In chemistry , a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood.
36-591: Tavurvur is an active stratovolcano near Rabaul , on the island of New Britain , in Papua New Guinea. It is a sub-vent of the Rabaul caldera and lies on the eastern rim of the larger feature. An eruption of the volcano largely destroyed the nearby town of Rabaul in 1994. Mount Tavurvur is the most active volcano in Rabaul caldera, and erupted most recently on 29 August 2014. The correct pronunciation of
72-506: A monohydrate n = 1, and in a hexahydrate n = 6. Numerical prefixes mostly of Greek origin are: A hydrate that has lost water is referred to as an anhydride ; the remaining water, if any exists, can only be removed with very strong heating. A substance that does not contain any water is referred to as anhydrous . Some anhydrous compounds are hydrated so easily that they are said to be hygroscopic and are used as drying agents or desiccants . In organic chemistry,
108-747: A 4-inch thick ash layer can weigh 120-200 pounds and can get twice as heavy when wet. Wet ash also poses a risk to electronics due to its conductive nature. Dense clouds of hot volcanic ash can be expelled due to the collapse of an eruptive column , or laterally due to the partial collapse of a volcanic edifice or lava dome during explosive eruptions . These clouds are known as pyroclastic surges and in addition to ash , they contain hot lava , pumice , rock , and volcanic gas . Pyroclastic surges flow at speeds over 50 mph and are at temperatures between 200 °C – 700 °C. These surges can cause major damage to property and people in their path. Lava flows from stratovolcanoes are generally not
144-418: A definite ratio as an integral part of the crystal " that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain water of crystallization or water of hydration . If the water is heavy water in which the constituent hydrogen is the isotope deuterium , then the term deuterate may be used in place of hydrate . A colorful example
180-443: A dihydrate (melting point 97 °C). Protein crystals commonly have as much as 50% water content. Molecules are also labeled as hydrates for historical reasons not covered above. Glucose , C 6 H 12 O 6 , was originally thought of as C 6 (H 2 O) 6 and described as a carbohydrate . Hydrate formation is common for active ingredients . Many manufacturing processes provide an opportunity for hydrates to form and
216-479: A fast moving mudflow . Lahars are typically about 60% sediment and 40% water. Depending on the abundance of volcanic debris the lahar can be fluid or thick like concrete. Lahars have the strength and speed to flatten structures and cause great bodily harm, gaining speeds up to dozens of kilometers per hour. In the 1985 eruption of Nevado del Ruiz in Colombia , Pyroclastic surges melted snow and ice atop
252-515: A final intermediate composition . When the magma nears the top surface, it pools in a magma chamber within the crust below the stratovolcano. The processes that trigger the final eruption remain a question for further research. Possible mechanisms include: These internal triggers may be modified by external triggers such as sector collapse , earthquakes , or interactions with groundwater . Some of these triggers operate only under limited conditions. For example, sector collapse (where part of
288-433: A hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by the addition of H to one C and OH to the other C, and so can be considered as the hydrate of ethene. A molecule of water may be eliminated, for example, by
324-769: A result of intraplate volcanism on oceanic islands far from plate boundaries. Examples are Teide in the Canary Islands , and Pico do Fogo in Cape Verde . Stratovolcanoes in the East African Rift include Ol Doinyo Lengai in Tanzania, and Longonot in Kenya. Subduction zone volcanoes form when hydrous minerals are pulled down into the mantle on the slab. These hydrous minerals, such as chlorite and serpentine , release their water into
360-461: A significant threat to humans or animals because the highly viscous lava moves slowly enough for everyone to evacuate. Most deaths attributed to lava are due to related causes such as explosions and asphyxiation from toxic gas . Lava flows can bury homes and farms in thick volcanic rock which greatly reduces property value. However, not all stratovolcanoes erupt viscous and sticky lava . Nyiragongo , near Lake Kivu in central Africa ,
396-438: Is methane hydrate (also known as gas hydrate, methane clathrate, etc.). Nonpolar molecules such as methane can form clathrate hydrates with water, especially under high pressure. Although there is no hydrogen bonding between water and guest molecules when methane is the guest molecule of the clathrate, guest–host hydrogen bonding often forms when the guest is a larger organic molecule such as tetrahydrofuran . In such cases
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#1732773029010432-407: Is cobalt(II) chloride , which turns from blue to red upon hydration , and can therefore be used as a water indicator. The notation " hydrated compound ⋅ n H 2 O ", where n is the number of water molecules per formula unit of the salt, is commonly used to show that a salt is hydrated. The n is usually a low integer , though it is possible for fractional values to occur. For example, in
468-531: Is a passive release of gas during periods of dormancy. As per the above examples, while eruptions like Mount Unzen have caused deaths and local damage, the impact of the June 1991 eruption of Mount Pinatubo was seen globally. The eruptive columns reached heights of 40 km and dumped 17 megatons of SO 2 into the lower stratosphere . The aerosols that formed from the sulfur dioxide (SO 2 ), carbon dioxide (CO 2 ), and other gases dispersed around
504-476: Is often felsic , having high to intermediate levels of silica (as in rhyolite , dacite , or andesite ), with lesser amounts of less viscous mafic magma . Extensive felsic lava flows are uncommon, but can travel as far as 8 km (5 mi). The term composite volcano is used because the strata are usually mixed and uneven instead of neat layers. They are among the most common types of volcanoes; more than 700 stratovolcanoes have erupted lava during
540-451: Is the most famous example of a hazardous stratovolcano eruption. It completely smothered the nearby ancient cities of Pompeii and Herculaneum with thick deposits of pyroclastic surges and pumice ranging from 6–7 meters deep. Pompeii had 10,000-20,000 inhabitants at the time of eruption. Mount Vesuvius is recognized as one of the most dangerous of the world's volcanoes, due to its capacity for powerful explosive eruptions coupled with
576-450: Is typically between 700 and 1,200 °C (1,300-2,200 °F). Volcanic bombs are masses of unconsolidated rock and lava that are ejected during an eruption. Volcanic bombs are classified as larger than 64mm (2.5 inches). Anything below 64mm is classified as a volcanic block . When erupted Bombs are still molten and partially cool and solidify on their descent. They can form ribbon or oval shapes that can also flatten on impact with
612-403: Is very dangerous because its magma has an unusually low silica content , making it much less viscous than other stratovolcanoes. Low viscosity lava can generate massive lava fountains , while lava of thicker viscosity can solidify within the vent, creating a volcanic plug . Volcanic plugs can trap gas and create pressure in the magma chamber, resulting in violent eruptions. Lava
648-824: The Holocene Epoch (the last 11,700 years), and many older, now extinct, stratovolcanoes erupted lava as far back as Archean times. Stratovolcanoes are typically found in subduction zones but they also occur in other geological settings. Two examples of stratovolcanoes famous for catastrophic eruptions are Krakatoa in Indonesia (which erupted in 1883 claiming 36,000 lives) and Mount Vesuvius in Italy (which erupted in 79 A.D killing an estimated 2,000 people). In modern times, Mount St. Helens (1980) in Washington State , US, and Mount Pinatubo (1991) in
684-579: The Philippines have erupted catastrophically, but with fewer deaths. Stratovolcanoes are common at subduction zones , forming chains and clusters along plate tectonic boundaries where an oceanic crust plate is drawn under a continental crust plate (continental arc volcanism, e.g. Cascade Range , Andes , Campania ) or another oceanic crust plate ( island arc volcanism, e.g. Japan , Philippines , Aleutian Islands ). Stratovolcanoes also occur in some other geological settings, for example as
720-891: The magma is too viscous to allow easy escape of volcanic gases . As a consequence, the tremendous internal pressures of the trapped volcanic gases remain and intermingle in the pasty magma . Following the breaching of the vent and the opening of the crater, the magma degasses explosively. The magma and gases blast out with high speed and full force. Since 1600 CE , nearly 300,000 people have been killed by volcanic eruptions . Most deaths were caused by pyroclastic flows and lahars , deadly hazards that often accompany explosive eruptions of subduction-zone stratovolcanoes. Pyroclastic flows are swift, avalanche-like, ground-sweeping, incandescent mixtures of hot volcanic debris, fine ash , fragmented lava , and superheated gases that can travel at speeds over 150 km/h (90 mph). Around 30,000 people were killed by pyroclastic flows during
756-443: The mantle which decreases its melting point by 60 to 100 °C. The release of water from hydrated minerals is termed " dewatering ", and occurs at specific pressures and temperatures for each mineral, as the plate descends to greater depths. This allows the mantle to partially melt and generate magma . This is called flux melting . The magma then rises through the crust , incorporating silica-rich crustal rock, leading to
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#1732773029010792-616: The 1902 eruption of Mount Pelée on the island of Martinique in the Caribbean . During March and April 1982, El Chichón in the State of Chiapas in southeastern Mexico , erupted 3 times, causing the worst volcanic disaster in that country's history and killied more than 2,000 people in pyroclastic flows . Two Decade Volcanoes that erupted in 1991 provide examples of stratovolcano hazards. On 15 June, Mount Pinatubo erupted and caused an ash cloud to shoot 40 km (25 mi) into
828-485: The 1982 eruption of Galunggung in Java , British Airways Flight 9 flew into the ash cloud, causing it to sustain temporary engine failure and structural damage. Although no crashes have happened due to ash, more than 60, mostly commercial aircraft , have been damaged. Some of these incidents resulted in emergency landings. Ashfalls are a threat to health when inhaled and are also a threat to property. A square yard of
864-585: The 5,321 m (17,457 ft) high Andean volcano. The ensuing lahar killed 25,000 people and flooded the city of Armero and nearby settlements. As a volcano forms, several different gases mix with magma in the volcanic chamber. During an eruption the gases are then released into the atmosphere which can lead to toxic human exposure. The most abundant of these gases is H 2 O ( water ) followed by CO 2 ( carbon dioxide ), SO 2 ( sulfur dioxide ), H 2 S ( hydrogen sulfide ), and HF ( hydrogen fluoride ). If at concentrations of more than 3% in
900-486: The action of sulfuric acid . Another example is chloral hydrate , CCl 3 −CH(OH) 2 , which can be formed by reaction of water with chloral , CCl 3 −CH=O . Many organic molecules, as well as inorganic molecules, form crystals that incorporate water into the crystalline structure without chemical alteration of the organic molecule ( water of crystallization ). The sugar trehalose , for example, exists in both an anhydrous form ( melting point 203 °C) and as
936-819: The air, when breathed in CO 2 can cause dizziness and difficulty breathing. At more than 15% concentration CO 2 causes death. CO 2 can settle into depressions in the land, leading to deadly, odorless pockets of gas. SO 2 classified as a respiratory, skin, and eye irritant if come into contact with. It is known for its pungent egg smell and role in ozone depletion and has the potential to cause acid rain downwind of an eruption. H 2 S has an even stronger odor than SO 2 as well as being even more toxic. Exposure for less than an hour at concentrations of over 500 ppm causes death. HF and similar species can coat ash particles and once deposited can poison soil and water. Gases are also emitted during volcanic degassing, which
972-748: The air. It produced large pyroclastic surges and lahar floods that caused a lot of damage to the surrounding area. Pinatubo , located in Central Luzon just 90 km (56 mi) west-northwest of Manila , had been dormant for six centuries before the 1991 eruption. This eruption was one of the 2nd largest in the 20th century. It produced a large volcanic ash cloud that affected global temperatures, lowering them in areas as much as .5 °C. The volcanic ash cloud consisted of 22 million tons of SO 2 which combined with water droplets to create sulfuric acid . In 1991 Japan's Unzen Volcano also erupted, after 200 years of inactivity. It's located on
1008-540: The flank of a volcano collapses in a massive landslide) can only trigger the eruption of a very shallow magma chamber . Magma differentiation and thermal expansion also are ineffective as triggers for eruptions from deep magma chambers . In recorded history , explosive eruptions at subduction zone ( convergent-boundary ) volcanoes have posed the greatest hazard to civilizations. Subduction-zone stratovolcanoes, such as Mount St. Helens , Mount Etna and Mount Pinatubo , typically erupt with explosive force because
1044-478: The ground. Volcanic Bombs are associated with Strombolian and Vulcanian eruptions and basaltic lava . Ejection velocities ranging from 200 to 400 m/s have been recorded causing volcanic bombs to be destructive. Lahars (from a Javanese term for volcanic mudflows) are a mixture of volcanic debris and water. Lahars can result from heavy rainfall during or before the eruption or interaction with ice and snow. Meltwater mixes with volcanic debris causing
1080-458: The high population density of the surrounding Metropolitan Naples area (totaling about 3.6 million inhabitants). In addition to potentially affecting the climate, volcanic ash clouds from explosive eruptions pose a serious hazard to aviation . Volcanic ash clouds consist of ash which is made of silt or sand sized pieces of rock, mineral, volcanic glass . Ash grains are jagged, abrasive, and don't dissolve in water. For example, during
1116-504: The island of Kyushu about 40 km (25 mi) east of Nagasaki . Beginning in June, a newly formed lava dome repeatedly collapsed. This generated a pyroclastic flow that flowed down the mountain's slopes at speeds as high as 200 km/h (120 mph). The 1991 eruption of Mount Unzen was one of the worst volcanic disasters in Japan's history, once killing more than 15,000 people in 1792. The eruption of Mount Vesuvius in 79 AD
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1152-464: The size of Mount Pinatubo affected the weather for a few years; with warmer winters and cooler summers observed. A similar phenomenon occurred in the April 1815, the eruption of Mount Tambora on Sumbawa island in Indonesia . The Mount Tambora eruption is recognized as the most powerful eruption in recorded history. Its eruption cloud lowered global temperatures as much as 0.4 to 0.7 °C. In
1188-412: The state of hydration can be changed with environmental humidity and time. The state of hydration of an active pharmaceutical ingredient can significantly affect the solubility and dissolution rate and therefore its bioavailability . Clathrate hydrates (also known as gas hydrates, gas clathrates, etc.) are water ice with gas molecules trapped within; they are a form of clathrate . An important example
1224-695: The volcano's name is tah-VOOR-voor, according to the Rabaul Volcanological Observatory. Stratovolcano A stratovolcano , also known as a composite volcano , is a conical volcano built up by many alternating layers ( strata ) of hardened lava and tephra . Unlike shield volcanoes , stratovolcanoes are characterized by a steep profile with a summit crater and explosive eruptions. Some have collapsed summit craters called calderas . The lava flowing from stratovolcanoes typically cools and solidifies before spreading far, due to high viscosity . The magma forming this lava
1260-412: The world. The SO 2 in this cloud combined with water (both of volcanic and atmospheric origin) and formed sulfuric acid , blocking a portion of the sunlight from reaching the troposphere . This caused the global temperature to decrease by about 0.4 °C (0.72 °F) from 1992 to 1993. These aerosols caused the ozone layer to reach the lowest concentrations recorded at that time. An eruption
1296-494: The year following the eruption, most of the Northern Hemisphere experienced cooler temperatures during the summer. In the northern hemisphere , 1816 was known as the " Year Without a Summer ". The eruption caused crop failures, food shortages, and floods that killed over 100,000 people across Europe , Asia , and North America . Hydrous Hydrates are inorganic salts "containing water molecules combined in
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