next centuries Muslim forces took Cyprus , Malta , Crete , Sicily , and parts of southern Italy . Between 711 and 720, most of the lands of the Visigothic Kingdom of Iberia were brought under Muslim rule—save for small areas in

6283-414: The Mediterranean Sea without the inclusion of any mountain ranges. Cartographer Herman Moll suggested in 1715 Europe was bounded by a series of partly-joined waterways directed towards the Turkish straits, and the Irtysh River draining into the upper part of the Ob River and the Arctic Ocean . In contrast, the present eastern boundary of Europe partially adheres to the Ural and Caucasus Mountains, which

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6386-433: The Soviet Geographical Society formally recommended that the boundary between the Europe and Asia be drawn in textbooks from Baydaratskaya Bay , on the Kara Sea , along the eastern foot of Ural Mountains, then following the Ural River until the Mugodzhar Hills , and then the Emba River ; and Kuma–Manych Depression, thus placing the Caucasus entirely in Asia and the Urals entirely in Europe. The Flora Europaea adopted

6489-400: The Tanais (the modern Don River) as the boundary. The Roman Empire did not attach a strong identity to the concept of continental divisions. However, following the fall of the Western Roman Empire , the culture that developed in its place , linked to Latin and the Catholic church, began to associate itself with the concept of "Europe". The term "Europe" is first used for a cultural sphere in

6592-422: The adoption of Christianity ( c. 1000 CE) . The powerful West Slavic state of Great Moravia spread its territory all the way south to the Balkans, reaching its largest territorial extent under Svatopluk I and causing a series of armed conflicts with East Francia . Further south, the first South Slavic states emerged in the late 7th and 8th century and adopted Christianity : the First Bulgarian Empire ,

6695-411: The basis of many modern legal systems, funded the construction of the Hagia Sophia and brought the Christian church under state control. From the 7th century onwards, as the Byzantines and neighbouring Sasanid Persians were severely weakened due to the protracted, centuries-lasting and frequent Byzantine–Sasanian wars , the Muslim Arabs began to make inroads into historically Roman territory, taking

6798-435: The boundary between the lower Don and Samara well into the 19th century. The 1745 atlas published by the Russian Academy of Sciences has the boundary follow the Don beyond Kalach as far as Serafimovich before cutting north towards Arkhangelsk , while other 18th- to 19th-century mapmakers such as John Cary followed Strahlenberg's prescription. To the south, the Kuma–Manych Depression was identified c.  1773 by

6901-400: The continent The prevalent definition of Europe as a geographical term has been in use since the mid-19th century. Europe is taken to be bounded by large bodies of water to the north, west and south; Europe's limits to the east and north-east are usually taken to be the Ural Mountains , the Ural River , and the Caspian Sea ; to the south-east, the Caucasus Mountains , the Black Sea , and

7004-453: The continent. Chinese, for example, uses the word Ōuzhōu ( 歐洲 / 欧洲 ), which is an abbreviation of the transliterated name Ōuluóbā zhōu ( 歐羅巴洲 ) ( zhōu means "continent"); a similar Chinese-derived term Ōshū ( 欧州 ) is also sometimes used in Japanese such as in the Japanese name of the European Union, Ōshū Rengō ( 欧州連合 ) , despite the katakana Yōroppa ( ヨーロッパ ) being more commonly used. In some Turkic languages,

7107-424: The continents as the lands given by Noah to his three sons; Europe was defined as stretching from the Pillars of Hercules at the Strait of Gibraltar , separating it from Northwest Africa , to the Don, separating it from Asia. The convention received by the Middle Ages and surviving into modern usage is that of the Roman era used by Roman-era authors such as Posidonius , Strabo , and Ptolemy , who took

7210-402: The development of major commercial routes along the coast of the Mediterranean and Baltic Seas . The growing wealth and independence acquired by some coastal cities gave the Maritime Republics a leading role in the European scene. The Middle Ages on the mainland were dominated by the two upper echelons of the social structure: the nobility and the clergy. Feudalism developed in France in

7313-466: The end of the 18th century, gave rise to radical economic, cultural, and social change in Western Europe and eventually the wider world. Both world wars began and were fought to a great extent in Europe, contributing to a decline in Western European dominance in world affairs by the mid-20th century as the Soviet Union and the United States took prominence and competed over dominance in Europe and globally. The resulting Cold War divided Europe along

7416-590: The epic poems of Homer ; in drama with Sophocles and Euripides ; in medicine with Hippocrates and Galen ; and in science with Pythagoras , Euclid , and Archimedes . In the course of the 5th century BCE, several of the Greek city states would ultimately check the Achaemenid Persian advance in Europe through the Greco-Persian Wars , considered a pivotal moment in world history, as

7519-584: The following two centuries it conquered Greece , Hispania ( Spain and Portugal ), the North African coast, much of the Middle East , Gaul ( France and Belgium ), and Britannia ( England and Wales ). Expanding from their base in central Italy beginning in the third century BCE, the Romans gradually expanded to eventually rule the entire Mediterranean basin and Western Europe by the turn of

7622-440: The growth of monolayer WS 2 include chemical vapor deposition (CVD), physical vapor deposition (PVD) or metal organic chemical vapor deposition (MOCVD), though most current methods produce sulfur vacancy defects in excess of 1×10  cm . Other routes entail thermolysis of tungsten(VI) sulfides (e.g., (R 4 N) 2 WS 4 ) or the equivalent (e.g., WS 3 ). Freestanding WS 2 films can be produced as follows. WS 2

7725-651: The height of its power during the High Middle Ages. An East-West Schism in 1054 split the former Roman Empire religiously, with the Eastern Orthodox Church in the Byzantine Empire and the Roman Catholic Church in the former Western Roman Empire. In 1095 Pope Urban II called for a crusade against Muslims occupying Jerusalem and the Holy Land . In Europe itself, the Church organised

7828-509: The idea of water boundaries as the only legitimate divides between Europe and Asia. Four years later, in 1725, Philip Johan von Strahlenberg was the first to depart from the classical Don boundary. He drew a new line along the Volga , following the Volga north until the Samara Bend , along Obshchy Syrt (the drainage divide between the Volga and Ural Rivers ), then north and east along

7931-659: The latter waterway to its source in the Ural Mountains . At this point he proposed that mountain ranges could be included as boundaries between continents as alternatives to nearby waterways. Accordingly, he drew the new boundary north along Ural Mountains rather than the nearby and parallel running Ob and Irtysh rivers. This was endorsed by the Russian Empire and introduced the convention that would eventually become commonly accepted. However, this did not come without criticism. Voltaire , writing in 1760 about Peter

8034-658: The mechanical properties of polymeric nanocomposites. In a study, WS 2 nanotubes reinforced biodegradable polymeric nanocomposites of polypropylene fumarate (PPF) showed significant increases in the Young's modulus, compression yield strength, flexural modulus and flexural yield strength, compared to single- and multi-walled carbon nanotubes reinforced PPF nanocomposites, suggesting that WS 2 nanotubes may be better reinforcing agents than carbon nanotubes. The addition of WS 2 nanotubes to epoxy resin improved adhesion , fracture toughness and strain energy release rate. The wear of

8137-577: The millennium. The Roman Republic ended in 27 BCE, when Augustus proclaimed the Roman Empire . The two centuries that followed are known as the pax romana , a period of unprecedented peace, prosperity and political stability in most of Europe. The empire continued to expand under emperors such as Antoninus Pius and Marcus Aurelius , who spent time on the Empire's northern border fighting Germanic , Pictish and Scottish tribes. Christianity

8240-525: The nanotubes-reinforced epoxy is lower than that of pure epoxy. WS 2 nanotubes were embedded into a poly(methyl methacrylate) (PMMA) nanofiber matrix via electrospinning. The nanotubes were well dispersed and aligned along fiber axis. The enhanced stiffness and toughness of PMMA fiber meshes by means of non-carbon nanotubes addition may have potential uses as impact-absorbing materials, e.g. for ballistic vests . WS 2 nanotubes are hollow and can be filled with another material, to preserve or guide it to

8343-710: The northwest ( Asturias ) and largely Basque regions in the Pyrenees . This territory, under the Arabic name Al-Andalus , became part of the expanding Umayyad Caliphate . The unsuccessful second siege of Constantinople (717) weakened the Umayyad dynasty and reduced their prestige. The Umayyads were then defeated by the Frankish leader Charles Martel at the Battle of Poitiers in 732, which ended their northward advance. In

8446-483: The originally Persian name Frangistan ("land of the Franks ") is used casually in referring to much of Europe, besides official names such as Avrupa or Evropa . Clickable map of Europe, showing one of the most commonly used continental boundaries Key: blue : states which straddle the border between Europe and Asia ; green : countries not geographically in Europe, but closely associated with

8549-444: The poetry devoted to it. An alternative view is that of Robert Beekes , who has argued in favour of a pre-Indo-European origin for the name, explaining that a derivation from eurus would yield a different toponym than Europa. Beekes has located toponyms related to that of Europa in the territory of ancient Greece, and localities such as that of Europos in ancient Macedonia . There have been attempts to connect Eurṓpē to

8652-576: The reaction likely include various tungsten oxide species and sulfuric acid . The oxidation of other semiconductor transition metal dichalcogenides (S-TMDs) such as MoS 2 , has similarly been observed to occur in ambient light and atmospheric conditions. WS 2 is also attacked by a mixture of nitric and hydrofluoric acid . When heated in oxygen-containing atmosphere, WS 2 converts to tungsten trioxide . When heated in absence of oxygen, WS 2 does not melt but decomposes to tungsten and sulfur, but only at 1250 °C. Historically monolayer WS 2

8755-543: The realisation of the European Union (EU), which represents today the majority of Europe. The European Union is a supranational political entity that lies between a confederation and a federation and is based on a system of European treaties . The EU originated in Western Europe but has been expanding eastward since the dissolution of the Soviet Union in 1991. A majority of its members have adopted

8858-564: The remote regions of north-western Iberia and the middle Pyrenees the power of the Muslims in the south was scarcely felt. It was here that the foundations of the Christian kingdoms of Asturias , Leon , and Galicia were laid and from where the reconquest of the Iberian Peninsula would start. However, no coordinated attempt would be made to drive the Moors out. The Christian kingdoms were mainly focused on their own internal power struggles. As

8961-425: The second-smallest continent (using the seven-continent model ). Politically, Europe is divided into about fifty sovereign states , of which Russia is the largest and most populous , spanning 39% of the continent and comprising 15% of its population. Europe had a total population of about 745 million (about 10% of the world population ) in 2021; the third-largest after Asia and Africa. The European climate

9064-752: The south, and Asia to the east. Europe shares the landmass of Eurasia with Asia, and of Afro-Eurasia with both Asia and Africa . Europe is commonly considered to be separated from Asia by the watershed of the Ural Mountains , the Ural River , the Caspian Sea , the Greater Caucasus , the Black Sea , and the waterway of the Bosporus Strait . Europe covers about 10.18 million km (3.93 million sq mi), or 2% of Earth's surface (6.8% of land area), making it

9167-535: The state of the Golden Horde with headquarters in Crimea, which later adopted Islam as a religion, and ruled over modern-day southern and central Russia for more than three centuries. After the collapse of Mongol dominions, the first Romanian states (principalities) emerged in the 14th century: Moldavia and Walachia . Previously, these territories were under the successive control of Pechenegs and Cumans. From

9270-407: The waterways connecting the Black Sea to the Mediterranean Sea . Islands are generally grouped with the nearest continental landmass, hence Iceland is considered to be part of Europe, while the nearby island of Greenland is usually assigned to North America , although politically belonging to Denmark. Nevertheless, there are some exceptions based on sociopolitical and cultural differences. Cyprus

9373-562: The west and the north, transmitting newly acquired skills in producing copper artifacts. In Western Europe the Neolithic period was characterised not by large agricultural settlements but by field monuments, such as causewayed enclosures , burial mounds and megalithic tombs . The Corded Ware cultural horizon flourished at the transition from the Neolithic to the Chalcolithic . During this period giant megalithic monuments, such as

9476-535: The west continued to decline, Roman traditions and the Roman state remained strong in the predominantly Greek-speaking Eastern Roman Empire , also known as the Byzantine Empire . During most of its existence, the Byzantine Empire was the most powerful economic, cultural, and military force in Europe. Emperor Justinian I presided over Constantinople's first golden age: he established a legal code that forms

9579-518: The western shore of the Aegean Sea . As a name for a part of the known world, it is first used in the 6th century BCE by Anaximander and Hecataeus . Anaximander placed the boundary between Asia and Europe along the Phasis River (the modern Rioni River on the territory of Georgia ) in the Caucasus, a convention still followed by Herodotus in the 5th century BCE. Herodotus mentioned that

9682-801: The widespread use of pottery—began around 7000 BCE in Greece and the Balkans , probably influenced by earlier farming practices in Anatolia and the Near East . It spread from the Balkans along the valleys of the Danube and the Rhine ( Linear Pottery culture ), and along the Mediterranean coast ( Cardial culture ). Between 4500 and 3000 BCE, these central European neolithic cultures developed further to

9785-627: The world had been divided by unknown persons into three parts—Europe, Asia, and Libya (Africa)—with the Nile and the Phasis forming their boundaries—though he also states that some considered the River Don , rather than the Phasis, as the boundary between Europe and Asia. Europe's eastern frontier was defined in the 1st century by geographer Strabo at the River Don. The Book of Jubilees described

9888-410: The world. The place name Evros was first used by the ancient Greeks to refer to their northernmost province, which bears the same name today. The principal river there – Evros (today's Maritsa ) – flows through the fertile valleys of Thrace , which itself was also called Europe, before the term meant the continent. In classical Greek mythology , Europa ( Ancient Greek : Εὐρώπη , Eurṓpē )

9991-700: The world. Between the 16th and 20th centuries, European powers colonised at various times the Americas , almost all of Africa and Oceania , and the majority of Asia. The Age of Enlightenment , the French Revolution , and the Napoleonic Wars shaped the continent culturally, politically, and economically from the end of the 17th century until the first half of the 19th century. The Industrial Revolution , which began in Great Britain at

10094-422: Was legalised by Constantine I in 313 CE after three centuries of imperial persecution . Constantine also permanently moved the capital of the empire from Rome to the city of Byzantium (modern-day Istanbul ) which was renamed Constantinople in his honour in 330 CE. Christianity became the sole official religion of the empire in 380 CE, and in 391–392 CE the emperor Theodosius outlawed pagan religions. This

10197-461: Was a Phoenician princess. One view is that her name derives from the Ancient Greek elements εὐρύς ( eurús ) 'wide, broad', and ὤψ ( ōps , gen. ὠπός , ōpós ) 'eye, face, countenance', hence their composite Eurṓpē would mean 'wide-gazing' or 'broad of aspect'. Broad has been an epithet of Earth herself in the reconstructed Proto-Indo-European religion and

10300-726: Was considered to be a conflict mineral due to the unethical mining practices observed in the Democratic Republic of the Congo , during the Congo Wars . Europe Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere . It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to

10403-619: Was eventually absorbed into Russia several centuries later. The period between the year 1000 and 1250 is known as the High Middle Ages , followed by the Late Middle Ages until c. 1500. During the High Middle Ages the population of Europe experienced significant growth, culminating in the Renaissance of the 12th century . Economic growth, together with the lack of safety on the mainland trading routes, made possible

10506-577: Was isolated using chemical exfoliation via intercalation with lithium from n-butyl lithium (in hexane), followed by exfoliation of the Li intercalated compound by sonication in water. WS 2 also undergoes exfoliation by treatment with various reagents such as chlorosulfonic acid and the lithium halides. WS 2 is produced by a number of methods. Many of these methods involve treating oxides with sources of sulfide or hydrosulfide, supplied as hydrogen sulfide or generated in situ . Widely used techniques for

10609-554: Was the first crisis that would strike Europe in the late Middle Ages. The period between 1348 and 1420 witnessed the heaviest loss. The population of France was reduced by half. Medieval Britain was afflicted by 95 famines, and France suffered the effects of 75 or more in the same period. Europe was devastated in the mid-14th century by the Black Death , one of the most deadly pandemics in human history which killed an estimated 25 million people in Europe alone—a third of

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