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123-534: The B-35 was the brainchild of Jack Northrop , who made the flying wing the focus of his work during the 1930s. In 1941 before the USA entered World War II, Northrop and Consolidated Vultee Corporation had been commissioned to develop a large wing-only, long-range bomber designated XB-35 and XB-36. Northrop advocated a "flying wing" as a means of reducing parasitic drag and eliminating structural weight not directly responsible for producing lift. Consolidated Vultee proposed

246-491: A precipitate of aluminium hydroxide , Al(OH) 3 , forms. This is useful for clarification of water, as the precipitate nucleates on suspended particles in the water, hence removing them. Increasing the pH even further leads to the hydroxide dissolving again as aluminate , [Al(H 2 O) 2 (OH) 4 ] , is formed. Aluminium hydroxide forms both salts and aluminates and dissolves in acid and alkali, as well as on fusion with acidic and basic oxides. This behavior of Al(OH) 3

369-509: A rudder for lateral control, so a set of clamshell-like, double split flaps (so-called flaperon , a portmanteau of flap and aileron) on the trailing edge of the wingtips were used. When aileron control was input, they were deflected up or down as a single unit, just like an aileron. When rudder input was made, the two surfaces on one side opened, top and bottom, creating drag, and yawing the aircraft. By applying input to both rudder pedals, both sets of surfaces were deployed creating drag so that

492-525: A "less classical sound". This name persisted: although the -um spelling was occasionally used in Britain, the American scientific language used -ium from the start. Most scientists throughout the world used -ium in the 19th century; and it was entrenched in several other European languages, such as French , German , and Dutch . In 1828, an American lexicographer, Noah Webster , entered only

615-499: A Swedish chemist, Jöns Jacob Berzelius , in which the name aluminium is given to the element that would be synthesized from alum. (Another article in the same journal issue also refers to the metal whose oxide is the basis of sapphire , i.e. the same metal, as to aluminium .) A January 1811 summary of one of Davy's lectures at the Royal Society mentioned the name aluminium as a possibility. The next year, Davy published

738-472: A YB-49 all-jet airframe crashed after Air Force test pilot Forbes pulled the outer wing panels off during stall tests at 4.8  g 0 (47  m/s ). The first YB-35 airframe jet-modified to a YB-49 completed all stall tests and even demonstrated recovery from a spin. It was later destroyed after the Flying Wing's forward landing gear strut and wheel collapsed after encountering high vibration during

861-561: A chemistry textbook in which he used the spelling aluminum . Both spellings have coexisted since. Their usage is currently regional: aluminum dominates in the United States and Canada; aluminium is prevalent in the rest of the English-speaking world. In 1812, British scientist Thomas Young wrote an anonymous review of Davy's book, in which he proposed the name aluminium instead of aluminum , which he thought had

984-674: A confusion of rank and job changes, eventually cancelled the XB-35 project, while continuing testing the B-35 airframe as the YB-49, even ordering 30 of the jet-powered bombers after the first YB-49 crashed. The first and second XB-35s were scrapped on 23 and 19 August 1949, respectively. On 30 September 1943, 13 pre-production YB-35s were ordered by the Army Air Force. The first one did not fly until 15 May 1948. While some Air Force generals felt

1107-491: A highly unusual taxi test procedure made with the engine's fuel tanks full, causing a fire that spread rapidly. Seven incomplete airframes began conversion to jet power as YB-49B but were never finished. A third YB-35 airframe was converted to use six jet engines (two placed in under wing pods) for use as a long-range reconnaissance aircraft, designated YRB-49A . After only a few months, the Air Force's order for 30 YRB-49As

1230-518: A more conventional design with fuselage and tail, which was much larger and heavier. In theory, the B-35 could carry a greater payload faster, farther, and cheaper than a conventional bomber. In December 1941, the Army Air Forces awarded prototype contracts to both Northrop and Consolidated Vultee for a bomber that could carry 4,500 kg (10,000 lb) of bombs to a round-trip mission of 16,000 km (10,000 mi). Requested performance

1353-406: A new aluminum alloy devised by Alcoa ; it was considerably stronger than any alloy used previously. In June 1946, the XB-35 made its first flight, a 45-minute trip from Hawthorne, California , to Muroc Dry Lake, without incident. The XB-35's engines and propellers were AAF property and had not been tested for engine-propeller compatibility by either Pratt & Whitney, Hamilton Standard, or by

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1476-441: A probable cause for it being soft with a low melting point and low electrical resistivity . Aluminium metal has an appearance ranging from silvery white to dull gray depending on its surface roughness . Aluminium mirrors are the most reflective of all metal mirrors for near ultraviolet and far infrared light. It is also one of the most reflective for light in the visible spectrum, nearly on par with silver in this respect, and

1599-683: A process termed passivation . Because of its general resistance to corrosion, aluminium is one of the few metals that retains silvery reflectance in finely powdered form, making it an important component of silver-colored paints. Aluminium is not attacked by oxidizing acids because of its passivation. This allows aluminium to be used to store reagents such as nitric acid , concentrated sulfuric acid , and some organic acids. In hot concentrated hydrochloric acid , aluminium reacts with water with evolution of hydrogen, and in aqueous sodium hydroxide or potassium hydroxide at room temperature to form aluminates —protective passivation under these conditions

1722-487: A reduced-scale version tested in 1940, ultimately became the giant Northrop YB-35 . The Northrop XP-56 Black Bullet , a welded magnesium fighter was one of the more significant of his World War II designs, along with the Northrop P-61 Black Widow , the first American night interceptor, of which more than 700 were constructed. His inventions continued into the postwar era of jet aircraft, to produce

1845-525: A refractory material, and in ceramics , as well as being the starting material for the electrolytic production of aluminium. Sapphire and ruby are impure corundum contaminated with trace amounts of other metals. The two main oxide-hydroxides, AlO(OH), are boehmite and diaspore . There are three main trihydroxides: bayerite , gibbsite , and nordstrandite , which differ in their crystalline structure ( polymorphs ). Many other intermediate and related structures are also known. Most are produced from ores by

1968-474: A stable noble gas configuration. Accordingly, the combined first three ionization energies of aluminium are far lower than the fourth ionization energy alone. Such an electron configuration is shared with the other well-characterized members of its group, boron , gallium , indium , and thallium ; it is also expected for nihonium . Aluminium can surrender its three outermost electrons in many chemical reactions (see below ). The electronegativity of aluminium

2091-820: A variety of wet processes using acid and base. Heating the hydroxides leads to formation of corundum. These materials are of central importance to the production of aluminium and are themselves extremely useful. Some mixed oxide phases are also very useful, such as spinel (MgAl 2 O 4 ), Na-β-alumina (NaAl 11 O 17 ), and tricalcium aluminate (Ca 3 Al 2 O 6 , an important mineral phase in Portland cement ). The only stable chalcogenides under normal conditions are aluminium sulfide (Al 2 S 3 ), selenide (Al 2 Se 3 ), and telluride (Al 2 Te 3 ). All three are prepared by direct reaction of their elements at about 1,000 °C (1,800 °F) and quickly hydrolyze completely in water to yield aluminium hydroxide and

2214-575: A way of purifying bauxite to yield alumina, now known as the Bayer process , in 1889. Modern production of aluminium is based on the Bayer and Hall–Héroult processes. As large-scale production caused aluminium prices to drop, the metal became widely used in jewelry, eyeglass frames, optical instruments, tableware, and foil , and other everyday items in the 1890s and early 20th century. Aluminium's ability to form hard yet light alloys with other metals provided

2337-434: Is Al. Al was present in the early Solar System with abundance of 0.005% relative to Al but its half-life of 728,000 years is too short for any original nuclei to survive; Al is therefore extinct . Unlike for Al, hydrogen burning is the primary source of Al, with the nuclide emerging after a nucleus of Mg catches a free proton. However, the trace quantities of Al that do exist are the most common gamma ray emitter in

2460-407: Is paramagnetic and thus essentially unaffected by static magnetic fields. The high electrical conductivity, however, means that it is strongly affected by alternating magnetic fields through the induction of eddy currents . Aluminium combines characteristics of pre- and post-transition metals. Since it has few available electrons for metallic bonding, like its heavier group 13 congeners, it has

2583-429: Is small and highly charged ; as such, it has more polarizing power , and bonds formed by aluminium have a more covalent character. The strong affinity of aluminium for oxygen leads to the common occurrence of its oxides in nature. Aluminium is found on Earth primarily in rocks in the crust , where it is the third-most abundant element , after oxygen and silicon , rather than in the mantle , and virtually never as

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2706-483: Is 1.61 (Pauling scale). A free aluminium atom has a radius of 143  pm . With the three outermost electrons removed, the radius shrinks to 39 pm for a 4-coordinated atom or 53.5 pm for a 6-coordinated atom. At standard temperature and pressure , aluminium atoms (when not affected by atoms of other elements) form a face-centered cubic crystal system bound by metallic bonding provided by atoms' outermost electrons; hence aluminium (at these conditions)

2829-548: Is a metal. This crystal system is shared by many other metals, such as lead and copper ; the size of a unit cell of aluminium is comparable to that of those other metals. The system, however, is not shared by the other members of its group: boron has ionization energies too high to allow metallization, thallium has a hexagonal close-packed structure, and gallium and indium have unusual structures that are not close-packed like those of aluminium and thallium. The few electrons that are available for metallic bonding in aluminium are

2952-522: Is almost never found in the elemental state; instead it is found in oxides or silicates. Feldspars , the most common group of minerals in the Earth's crust, are aluminosilicates. Aluminium also occurs in the minerals beryl , cryolite , garnet , spinel , and turquoise . Impurities in Al 2 O 3 , such as chromium and iron , yield the gemstones ruby and sapphire , respectively. Native aluminium metal

3075-405: Is also easily machined and cast . Aluminium is an excellent thermal and electrical conductor , having around 60% the conductivity of copper , both thermal and electrical, while having only 30% of copper's density. Aluminium is capable of superconductivity , with a superconducting critical temperature of 1.2 kelvin and a critical magnetic field of about 100 gauss (10 milliteslas ). It

3198-603: Is also known as Jack Northrop Field in his honor. Aluminum Aluminium (or aluminum in North American English ) is a chemical element ; it has symbol   Al and atomic number  13. Aluminium has a density lower than that of other common metals , about one-third that of steel . It has a great affinity towards oxygen , forming a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver , both in its color and in its great ability to reflect light. It

3321-553: Is extremely rare and can only be found as a minor phase in low oxygen fugacity environments, such as the interiors of certain volcanoes. Native aluminium has been reported in cold seeps in the northeastern continental slope of the South China Sea . It is possible that these deposits resulted from bacterial reduction of tetrahydroxoaluminate Al(OH) 4 . Although aluminium is a common and widespread element, not all aluminium minerals are economically viable sources of

3444-536: Is greatly reduced by aqueous salts, particularly in the presence of dissimilar metals. Aluminium reacts with most nonmetals upon heating, forming compounds such as aluminium nitride (AlN), aluminium sulfide (Al 2 S 3 ), and the aluminium halides (AlX 3 ). It also forms a wide range of intermetallic compounds involving metals from every group on the periodic table. The vast majority of compounds, including all aluminium-containing minerals and all commercially significant aluminium compounds, feature aluminium in

3567-492: Is in fact more basic than that of gallium. Aluminium also bears minor similarities to the metalloid boron in the same group: AlX 3 compounds are valence isoelectronic to BX 3 compounds (they have the same valence electronic structure), and both behave as Lewis acids and readily form adducts . Additionally, one of the main motifs of boron chemistry is regular icosahedral structures, and aluminium forms an important part of many icosahedral quasicrystal alloys, including

3690-476: Is low in comparison with many other metals. All other isotopes of aluminium are radioactive . The most stable of these is Al : while it was present along with stable Al in the interstellar medium from which the Solar System formed, having been produced by stellar nucleosynthesis as well, its half-life is only 717,000 years and therefore a detectable amount has not survived since the formation of

3813-500: Is negligible. Aqua regia also dissolves aluminium. Aluminium is corroded by dissolved chlorides , such as common sodium chloride , which is why household plumbing is never made from aluminium. The oxide layer on aluminium is also destroyed by contact with mercury due to amalgamation or with salts of some electropositive metals. As such, the strongest aluminium alloys are less corrosion-resistant due to galvanic reactions with alloyed copper , and aluminium's corrosion resistance

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3936-521: Is not as important. It is a polymer with the formula (AlH 3 ) n , in contrast to the corresponding boron hydride that is a dimer with the formula (BH 3 ) 2 . Aluminium's per-particle abundance in the Solar System is 3.15 ppm (parts per million). It is the twelfth most abundant of all elements and third most abundant among the elements that have odd atomic numbers, after hydrogen and nitrogen. The only stable isotope of aluminium, Al,

4059-416: Is quite soft and lacking in strength. In most applications various aluminium alloys are used instead because of their higher strength and hardness. The yield strength of pure aluminium is 7–11 MPa , while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium is ductile , with a percent elongation of 50-70%, and malleable allowing it to be easily drawn and extruded . It

4182-435: Is soft, nonmagnetic , and ductile . It has one stable isotope, Al, which is highly abundant, making aluminium the twelfth-most common element in the universe. The radioactivity of Al leads to it being used in radiometric dating . Chemically, aluminium is a post-transition metal in the boron group ; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state . The aluminium cation Al

4305-422: Is surrounded by six fluorine atoms in a distorted octahedral arrangement, with each fluorine atom being shared between the corners of two octahedra. Such {AlF 6 } units also exist in complex fluorides such as cryolite , Na 3 AlF 6 . AlF 3 melts at 1,290 °C (2,354 °F) and is made by reaction of aluminium oxide with hydrogen fluoride gas at 700 °C (1,300 °F). With heavier halides,

4428-547: Is termed amphoterism and is characteristic of weakly basic cations that form insoluble hydroxides and whose hydrated species can also donate their protons. One effect of this is that aluminium salts with weak acids are hydrolyzed in water to the aquated hydroxide and the corresponding nonmetal hydride: for example, aluminium sulfide yields hydrogen sulfide . However, some salts like aluminium carbonate exist in aqueous solution but are unstable as such; and only incomplete hydrolysis takes place for salts with strong acids, such as

4551-416: Is that of the preceding noble gas , whereas those of its heavier congeners gallium , indium , thallium , and nihonium also include a filled d-subshell and in some cases a filled f-subshell. Hence, the inner electrons of aluminium shield the valence electrons almost completely, unlike those of aluminium's heavier congeners. As such, aluminium is the most electropositive metal in its group, and its hydroxide

4674-433: Is the eighteenth most abundant nucleus in the universe. It is created almost entirely after fusion of carbon in massive stars that will later become Type II supernovas : this fusion creates Mg, which upon capturing free protons and neutrons, becomes aluminium. Some smaller quantities of Al are created in hydrogen burning shells of evolved stars, where Mg can capture free protons. Essentially all aluminium now in existence

4797-774: The American Society of Mechanical Engineers for "meritorious service in the advancement of aeronautics." Investiture in the International Aerospace Hall of Fame came in 1972, and in the National Aviation Hall of Fame in 1974. He was posthumously inducted into the National Inventors Hall of Fame in 2003. Northrop's passion for tailless flight was honored by the naming of a giant tailless pterosaur Quetzalcoatlus northropi . Hawthorne Municipal Airport

4920-476: The B-2 Spirit flying wing to be flown like a conventional aircraft. The flying wing and the pursuit of low drag high lift designs were Northrop's passion and its failure to be selected as the next generation bomber platform after World War II, and the subsequent dismantling of all prototypes and incomplete YB-49s, were a severe blow to him. He retired at age 57 in 1952 and virtually ended his association with

5043-455: The Friedel–Crafts reactions . Aluminium trichloride has major industrial uses involving this reaction, such as in the manufacture of anthraquinones and styrene ; it is also often used as the precursor for many other aluminium compounds and as a reagent for converting nonmetal fluorides into the corresponding chlorides (a transhalogenation reaction ). Aluminium forms one stable oxide with

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5166-475: The London Metal Exchange , the oldest industrial metal exchange in the world, in 1978. The output continued to grow: the annual production of aluminium exceeded 50,000,000 metric tons in 2013. The real price for aluminium declined from $ 14,000 per metric ton in 1900 to $ 2,340 in 1948 (in 1998 United States dollars). Extraction and processing costs were lowered over technological progress and

5289-834: The Northrop Corporation in 1939. His career began in 1916 as a draftsman for Loughead Aircraft Manufacturing Company (founded 1912). He joined the Douglas Aircraft Company in 1923 and worked on the Douglas World Cruiser , where in time he became a project engineer. In 1927 he joined the Lockheed Corporation , where he was a chief engineer on the Lockheed Vega transport. He left in 1929 to found Avion Corporation, which he sold in 1930. Two years later, he founded

5412-735: The Northrop F-89 Scorpion all-weather interceptor, the Northrop YB-49 long-range bomber, the Northrop Snark intercontinental missile, and automatic celestial navigation systems. He produced a number of flying wings, including the Northrop N-1M , Northrop N-9M , and Northrop YB-35 . His ideas regarding flying wing technology were years ahead of the computer and electronic advances of "fly-by-wire" stability systems which allow inherently unstable aircraft like

5535-643: The Northrop Gamma and Northrop Delta . By 1939 the Northrop Corporation had become a subsidiary of Douglas Aircraft, so Northrop founded another completely independent company of the same name in Hawthorne, California , a site located by Moye Stephens , one of the co-founders. While working at this company, Northrop focused on the flying wing design, which he was convinced was the next major step in aircraft design. His first project,

5658-475: The aluminum spelling in his American Dictionary of the English Language . In the 1830s, the -um spelling gained usage in the United States; by the 1860s, it had become the more common spelling there outside science. In 1892, Hall used the -um spelling in his advertising handbill for his new electrolytic method of producing the metal, despite his constant use of the -ium spelling in all

5781-423: The chemical formula Al 2 O 3 , commonly called alumina . It can be found in nature in the mineral corundum , α-alumina; there is also a γ-alumina phase. Its crystalline form, corundum, is very hard ( Mohs hardness 9), has a high melting point of 2,045 °C (3,713 °F), has very low volatility, is chemically inert, and a good electrical insulator, it is often used in abrasives (such as toothpaste), as

5904-638: The free metal . It is obtained industrially by mining bauxite , a sedimentary rock rich in aluminium minerals. The discovery of aluminium was announced in 1825 by Danish physicist Hans Christian Ørsted . The first industrial production of aluminium was initiated by French chemist Henri Étienne Sainte-Claire Deville in 1856. Aluminium became much more available to the public with the Hall–Héroult process developed independently by French engineer Paul Héroult and American engineer Charles Martin Hall in 1886, and

6027-551: The interstellar gas ; if the original Al were still present, gamma ray maps of the Milky Way would be brighter. Overall, the Earth is about 1.59% aluminium by mass (seventh in abundance by mass). Aluminium occurs in greater proportion in the Earth's crust than in the universe at large. This is because aluminium easily forms the oxide and becomes bound into rocks and stays in the Earth's crust , while less reactive metals sink to

6150-526: The 5th century BCE. The ancients are known to have used alum as a dyeing mordant and for city defense. After the Crusades , alum, an indispensable good in the European fabric industry, was a subject of international commerce; it was imported to Europe from the eastern Mediterranean until the mid-15th century. The nature of alum remained unknown. Around 1530, Swiss physician Paracelsus suggested alum

6273-462: The AAF which bought them at Wright Field without testing them or assuring reliability, and then shipped them to Northrop. Microfilmed records of reports and correspondence of the XB-35 program relate that after three or four flights, power plant and propeller vibrations increased, and the very efficient contra-rotating propellers began failing with frustrating frequency. Meetings were called by Northrop, of

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6396-525: The AAF, Pratt & Whitney and Hamilton Standard where no one would take responsibility for correcting the AAF's engines and propellers. In addition, the AAF failed to supply the AC electrical alternator, insisting on Northrop using an onboard auxiliary power unit (APU) unit driven by an automotive engine which limited the high-altitude, high-speed XB-35 to test flights below 15,000 ft (4,600 m). The AAF also refused to allow Northrop proposed modification of

6519-472: The Al–Zn–Mg class. Aluminium has a high chemical affinity to oxygen, which renders it suitable for use as a reducing agent in the thermite reaction. A fine powder of aluminium reacts explosively on contact with liquid oxygen ; under normal conditions, however, aluminium forms a thin oxide layer (~5 nm at room temperature) that protects the metal from further corrosion by oxygen, water, or dilute acid,

6642-645: The Convair B-36 needed more development money. At that time, it appeared the B-36 program might be cancelled as well as the B-35. The USAF and the Texas Congressional delegation desired to have a production program for the large Fort Worth aircraft production factory, and Convair had much more effective lobbyists in Washington, DC. The Northrop Corporation was always a technological trailblazer, but

6765-465: The Loughead brothers and their newly founded (in 1926) Lockheed Aircraft Company , working as chief engineer on the Lockheed Vega , the civilian transport monoplane with a cantilever wing that produced unusually high performance for that period, and was widely used by such top pilots as Wiley Post , Amelia Earhart , and Hubert Wilkins . In 1929 he produced an all-metal monoplane with an engine within

6888-628: The Northrop "all-wing" designs. There are long-standing conspiracy theories about the cancellation of the Flying Wing program; specifically, an accusation from Jack Northrop that Secretary of the Air Force Stuart Symington attempted to coerce him to merge his company with the Atlas Corporation-controlled Convair . In a 1979 taped interview, Jack Northrop claimed the Flying Wing contract

7011-724: The Northrop Corporation. This firm became a subsidiary of Douglas Aircraft in 1939, so he co-founded a second company named Northrop. Born in Newark, New Jersey , in 1895, Northrop grew up in Santa Barbara, California . In 1916, Northrop's first job in aviation was in working as a draftsman for the Santa Barbara-based Loughead Aircraft Manufacturing Company . After the outbreak of the First World War , Northrop

7134-418: The United States dollar, and alumina prices. The BRIC countries' combined share in primary production and primary consumption grew substantially in the first decade of the 21st century. China is accumulating an especially large share of the world's production thanks to an abundance of resources, cheap energy, and governmental stimuli; it also increased its consumption share from 2% in 1972 to 40% in 2010. In

7257-514: The United States, Western Europe, and Japan, most aluminium was consumed in transportation, engineering, construction, and packaging. In 2021, prices for industrial metals such as aluminium have soared to near-record levels as energy shortages in China drive up costs for electricity. The names aluminium and aluminum are derived from the word alumine , an obsolete term for alumina , the primary naturally occurring oxide of aluminium . Alumine

7380-524: The XB-35s until the government fixed their propulsion system. Concurrently, the AAF ordered Northrop to convert two of the YB-35 airframes to YB-49s, essentially substituting eight jet engines for four reciprocating engines. As a result, the airframe promptly flew to more than 40,000 ft (12,000 m) and topped 520 mph (840 km/h) in flight tests, verifying the XB-35 air frame's aerodynamics, but at

7503-616: The airspeed or the glide angle could be manipulated. On 22 November 1941, the United States Army Air Forces (USAAF, or AAF) signed the development contract for an XB-35; the contract included an option for a second aircraft, which was exercised on 2 January 1942. The first was to be delivered in November 1943, the second in April of the next year. Detailed engineering began in early 1942. A fuselage-like crew cabin

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7626-578: The aluminium atoms have tetrahedral four-coordination and the other half have trigonal bipyramidal five-coordination. Four pnictides – aluminium nitride (AlN), aluminium phosphide (AlP), aluminium arsenide (AlAs), and aluminium antimonide (AlSb) – are known. They are all III-V semiconductors isoelectronic to silicon and germanium , all of which but AlN have the zinc blende structure. All four can be made by high-temperature (and possibly high-pressure) direct reaction of their component elements. Aluminium alloys well with most other metals (with

7749-577: The bomb bays to carry the standard Mk. 3 atomic bomb, while at the same time declaring the AF would not buy the bomber unless it could carry the A-bomb. Northrop reluctantly agreed to try a single-rotation propeller, which slightly increased takeoff distance and a reduced rate-of-climb and maximum speed. Problems with the quartet of contra-rotating propellers ' shafts comprising each aircraft's drive-line system continued until finally Jack Northrop himself grounded

7872-403: The carrying of large bombs, and the early atomic bombs , without bomb bay redesign and modifications. Production aircraft would have defensive armament of twenty 0.5 in (12.7 mm) machine guns or 20 mm cannon, carried in six turrets, two turrets along the aircraft's center line, four above and below the outer wings, and four in the "stinger" tail cone. The B-35 would take advantage of

7995-436: The characteristic physical properties of a post-transition metal, with longer-than-expected interatomic distances. Furthermore, as Al is a small and highly charged cation, it is strongly polarizing and bonding in aluminium compounds tends towards covalency ; this behavior is similar to that of beryllium (Be ), and the two display an example of a diagonal relationship . The underlying core under aluminium's valence shell

8118-455: The company for the next 30 years. He broke a decades-long silence on the Flying Wing's demise in a 1979 television interview, accusing the Air Force of killing the project to punish him for refusing to merge his company with Consolidated Vultee . He alleged that Air Force Secretary Stuart Symington threatened him by saying, "You’ll be goddamned sorry if you don’t". Symington later left

8241-404: The competing propeller-driven B-36 was obsolete by that time and had just as many or even more development problems, the Air Force needed a very long-range, post-war atomic bomber to counter the perceived Soviet threat. It had more faith that the B-36's "teething" problems could be overcome, compared to those of the new and radical "Flying Wing", the unofficial name that was later associated with all

8364-419: The coordination numbers are lower. The other trihalides are dimeric or polymeric with tetrahedral four-coordinate aluminium centers. Aluminium trichloride (AlCl 3 ) has a layered polymeric structure below its melting point of 192.4 °C (378 °F) but transforms on melting to Al 2 Cl 6 dimers. At higher temperatures those increasingly dissociate into trigonal planar AlCl 3 monomers similar to

8487-428: The core. In the Earth's crust, aluminium is the most abundant metallic element (8.23% by mass ) and the third most abundant of all elements (after oxygen and silicon). A large number of silicates in the Earth's crust contain aluminium. In contrast, the Earth's mantle is only 2.38% aluminium by mass. Aluminium also occurs in seawater at a concentration of 2 μg/kg. Because of its strong affinity for oxygen, aluminium

8610-474: The decay of Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago. The remaining isotopes of aluminium, with mass numbers ranging from 21 to 43, all have half-lives well under an hour. Three metastable states are known, all with half-lives under a minute. An aluminium atom has 13 electrons, arranged in an electron configuration of [ Ne ] 3s 3p , with three electrons beyond

8733-436: The effectiveness of propeller control. After only 19 flights, Northrop grounded the first XB-35; the second aircraft was grounded after eight test flights. During this time, the contra-rotating propellers were removed and replaced with four-blade single-rotation propellers. In addition to having continued drive shaft vibration problems, the new single-rotation props greatly reduced the aircraft's speed and performance. Furthermore,

8856-399: The environment, no living organism is known to metabolize aluminium salts , but this aluminium is well tolerated by plants and animals. Because of the abundance of these salts, the potential for a biological role for them is of interest, and studies are ongoing. Of aluminium isotopes, only Al is stable. This situation is common for elements with an odd atomic number. It is

8979-478: The exception of most alkali metals and group 13 metals) and over 150 intermetallics with other metals are known. Preparation involves heating fixed metals together in certain proportion, followed by gradual cooling and annealing . Bonding in them is predominantly metallic and the crystal structure primarily depends on efficiency of packing. There are few compounds with lower oxidation states. A few aluminium(I) compounds exist: AlF, AlCl, AlBr, and AlI exist in

9102-520: The fact that its nuclei are much lighter, while difference in the unit cell size does not compensate for this difference. The only lighter metals are the metals of groups 1 and 2 , which apart from beryllium and magnesium are too reactive for structural use (and beryllium is very toxic). Aluminium is not as strong or stiff as steel, but the low density makes up for this in the aerospace industry and for many other applications where light weight and relatively high strength are crucial. Pure aluminium

9225-555: The first delivery date back to 1947. Seeing that it would almost certainly never be ready in time for the war, the Army Air Forces canceled the production contract, though the Air Technical Services Command continued to run the program for research purposes. Actual flight tests of the aircraft revealed several problems: the contra-rotating props caused constant heavy drive-shaft vibration and the government-supplied gearboxes had frequent malfunctions and reduced

9348-730: The gas phase after explosion and in stellar absorption spectra. More thoroughly investigated are compounds of the formula R 4 Al 2 which contain an Al–Al bond and where R is a large organic ligand . A variety of compounds of empirical formula AlR 3 and AlR 1.5 Cl 1.5 exist. The aluminium trialkyls and triaryls are reactive, volatile, and colorless liquids or low-melting solids. They catch fire spontaneously in air and react with water, thus necessitating precautions when handling them. They often form dimers, unlike their boron analogues, but this tendency diminishes for branched-chain alkyls (e.g. Pr , Bu , Me 3 CCH 2 ); for example, triisobutylaluminium exists as an equilibrium mixture of

9471-453: The gaseous phase when the respective trihalide is heated with aluminium, and at cryogenic temperatures. A stable derivative of aluminium monoiodide is the cyclic adduct formed with triethylamine , Al 4 I 4 (NEt 3 ) 4 . Al 2 O and Al 2 S also exist but are very unstable. Very simple aluminium(II) compounds are invoked or observed in the reactions of Al metal with oxidants. For example, aluminium monoxide , AlO, has been detected in

9594-440: The government to head the very same Consolidated Vultee company Northrop had refused to merge with. Symington called the charge "preposterous and absurd" and told a researcher "There was a tremendous overcapacity in the industry following World War II". He said Northrop came to him, seeking more business to help his struggling company. Symington said, "I may very well have suggested that he merge his company with Convair, who we knew

9717-646: The halides, nitrate , and sulfate . For similar reasons, anhydrous aluminium salts cannot be made by heating their "hydrates": hydrated aluminium chloride is in fact not AlCl 3 ·6H 2 O but [Al(H 2 O) 6 ]Cl 3 , and the Al–O bonds are so strong that heating is not sufficient to break them and form Al–Cl bonds instead: All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium fluoride (AlF 3 ) features six-coordinate aluminium, which explains its involatility and insolubility as well as high heat of formation . Each aluminium atom

9840-400: The independent nature of Jack Northrop often collided with the political wheeling-and-dealing in Washington that tended to run huge military allocations. Consequently, the B-36 prevailed, with just over 380 aircraft built. Furthermore, earlier the same year, when the YB-49 jet bomber was cancelled, Northrop received a smaller production contract for its F-89 Scorpion fighter as compensation for

9963-529: The intricate exhaust system turned into a fiasco to maintain. After only two years of use, the engines already showed signs of metal fatigue . In the end, the program was terminated due to its technical difficulties and the obsolescence of its reciprocating propeller engines, and the fact it was far behind schedule and over budget. Another contributing factor to the program's failure was the tendency of Northrop to become engaged in many experimental programs, which spread its small engineering staff far too wide. While

10086-456: The lost Flying Wing contract. Data from Northrop Flying Wings : a history of Jack Northrop's visionary aircraft General characteristics Performance Armament Related development Aircraft of comparable role, configuration, and era Related lists John Knudsen Northrop John Knudsen Northrop (November 10, 1895 – February 18, 1981) was an American aircraft industrialist and designer who founded

10209-573: The low drag high lift concept inherent in the flying wing. NASA replied that the idea had technological merit, encouraging Northrop that his flying wing concepts had not been completely abandoned. By the late 1970s a variety of illnesses left him unable to walk or speak. Shortly before his death, he was given clearance to see designs and hold a scale model of the Northrop Grumman B-2 Spirit stealth bomber, which shared design features of his YB-35 and YB-49. The B-2, for example, has

10332-433: The low-pressure polymerization of ethene and propene . There are also some heterocyclic and cluster organoaluminium compounds involving Al–N bonds. The industrially most important aluminium hydride is lithium aluminium hydride (LiAlH 4 ), which is used as a reducing agent in organic chemistry . It can be produced from lithium hydride and aluminium trichloride . The simplest hydride, aluminium hydride or alane,

10455-512: The mass production of aluminium led to its extensive use in industry and everyday life. In the First and Second World Wars, aluminium was a crucial strategic resource for aviation . In 1954, aluminium became the most produced non-ferrous metal , surpassing copper . In the 21st century, most aluminium was consumed in transportation, engineering, construction, and packaging in the United States, Western Europe, and Japan. Despite its prevalence in

10578-529: The metal remained rare; its cost exceeded that of gold. The first industrial production of aluminium was established in 1856 by French chemist Henri Etienne Sainte-Claire Deville and companions. Deville had discovered that aluminium trichloride could be reduced by sodium, which was more convenient and less expensive than potassium, which Wöhler had used. Even then, aluminium was still not of great purity and produced aluminium differed in properties by sample. Because of its electricity-conducting capacity, aluminium

10701-655: The metal to be isolated from alum was alumium , which Davy suggested in an 1808 article on his electrochemical research, published in Philosophical Transactions of the Royal Society . It appeared that the name was created from the English word alum and the Latin suffix -ium ; but it was customary then to give elements names originating in Latin, so this name was not adopted universally. This name

10824-465: The metal with many uses at the time. During World War I , major governments demanded large shipments of aluminium for light strong airframes; during World War II , demand by major governments for aviation was even higher. By the mid-20th century, aluminium had become a part of everyday life and an essential component of housewares. In 1954, production of aluminium surpassed that of copper , historically second in production only to iron, making it

10947-491: The metal. Almost all metallic aluminium is produced from the ore bauxite (AlO x (OH) 3–2 x ). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic conditions. In 2017, most bauxite was mined in Australia, China, Guinea, and India. The history of aluminium has been shaped by usage of alum . The first written record of alum, made by Greek historian Herodotus , dates back to

11070-485: The monomer and dimer. These dimers, such as trimethylaluminium (Al 2 Me 6 ), usually feature tetrahedral Al centers formed by dimerization with some alkyl group bridging between both aluminium atoms. They are hard acids and react readily with ligands, forming adducts. In industry, they are mostly used in alkene insertion reactions, as discovered by Karl Ziegler , most importantly in "growth reactions" that form long-chain unbranched primary alkenes and alcohols, and in

11193-506: The most produced non-ferrous metal . During the mid-20th century, aluminium emerged as a civil engineering material, with building applications in both basic construction and interior finish work, and increasingly being used in military engineering, for both airplanes and land armor vehicle engines. Earth's first artificial satellite , launched in 1957, consisted of two separate aluminium semi-spheres joined and all subsequent space vehicles have used aluminium to some extent. The aluminium can

11316-614: The next decade, the -um spelling dominated American usage. In 1925, the American Chemical Society adopted this spelling. The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990. In 1993, they recognized aluminum as an acceptable variant; the most recent 2005 edition of the IUPAC nomenclature of inorganic chemistry also acknowledges this spelling. IUPAC official publications use

11439-429: The only primordial aluminium isotope, i.e. the only one that has existed on Earth in its current form since the formation of the planet. It is therefore a mononuclidic element and its standard atomic weight is virtually the same as that of the isotope. This makes aluminium very useful in nuclear magnetic resonance (NMR), as its single stable isotope has a high NMR sensitivity. The standard atomic weight of aluminium

11562-407: The oxidation state 3+. The coordination number of such compounds varies, but generally Al is either six- or four-coordinate. Almost all compounds of aluminium(III) are colorless. In aqueous solution, Al exists as the hexaaqua cation [Al(H 2 O) 6 ] , which has an approximate K a of 10 . Such solutions are acidic as this cation can act as a proton donor and progressively hydrolyze until

11685-460: The patents he filed between 1886 and 1903. It is unknown whether this spelling was introduced by mistake or intentionally, but Hall preferred aluminum since its introduction because it resembled platinum , the name of a prestigious metal. By 1890, both spellings had been common in the United States, the -ium spelling being slightly more common; by 1895, the situation had reversed; by 1900, aluminum had become twice as common as aluminium ; in

11808-402: The piston engines made the B-35 obsolete, it remained superior in overall performance and range to its competitor, the Convair B-36, and General Hoyt Vandenberg wrote that only the B-35 and the B-36 had adequate range for the Air Force's primary mission, and nothing comparable would be available until the mid-1950s. Only the first YB-35 was ever flown. Multiple flight testing demonstrated that it

11931-404: The planet. However, minute traces of Al are produced from argon in the atmosphere by spallation caused by cosmic ray protons. The ratio of Al to Be has been used for radiodating of geological processes over 10 to 10  year time scales, in particular transport, deposition, sediment storage, burial times, and erosion. Most meteorite scientists believe that the energy released by

12054-528: The price of range. The prop-version had a design range capable of reaching targets 4,000 mi (6,400 km) away, but the jet-engine version's range was cut nearly in half. The new version disqualified it for the Air Force's top-priority mission as a strategic bomber, which at that time meant striking at the USSR's industrial and military complexes in the Ural Mountains. The Air Force, itself involved in

12177-423: The respective hydrogen chalcogenide . As aluminium is a small atom relative to these chalcogens, these have four-coordinate tetrahedral aluminium with various polymorphs having structures related to wurtzite , with two-thirds of the possible metal sites occupied either in an orderly (α) or random (β) fashion; the sulfide also has a γ form related to γ-alumina, and an unusual high-temperature hexagonal form where half

12300-481: The same 172-foot wingspan as the jet-powered flying wing, YB-49. Northrop reportedly wrote on a sheet of paper "Now I know why God has kept me alive for 25 years". B-2 project designer John Cashen said, "As he held this model in his shaking hands, it was as if you could see his entire history with the flying wing passing through his mind." He died ten months later. In 1947 he received the Spirit of St. Louis Medal from

12423-485: The scale of the economies. However, the need to exploit lower-grade poorer quality deposits and the use of fast increasing input costs (above all, energy) increased the net cost of aluminium; the real price began to grow in the 1970s with the rise of energy cost. Production moved from the industrialized countries to countries where production was cheaper. Production costs in the late 20th century changed because of advances in technology, lower energy prices, exchange rates of

12546-408: The structure of BCl 3 . Aluminium tribromide and aluminium triiodide form Al 2 X 6 dimers in all three phases and hence do not show such significant changes of properties upon phase change. These materials are prepared by treating aluminium with the halogen. The aluminium trihalides form many addition compounds or complexes; their Lewis acidic nature makes them useful as catalysts for

12669-403: The tooling for building the prototypes ... as explained in detail in the book "Goodbye Beautiful Wing" by Terrence O'Neill ( ISBN   978-0979012129 ). The N9Ms would also be used as a flight trainer, to familiarize pilots with the radical, all-wing concept. Early in 1942, design work on the XB-35 itself began in earnest. Unlike conventional aircraft, truly "tailless" flying wings do not have

12792-536: The two therefore look similar. Aluminium is also good at reflecting solar radiation , although prolonged exposure to sunlight in air adds wear to the surface of the metal; this may be prevented if aluminium is anodized , which adds a protective layer of oxide on the surface. The density of aluminium is 2.70 g/cm , about 1/3 that of steel, much lower than other commonly encountered metals, making aluminium parts easily identifiable through their lightness. Aluminium's low density compared to most other metals arises from

12915-620: The wing structure. Although this aircraft had booms to attach the tail group, it was in fact the first step toward the flying wing. In 1929, Northrop struck out on his own, founding the Avion Corporation, which he was forced to sell to United Aircraft and Transport Corporation in 1930. In 1932, Northrop, backed by Donald Douglas of Douglas Aircraft, founded another company, the Northrop Corporation in El Segundo, California . This company built two highly successful monoplanes,

13038-642: Was a U.S. Navy designation for one YB-35 airframe to be used for development trials; the project was canceled while still in the planning stage. The U.S. Army Air Forces had originally ordered 200 production model B-35s. Since Northrop's facilities were not up to the task of producing them, the Glenn L. Martin Company agreed to undertake mass production. This proved irrelevant when the aircraft had too many development problems. Even disregarding these, so many of Martin's engineers had been drafted by 1944 that Martin pushed

13161-475: Was a maximum speed of 720 km/h (450 mph), cruise speed of 443 km/h (275 mph), and service ceiling of 14,000 m (45,000 ft). This aircraft would be able to bomb Nazi-occupied Europe in the event that Britain fell (this was similar to Nazi Germany's own Amerikabomber program design competition through the RLM , itself initiated in the spring of 1942). The original April 1941 USAAC proposal

13284-461: Was a salt of an earth of alum. In 1595, German doctor and chemist Andreas Libavius experimentally confirmed this. In 1722, German chemist Friedrich Hoffmann announced his belief that the base of alum was a distinct earth. In 1754, German chemist Andreas Sigismund Marggraf synthesized alumina by boiling clay in sulfuric acid and subsequently adding potash . Attempts to produce aluminium date back to 1760. The first successful attempt, however,

13407-559: Was actually for two prototypes of the XB-35, and included Northrop's plan to also build two all-wood one-third scale flying models to measure performance and stability; these were dubbed the Northrop N-9M (M standing for model). This aircraft would be used to gather flight test data on the Flying Wing design. Jack Northrop also hired part-time the leading aeronautical designer of the day Theodore von Kármán , to evaluate and who approved of Northrop's initial design, and to start building

13530-404: Was airworthy; it was then parked and ignored for more than a year until being scrapped on 20 July 1949. The unfinished YB-35 #2, was scrapped almost a month later, on 19 August 1949. The other 11 of 13 YB-35 aircraft ordered underwent conversion to other power plants. Two of those airframes were converted to use eight Allison J35 jet engines and designated YB-49 . The second YB-35 converted to

13653-494: Was borrowed from French, which in turn derived it from alumen , the classical Latin name for alum , the mineral from which it was collected. The Latin word alumen stems from the Proto-Indo-European root *alu- meaning "bitter" or "beer". British chemist Humphry Davy , who performed a number of experiments aimed to isolate the metal, is credited as the person who named the element. The first name proposed for

13776-413: Was cancelled because he would not agree to a merger because Convair's merger demands were "grossly unfair to Northrop." When Northrop refused, Symington supposedly arranged to cancel the B-35 and B-49 program. Symington became president of Convair after he left government service a short time later. Other observers note that the B-35 and B-49 designs had well-documented performance and design issues while

13899-422: Was completed in 1824 by Danish physicist and chemist Hans Christian Ørsted . He reacted anhydrous aluminium chloride with potassium amalgam , yielding a lump of metal looking similar to tin. He presented his results and demonstrated a sample of the new metal in 1825. In 1827, German chemist Friedrich Wöhler repeated Ørsted's experiments but did not identify any aluminium. (The reason for this inconsistency

14022-496: Was criticized by contemporary chemists from France, Germany, and Sweden, who insisted the metal should be named for the oxide, alumina, from which it would be isolated. The English name alum does not come directly from Latin, whereas alumine / alumina obviously comes from the Latin word alumen (upon declension , alumen changes to alumin- ). One example was Essai sur la Nomenclature chimique (July 1811), written in French by

14145-552: Was drafted into the U.S. Army , where he served in the Army Signal Corps . Northrop served in the military for six months before Loughead successfully petitioned for his return to work in the private sector. In 1923, Northrop joined Douglas Aircraft Company , where he participated in the design of the Douglas Round-the-World-Cruiser and worked up to project engineer. In 1927 he rejoined

14268-524: Was first submitted to Boeing and Consolidated Aircraft Company and led to the production of the Convair B-36 . In May, one month before the USAAF was created, the contract was also extended to include Northrop, inviting it to submit a design along the lines it was already exploring. Since the new aircraft would require a significant amount of engineering work in untested waters, the first order placed

14391-475: Was going to get business." Aviation expert Bud Baker, who studied declassified documents and public records and conducted personal interviews with Symington, Air Force generals and Northrop's chairman, concluded the cancellation "was a sound decision, based on budgetary, technical, and strategic realities." Northrop dabbled in real estate and lost much of his personal fortune. In 1976, with his health failing, he felt compelled to communicate to NASA his belief in

14514-418: Was invented in 1956 and employed as a storage for drinks in 1958. Throughout the 20th century, the production of aluminium rose rapidly: while the world production of aluminium in 1900 was 6,800 metric tons, the annual production first exceeded 100,000 metric tons in 1916; 1,000,000 tons in 1941; 10,000,000 tons in 1971. In the 1970s, the increased demand for aluminium made it an exchange commodity; it entered

14637-433: Was only discovered in 1921.) He conducted a similar experiment in the same year by mixing anhydrous aluminium chloride with potassium and produced a powder of aluminium. In 1845, he was able to produce small pieces of the metal and described some physical properties of this metal. For many years thereafter, Wöhler was credited as the discoverer of aluminium. As Wöhler's method could not yield great quantities of aluminium,

14760-415: Was suddenly cancelled without explanation. The sole YRB-49A built flew 13 test flights and then was returned to Northrop's Ontario Airport. The last of Northrop's big Flying Wings sat abandoned at the airport's edge for two years and was finally ordered scrapped on 1 December 1953. In order to test the advanced Northrop T37 Turbodyne turboprop engine, produced by a Northrop subsidiary, the ultimate YB-35A

14883-570: Was to be converted to a single EB-35B test aircraft (in this case the prefix "E" for the designation meant "Exempt," not the later Electronic). The test aircraft would use two of the powerful T37 engines, each driving a pair of contra-rotating, paddle-blade propellers; the first planned ground tests were to be made using a single T37 engine. When the EB-35B project was canceled, the Air Force had Northrop's Turbodyne engine name, all its patents, and technical data reassigned to General Electric . The XB2T-1

15006-497: Was to be embedded inside the wing; it included a tail cone protruding from the trailing edge. This tail cone would contain the remote sighting stations for the bomber's gunners and a cluster of rear-firing machine guns in the production aircraft. In the midsection of the cabin, there were folding bunks for off-duty crew on long missions. The aircraft's bomb load was to be carried in six smaller bomb bays, three in each wing section, fitted with roll-away doors; this original design precluded

15129-580: Was used as the cap of the Washington Monument , completed in 1885. The tallest building in the world at the time, the non-corroding metal cap was intended to serve as a lightning rod peak. The first industrial large-scale production method was independently developed in 1886 by French engineer Paul Héroult and American engineer Charles Martin Hall ; it is now known as the Hall–Héroult process . The Hall–Héroult process converts alumina into metal. Austrian chemist Carl Joseph Bayer discovered

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