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100-606: The station's chimney stands 307 metres (1007 ft, 3 in) tall, making it the tallest in Germany. The power station was modernized in 2002 to increase its efficiency. It has an output capacity of 390 megawatts . Plans for Buschhaus Power Stations were drawn up at the end of the 1970s, despite the lack of demand for more electricity in West Germany at the time. The new plant created new jobs not only in construction and operation, but also in coal mining. In September 2016,

200-410: A fuel . Deposits of this substance can interfere with the airflow and more importantly, they are combustible and can cause dangerous chimney fires if the deposits ignite in the chimney. Heaters that burn natural gas drastically reduce the amount of creosote buildup due to natural gas burning much cleaner and more efficiently than traditional solid fuels. While in most cases there is no need to clean

300-613: A cap and be insulated if they service solid fuel appliances, but following the manufacturer's instructions carefully. Aluminum and galvanized steel chimneys are known as class A and class B chimneys. Class A are either an insulated, double wall stainless steel pipe or triple wall, air-insulated pipe often known by its genericized trade name Metalbestos. Class B are uninsulated double wall pipes often called B-vent, and are only used to vent non-condensing gas appliances. These may have an aluminum inside layer and galvanized steel outside layer. Concrete flue liners are like clay liners but are made of

400-492: A chimney is called the flue . Chimneys are adjacent to large industrial refineries , fossil fuel combustion facilities or part of buildings, steam locomotives and ships. In the United States , the term smokestack industry refers to the environmental impacts of burning fossil fuels by industrial society, including the electric industry during its earliest history. The term smokestack (colloquially, stack )

500-591: A concrete windshield with a number of flues on the inside. The 300 m (980 ft) high steam plant chimney at the Secunda CTL 's synthetic fuel plant in Secunda, South Africa consists of a 26 m (85 ft) diameter windshield with four 4.6 metre diameter concrete flues which are lined with refractory bricks built on rings of corbels spaced at 10 metre intervals. The reinforced concrete can be cast by conventional formwork or sliding formwork. The height

600-433: A density of 11.34 g/cm , which is greater than that of common metals such as iron (7.87 g/cm ), copper (8.93 g/cm ), and zinc (7.14 g/cm ). This density is the origin of the idiom to go over like a lead balloon . Some rarer metals are denser: tungsten and gold are both at 19.3 g/cm , and osmium —the densest metal known—has a density of 22.59 g/cm , almost twice that of lead. Lead

700-399: A downdraft of smoke and wind down the chimney. An H-style cap is a chimney top constructed from chimney pipes shaped like the letter H. It is an age-old method of regulating draft in situations where prevailing winds or turbulences cause downdraft and back-puffing. Although the H cap has a distinct advantage over most other downdraft caps, it fell out of favor because of its bulky design. It

800-492: A few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22.2 years, small quantities occur in nature because lead-210 is produced by a long decay series that starts with uranium-238 (that has been present for billions of years on Earth). Lead-211, −212, and −214 are present in the decay chains of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from

900-662: A flue liner. Chimneys built without a liner can usually have a liner added, but the type of liner needs to match the type of appliance it services. Flue liners may be clay or concrete tile, metal, or poured in place concrete. Clay tile flue liners are very common in the United States, although it is the only liner that does not meet Underwriters Laboratories 1777 approval and frequently they have problems such as cracked tiles and improper installation. Clay tiles are usually about 2 feet (0.61 m) long, available in various sizes and shapes, and are installed in new construction as

1000-668: A gas chimney on an annual basis that does not mean that other parts of the chimney cannot fall into disrepair. Disconnected or loose chimney fittings caused by corrosion over time can pose serious dangers for residents due to leakage of carbon monoxide into the home. Thus, it is recommended—and in some countries even mandatory—that chimneys be inspected annually and cleaned on a regular basis to prevent these problems. The workers who perform this task are called chimney sweeps or steeplejacks . This work used to be done largely by child labour and, as such , features in Victorian literature . In

1100-430: A metal flue. Bracing or strapping old masonry chimneys has not proven to be very effective in preventing damage or injury from earthquakes. It is now possible to buy "faux-brick" facades to cover these modern chimney structures. Other potential problems include: Several chimneys with observation decks were built. The following possibly incomplete list shows them. At several thermal power stations at least one smokestack

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1200-558: A neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around 17 million years. Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this beta decays to polonium-210, which alpha decays to lead-206. The cycle hence ends at lead-206, lead-207, lead-208, and bismuth-209. In

1300-466: A polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp hybrid orbitals, the other two being an external lone pair . They may be made in liquid ammonia via the reduction of lead by sodium . Lead can form multiply-bonded chains , a property it shares with its lighter homologs in the carbon group. Its capacity to do so is much less because the Pb–Pb bond energy

1400-413: A refractory cement and are more durable than the clay liners. Poured in place concrete liners are made by pouring special concrete into the existing chimney with a form. These liners are highly durable, work with any heating appliance, and can reinforce a weak chimney, but they are irreversible. A chimney pot is placed on top of the chimney to expand the length of the chimney inexpensively, and to improve

1500-428: A roof, flashing is used to seal up the joints. The down-slope piece is called an apron, the sides receive step flashing and a cricket is used to divert water around the upper side of the chimney underneath the flashing. Industrial chimneys are commonly referred to as flue-gas stacks and are generally external structures, as opposed to those built into the wall of a building. They are generally located adjacent to

1600-437: A significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. The inert pair effect is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity, such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp hybridization

1700-438: A single decay chain). In total, 43 lead isotopes have been synthesized, with mass numbers 178–220. Lead-205 is the most stable radioisotope, with a half-life of around 1.70 × 10  years. The second-most stable is lead-202, which has a half-life of about 52,500 years, longer than any of the natural trace radioisotopes. Bulk lead exposed to moist air forms a protective layer of varying composition. Lead(II) carbonate

1800-421: A steam-generating boiler or industrial furnace and the gases are carried to them with ductwork. Today the use of reinforced concrete has almost entirely replaced brick as a structural element in the construction of industrial chimneys. Refractory bricks are often used as a lining, particularly if the type of fuel being burned generates flue gases containing acids. Modern industrial chimneys sometimes consist of

1900-452: A structure, with every alternate layer of oxygen atoms absent. Negative oxidation states can occur as Zintl phases , as either free lead anions, as in Ba 2 Pb, with lead formally being lead(−IV), or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the trigonal bipyramidal Pb 5 ion, where two lead atoms are lead(−I) and three are lead(0). In such anions, each atom is at

2000-447: A variety of designs are sometimes placed on the top of chimneys. In the 18th and 19th centuries, the methods used to extract lead from its ore produced large amounts of toxic fumes. In the north of England, long near-horizontal chimneys were built, often more than 3 km (2 mi) long, which typically terminated in a short vertical chimney in a remote location where the fumes would cause less harm. Lead and silver deposits formed on

2100-563: A water tank on their structure. This combination has the advantage that the warm smoke running through the chimney prevents the water in the tank from freezing. Before World War II such structures were not uncommon, especially in countries influenced by Germany. Chimneys can carry antennas for radio relay services, cell phone transmissions, FM-radio and TV on their structure. Also long wire antennas for mediumwave transmissions can be fixed at chimneys. In all cases it had to be considered that these objects can easily corrode especially when placed near

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2200-590: Is 6 times higher, copper 10 times, and mild steel 15 times higher); it can be strengthened by adding small amounts of copper or antimony . The melting point of lead—at 327.5 °C (621.5 °F) —is very low compared to most metals. Its boiling point of 1749 °C (3180 °F) is the lowest among the carbon-group elements. The electrical resistivity of lead at 20 °C is 192 nanoohm -meters, almost an order of magnitude higher than those of other industrial metals (copper at 15.43 nΩ·m ; gold 20.51 nΩ·m ; and aluminium at 24.15 nΩ·m ). Lead

2300-521: Is a chemical element ; it has symbol Pb (from Latin plumbum ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable , and also has a relatively low melting point . When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead

2400-520: Is a neurotoxin that accumulates in soft tissues and bones. It damages the nervous system and interferes with the function of biological enzymes , causing neurological disorders ranging from behavioral problems to brain damage, and also affects general health, cardiovascular, and renal systems. Lead's toxicity was first documented by ancient Greek and Roman writers, who noted some of the symptoms of lead poisoning , but became widely recognized in Europe in

2500-401: Is a superconductor at temperatures lower than 7.19  K ; this is the highest critical temperature of all type-I superconductors and the third highest of the elemental superconductors. Natural lead consists of four stable isotopes with mass numbers of 204, 206, 207, and 208, and traces of six short-lived radioisotopes with mass numbers 209–214 inclusive. The high number of isotopes

2600-420: Is a common constituent; the sulfate or chloride may also be present in urban or maritime settings. This layer makes bulk lead effectively chemically inert in the air. Finely powdered lead, as with many metals, is pyrophoric , and burns with a bluish-white flame. Fluorine reacts with lead at room temperature, forming lead(II) fluoride . The reaction with chlorine is similar but requires heating, as

2700-780: Is a mixed sulfide derived from galena; anglesite , PbSO 4 , is a product of galena oxidation; and cerussite or white lead ore, PbCO 3 , is a decomposition product of galena. Arsenic , tin , antimony , silver , gold , copper , bismuth are common impurities in lead minerals. World lead resources exceed two billion tons. Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, United States. Global reserves—resources that are economically feasible to extract—totaled 88 million tons in 2016, of which Australia had 35 million, China 17 million, Russia 6.4 million. Typical background concentrations of lead do not exceed 0.1 μg/m in

2800-420: Is a relatively unreactive post-transition metal . Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases , and it tends to form covalent bonds . Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group . Exceptions are mostly limited to organolead compounds . Like

2900-426: Is a strong oxidizing agent, capable of oxidizing hydrochloric acid to chlorine gas. This is because the expected PbCl 4 that would be produced is unstable and spontaneously decomposes to PbCl 2 and Cl 2 . Analogously to lead monoxide , lead dioxide is capable of forming plumbate anions. Lead disulfide and lead diselenide are only stable at high pressures. Lead tetrafluoride , a yellow crystalline powder,

3000-404: Is a very soft metal with a Mohs hardness of 1.5; it can be scratched with a fingernail. It is quite malleable and somewhat ductile. The bulk modulus of lead—a measure of its ease of compressibility—is 45.8  GPa . In comparison, that of aluminium is 75.2 GPa; copper 137.8 GPa; and mild steel 160–169 GPa. Lead's tensile strength , at 12–17 MPa, is low (that of aluminium

3100-520: Is also used when referring to locomotive chimneys or ship chimneys , and the term funnel can also be used. The height of a chimney influences its ability to transfer flue gases to the external environment via stack effect . Additionally, the dispersion of pollutants at higher altitudes can reduce their impact on the immediate surroundings. The dispersion of pollutants over a greater area can reduce their concentrations and facilitate compliance with regulatory limits. Industrial chimney use dates to

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3200-436: Is an architectural ventilation structure made of masonry, clay or metal that isolates hot toxic exhaust gases or smoke produced by a boiler , stove , furnace , incinerator , or fireplace from human living areas. Chimneys are typically vertical, or as near as possible to vertical, to ensure that the gases flow smoothly, drawing air into the combustion in what is known as the stack, or chimney effect . The space inside

3300-433: Is called "natural draught/draft", "natural ventilation" , "chimney effect", or " stack effect ". The taller the stack, the more draught or draft is created. There can be cases of diminishing returns: if a stack is overly tall in relation to the heat being sent out of the stack, the flue gases may cool before reaching the top of the chimney. This condition can result in poor drafting, and in the case of wood burning appliances,

3400-439: Is combusted in a stove, oven, fireplace, hot water boiler, or industrial furnace, the hot combustion product gases that are formed are called flue gases. Those gases are generally exhausted to the ambient outside air through chimneys or industrial flue-gas stacks (sometimes referred to as smokestacks). The combustion flue gases inside the chimneys or stacks are much hotter than the ambient outside air and therefore less dense than

3500-445: Is common for the carbon group. The divalent state is rare for carbon and silicon , minor for germanium, important (but not prevailing) for tin, and is the more important of the two oxidation states for lead. This is attributable to relativistic effects , specifically the inert pair effect , which manifests itself when there is a large difference in electronegativity between lead and oxide , halide , or nitride anions, leading to

3600-415: Is common for the metal to become warped over time, thus further degrading the ability of the throat damper to seal. However, the advantage of a throat damper is that it seals off the living space from the air mass in the chimney, which, especially for chimneys positioned on an outside of wall of the home, is generally very cold. It is possible in practice to use both a top damper and a throat damper to obtain

3700-408: Is consistent with lead's atomic number being even. Lead has a magic number of protons (82), for which the nuclear shell model accurately predicts an especially stable nucleus. Lead-208 has 126 neutrons, another magic number, which may explain why lead-208 is extraordinarily stable. With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208

3800-414: Is exploited in the synthesis of other lead compounds. Few inorganic lead(IV) compounds are known. They are only formed in highly oxidizing solutions and do not normally exist under standard conditions. Lead(II) oxide gives a mixed oxide on further oxidation, Pb 3 O 4 . It is described as lead(II,IV) oxide , or structurally 2PbO·PbO 2 , and is the best-known mixed valence lead compound. Lead dioxide

3900-517: Is found mostly in marine use but has been regaining popularity due to its energy-saving functionality. The H-cap stabilizes the draft rather than increasing it. Other downdraft caps are based on the Venturi effect , solving downdraft problems by increasing the updraft constantly resulting in much higher fuel consumption. A chimney damper is a metal plate that can be positioned to close off the chimney when not in use and prevent outside air from entering

4000-502: Is more prevalent than most other elements with atomic numbers greater than 40. Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the s- and r-processes . In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo beta decay . A stable thallium-203 nucleus can capture

4100-650: Is not stable, as both the lead(III) ion and the larger complexes containing it are radicals . The same applies for lead(I), which can be found in such radical species. Numerous mixed lead(II,IV) oxides are known. When PbO 2 is heated in air, it becomes Pb 12 O 19 at 293 °C, Pb 12 O 17 at 351 °C, Pb 3 O 4 at 374 °C, and finally PbO at 605 °C. A further sesquioxide , Pb 2 O 3 , can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective fluorite structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such

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4200-741: Is over three and a half times lower than that of the C–C bond . With itself, lead can build metal–metal bonds of an order up to three. With carbon, lead forms organolead compounds similar to, but generally less stable than, typical organic compounds (due to the Pb–C bond being rather weak). This makes the organometallic chemistry of lead far less wide-ranging than that of tin. Lead predominantly forms organolead(IV) compounds, even when starting with inorganic lead(II) reactants; very few organolead(II) compounds are known. The most well-characterized exceptions are Pb[CH(SiMe 3 ) 2 ] 2 and plumbocene . The lead analog of

4300-415: Is stable, but less so than the difluoride . Lead tetrachloride (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable. Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state

4400-413: Is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds. There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down the carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in

4500-448: Is the heaviest stable nucleus. (This distinction formerly fell to bismuth , with an atomic number of 83, until its only primordial isotope , bismuth-209, was found in 2003 to decay very slowly.) The four stable isotopes of lead could theoretically undergo alpha decay to isotopes of mercury with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 10 to 10 years (at least 10 times

4600-419: Is the minimum required flow area from water heater tank and A f =19.6 inch is the minimum flow area from a furnace of a central heating system. Gas fired appliances must have a draft hood to cool combustion products entering the chimney and prevent updrafts or downdrafts. A characteristic problem of chimneys is they develop deposits of creosote on the walls of the structure when used with wood as

4700-538: Is the origin of the English word " plumbing ". Its ease of working, its low melting point enabling the easy fabrication of completely waterproof welded joints, and its resistance to corrosion ensured its widespread use in other applications, including pharmaceuticals, roofing, currency, warfare. Writers of the time, such as Cato the Elder , Columella , and Pliny the Elder , recommended lead (and lead-coated) vessels for

4800-525: Is the so-called inert pair effect : the 6s electrons of lead become reluctant to participate in bonding, stabilising the +2 oxidation state and making the distance between nearest atoms in crystalline lead unusually long. Lead's lighter carbon group congeners form stable or metastable allotropes with the tetrahedrally coordinated and covalently bonded diamond cubic structure. The energy levels of their outer s- and p-orbitals are close enough to allow mixing into four hybrid sp orbitals. In lead,

4900-400: Is to ensure the pollutants are dispersed over a wider area to meet legal or other safety requirements. A flue liner is a secondary barrier in a chimney that protects the masonry from the acidic products of combustion, helps prevent flue gas from entering the house, and reduces the size of an oversized flue. Since the 1950s, building codes in many locations require newly built chimneys to have

5000-656: Is used as electricity pylon. The following possibly incomplete list shows them. Nearly all this structures exist in an area, which was once part of the Soviet Union. Although this use has the disadvantage that conductor ropes may corrode faster due to the exhaust gases, one can find such structures also sometimes in countries not influenced by the former Soviet Union. An example herefore is one chimney of Scholven Power Plant in Gelsenkirchen, which carries one circuit of an outgoing 220 kV-line. Chimneys can also carry

5100-446: Is usefully exploited: lead tetraacetate is an important laboratory reagent for oxidation in organic synthesis. Tetraethyllead, once added to automotive gasoline, was produced in larger quantities than any other organometallic compound, and is still widely used in fuel for small aircraft . Other organolead compounds are less chemically stable. For many organic compounds, a lead analog does not exist. Lead's per-particle abundance in

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5200-490: The Middle Ages in some parts of Europe, a stepped gable design was developed, partly to provide access to chimneys without use of ladders. Masonry (brick) chimneys have also proven to be particularly prone to crumbling during earthquakes . Government housing authorities in cities prone to earthquakes such as San Francisco , Los Angeles , and San Diego now recommend building new homes with stud-framed chimneys around

5300-630: The Phoenicians worked deposits in the Iberian peninsula ; by 1600 BC, lead mining existed in Cyprus , Greece , and Sardinia . Rome's territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the classical era , with an estimated annual output peaking at 80,000 tonnes. Like their predecessors,

5400-552: The Romans , who drew smoke from their bakeries with tubes embedded in the walls. However, domestic chimneys first appeared in large dwellings in northern Europe in the 12th century. The earliest surviving example of an English chimney is at the keep of Conisbrough Castle in Yorkshire , which dates from 1185 AD, but they did not become common in houses until the 16th and 17th centuries. Smoke hoods were an early method of collecting

5500-671: The Solar System is 0.121  ppb (parts per billion). This figure is two and a half times higher than that of platinum , eight times more than mercury , and seventeen times more than gold . The amount of lead in the universe is slowly increasing as most heavier atoms (all of which are unstable) gradually decay to lead. The abundance of lead in the Solar System since its formation 4.5 billion years ago has increased by about 0.75%. The solar system abundances table shows that lead, despite its relatively high atomic number,

5600-804: The fall of Rome and did not reach comparable levels until the Industrial Revolution . Lead played a crucial role in the development of the printing press , as movable type could be relatively easily cast from lead alloys. In 2014, the annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ductility and relative inertness to oxidation make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in construction , plumbing , batteries , bullets , shots , weights , solders , pewters , fusible alloys , lead paints , leaded gasoline , and radiation shielding . Lead

5700-401: The nucleus , and more shielded by smaller orbitals. The sum of the first four ionization energies of lead exceeds that of tin, contrary to what periodic trends would predict. This is explained by relativistic effects , which become significant in heavier atoms, which contract s and p orbitals such that lead's 6s electrons have larger binding energies than its 5s electrons. A consequence

5800-468: The +4 state. Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong oxidizing agents like fluorine and chlorine react with lead to give only PbF 2 and PbCl 2 . Lead(II) ions are usually colorless in solution, and partially hydrolyze to form Pb(OH) and finally [Pb 4 (OH) 4 ] (in which the hydroxyl ions act as bridging ligands ), but are not reducing agents as tin(II) ions are. Techniques for identifying

5900-626: The Egyptians had used lead for sinkers in fishing nets , glazes , glasses , enamels , ornaments . Various civilizations of the Fertile Crescent used lead as a writing material , as coins , and as a construction material . Lead was used by the ancient Chinese as a stimulant , as currency , as contraceptive , and in chopsticks . The Indus Valley civilization and the Mesoamericans used it for making amulets ; and

6000-475: The Romans obtained lead mostly as a by-product of silver smelting. Lead mining occurred in central Europe , Britain , Balkans , Greece , Anatolia , Hispania , the latter accounting for 40% of world production. Lead tablets were commonly used as a material for letters. Lead coffins, cast in flat sand forms and with interchangeable motifs to suit the faith of the deceased, were used in ancient Judea . Lead

6100-413: The ambient air. That causes the bottom of the vertical column of hot flue gas to have a lower pressure than the pressure at the bottom of a corresponding column of outside air. That higher pressure outside the chimney is the driving force that moves the required combustion air into the combustion zone and also moves the flue gas up and out of the chimney. That movement or flow of combustion air and flue gas

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6200-607: The atmosphere; 100 mg/kg in soil; 4 mg/kg in vegetation, 5 μg/L in fresh water and seawater. The modern English word lead is of Germanic origin; it comes from the Middle English leed and Old English lēad (with the macron above the "e" signifying that the vowel sound of that letter is long). The Old English word is derived from the hypothetical reconstructed Proto-Germanic * lauda- ('lead'). According to linguistic theory, this word bore descendants in multiple Germanic languages of exactly

6300-581: The benefits of both. The two top damper designs currently on the market are the Lyemance (pivoting door) and the Lock Top (translating door). In the late Middle Ages in Western Europe the design of stepped gables arose to allow maintenance access to the chimney top, especially for tall structures such as castles and great manor houses . When coal, oil, natural gas, wood, or any other fuel

6400-403: The chimney and making it onto the roof. Although the masonry inside the chimney can absorb a large amount of moisture which later evaporates, rainwater can collect at the base of the chimney. Sometimes weep holes are placed at the bottom of the chimney to drain out collected water. A chimney cowl or wind directional cap is a helmet-shaped chimney cap that rotates to align with the wind and prevent

6500-459: The chimney is built. A refractory cement is used between each tile. Metal liners may be stainless steel, aluminum, or galvanized iron and may be flexible or rigid pipes. Stainless steel is made in several types and thicknesses. Type 304 is used with firewood , wood pellet fuel , and non-condensing oil appliances, types 316 and 321 with coal, and type AL 29-4C is used with high efficiency condensing gas appliances. Stainless steel liners must have

6600-430: The chimney's draft . A chimney with more than one pot on it indicates that multiple fireplaces on different floors share the chimney. A cowl is placed on top of the chimney to prevent birds and other animals from nesting in the chimney. They often feature a rain guard to prevent rain or snow from going down the chimney. A metal wire mesh is often used as a spark arrestor to minimize burning debris from rising out of

6700-435: The cooling of the gases before emission can cause creosote to condense near the top of the chimney. The creosote can restrict the exit of flue gases and may pose a fire hazard. Designing chimneys and stacks to provide the correct amount of natural draft involves a number of design factors, many of which require iterative trial-and-error methods. As a "first guess" approximation, the following equation can be used to estimate

6800-489: The course of the Earth's history, have remained in the crust instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high crustal abundance of 14 ppm; it is the 36th most abundant element in the crust. The main lead-bearing mineral is galena (PbS), which is mostly found with zinc ores. Most other lead minerals are related to galena in some way; boulangerite , Pb 5 Sb 4 S 11 ,

6900-419: The current age of the universe). Three of the stable isotopes are found in three of the four major decay chains : lead-206, lead-207, and lead-208 are the final decay products of uranium-238 , uranium-235 , and thorium-232 , respectively. These decay chains are called the uranium chain , the actinium chain , and the thorium chain . Their isotopic concentrations in a natural rock sample depends greatly on

7000-428: The diiodide . Many lead(II) pseudohalides are known, such as the cyanide, cyanate, and thiocyanate . Lead(II) forms an extensive variety of halide coordination complexes , such as [PbCl 4 ] , [PbCl 6 ] , and the [Pb 2 Cl 9 ] n chain anion. Lead(II) sulfate is insoluble in water, like the sulfates of other heavy divalent cations . Lead(II) nitrate and lead(II) acetate are very soluble, and this

7100-525: The eastern and southern Africans used lead in wire drawing . Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor from 3000 BC; later, lead deposits were developed in the Aegean and Laurion . These three regions collectively dominated production of mined lead until c.  1200 BC . Beginning c. 2000 BC,

7200-578: The element its chemical symbol Pb . The word * ɸloud-io- is thought to be the origin of Proto-Germanic * bliwa- (which also means 'lead'), from which stemmed the German Blei . The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic * laidijan- ('to lead'). Metallic lead beads dating back to 7000–6500 BC have been found in Asia Minor and may represent

7300-421: The exhaust. Sometimes chimneys were converted into radio towers and are not useable as ventilation structure any more. As chimneys are often the tallest part of a factory, they offer the possibility as advertising billboard either by writing the name of the company to which they belong on the shaft or by installing advertisement boards on their structure. At some power stations, which are equipped with plants for

7400-407: The fireplace from the chimney. The advantage of a top damper is the tight weatherproof seal that it provides when closed, which prevents cold outside air from flowing down the chimney and into the living space—a feature that can rarely be matched by the metal-on-metal seal afforded by a throat damper. Additionally, because the throat damper is subjected to intense heat from the fire directly below, it

7500-413: The first example of metal smelting . At that time, lead had few (if any) applications due to its softness and dull appearance. The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral). The Ancient Egyptians were the first to use lead minerals in cosmetics, an application that spread to Ancient Greece and beyond;

7600-430: The group. Lead dihalides are well-characterized; this includes the diastatide and mixed halides, such as PbFCl. The relative insolubility of the latter forms a useful basis for the gravimetric determination of fluorine. The difluoride was the first solid ionically conducting compound to be discovered (in 1834, by Michael Faraday ). The other dihalides decompose on exposure to ultraviolet or visible light, especially

7700-449: The inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization. Rather than having a diamond cubic structure, lead forms metallic bonds in which only the p-electrons are delocalized and shared between the Pb ions. Lead consequently has a face-centered cubic structure like

7800-469: The inside of these long chimneys, and periodically workers would be sent along the chimneys to scrape off these valuable deposits. As a result of the limited ability to handle transverse loads with brick, chimneys in houses were often built in a "stack", with a fireplace on each floor of the house sharing a single chimney, often with such a stack at the front and back of the house. Today's central heating systems have made chimney placement less critical, and

7900-426: The interior space, and can be opened to permit hot gases to exhaust when a fire is burning. A top damper or cap damper is a metal spring door placed at the top of the chimney with a long metal chain that allows one to open and close the damper from the fireplace. A throat damper is a metal plate at the base of the chimney, just above the firebox, that can be opened and closed by a lever, gear, or chain to seal off

8000-399: The late 18th century. Chimneys in ordinary dwellings were first built of wood and plaster or mud. Since then chimneys have traditionally been built of brick or stone, both in small and large buildings. Early chimneys were of simple brick construction. Later chimneys were constructed by placing the bricks around tile liners. To control downdrafts, venting caps (often called chimney pots ) with

8100-447: The late 19th century AD. A lead atom has 82 electrons , arranged in an electron configuration of [ Xe ]4f 5d 6s 6p . The sum of lead's first and second ionization energies —the total energy required to remove the two 6p electrons—is close to that of tin , lead's upper neighbor in the carbon group . This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from

8200-560: The latter being stable only above around 488 °C. Litharge is the most commonly used inorganic compound of lead. There is no lead(II) hydroxide; increasing the pH of solutions of lead(II) salts leads to hydrolysis and condensation. Lead commonly reacts with heavier chalcogens. Lead sulfide is a semiconductor , a photoconductor , and an extremely sensitive infrared radiation detector . The other two chalcogenides, lead selenide and lead telluride , are likewise photoconducting. They are unusual in that their color becomes lighter going down

8300-441: The latter is not; this allows for lead–lead dating . As uranium decays into lead, their relative amounts change; this is the basis for uranium–lead dating . Lead-207 exhibits nuclear magnetic resonance , a property that has been used to study its compounds in solution and solid state, including in the human body. Apart from the stable isotopes, which make up almost all lead that exists naturally, there are trace quantities of

8400-461: The lighter members of the group, lead tends to bond with itself ; it can form chains and polyhedral structures. Since lead is easily extracted from its ores , prehistoric people in the Near East were aware of it . Galena is a principal ore of lead which often bears silver. Interest in silver helped initiate widespread extraction and use of lead in ancient Rome . Lead production declined after

8500-529: The natural draught/draft flow rate by assuming that the molecular mass (i.e., molecular weight) of the flue gas and the external air are equal and that the frictional pressure and heat losses are negligible: Q = C A 2 g H T i − T e T e {\displaystyle Q=C\,A\,{\sqrt {2\,g\,H\,{\frac {T_{i}-T_{e}}{T_{e}}}}}} where: Combining two flows into chimney: A t + A f < A , where A t =7.1 inch

8600-539: The neutrons are arranged in complete shells in the atomic nucleus, and it becomes harder to energetically accommodate more of them. When the neutron flux subsides, these nuclei beta decay into stable isotopes of osmium , iridium , platinum . Lead is classified as a chalcophile under the Goldschmidt classification , meaning it is generally found combined with sulfur. It rarely occurs in its native , metallic form. Many lead minerals are relatively light and, over

8700-462: The power plant has been shut down. Until 2020, the power station will be kept as cold-reserve. Afterwards, the power plant will be decommissioned. This article about a building or structure in Lower Saxony is a stub . You can help Misplaced Pages by expanding it . This article about a Germany power station is a stub . You can help Misplaced Pages by expanding it . Chimney A chimney

8800-418: The preparation of sweeteners and preservatives added to wine and food. The lead conferred an agreeable taste due to the formation of "sugar of lead" ( lead(II) acetate ), whereas copper vessels imparted a bitter flavor through verdigris formation. This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic

8900-414: The presence of the Pb ion in water generally rely on the precipitation of lead(II) chloride using dilute hydrochloric acid. As the chloride salt is sparingly soluble in water, in very dilute solutions the precipitation of lead(II) sulfide is instead achieved by bubbling hydrogen sulfide through the solution. Lead monoxide exists in two polymorphs , litharge α-PbO (red) and massicot β-PbO (yellow),

9000-422: The presence of these three parent uranium and thorium isotopes. For example, the relative abundance of lead-208 can range from 52% in normal samples to 90% in thorium ores; for this reason, the standard atomic weight of lead is given to only one decimal place. As time passes, the ratio of lead-206 and lead-207 to lead-204 increases, since the former two are supplemented by radioactive decay of heavier elements while

9100-432: The r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a supernova or the merger of two neutron stars . The neutron flux involved may be on the order of 10 neutrons per square centimeter per second. The r-process does not form as much lead as the s-process. It tends to stop once neutron-rich nuclei reach 126 neutrons. At this point,

9200-629: The removal of sulfur dioxide and nitrogen oxides , it is possible to use the cooling tower as a chimney. Such cooling towers can be seen in Germany at the Großkrotzenburg Power Station and at the Rostock Power Station . At power stations that are not equipped for removing sulfur dioxide, such usage of cooling towers could result in serious corrosion problems which are not easy to prevent. Download coordinates as: Lead Lead (pronounced "led")

9300-541: The resulting chloride layer diminishes the reactivity of the elements. Molten lead reacts with the chalcogens to give lead(II) chalcogenides. Lead metal resists sulfuric and phosphoric acid but not hydrochloric or nitric acid ; the outcome depends on insolubility and subsequent passivation of the product salt. Organic acids, such as acetic acid , dissolve lead in the presence of oxygen. Concentrated alkalis dissolve lead and form plumbites . Lead shows two main oxidation states: +4 and +2. The tetravalent state

9400-518: The same meaning. There is no consensus on the origin of the Proto-Germanic * lauda- . One hypothesis suggests it is derived from Proto-Indo-European * lAudh- ('lead'; capitalization of the vowel is equivalent to the macron). Another hypothesis suggests it is borrowed from Proto-Celtic * ɸloud-io- ('lead'). This word is related to the Latin plumbum , which gave

9500-491: The similarly sized divalent metals calcium and strontium . Pure lead has a bright, shiny gray appearance with a hint of blue. It tarnishes on contact with moist air and takes on a dull appearance, the hue of which depends on the prevailing conditions. Characteristic properties of lead include high density , malleability, ductility, and high resistance to corrosion due to passivation . Lead's close-packed face-centered cubic structure and high atomic weight result in

9600-588: The simplest organic compound , methane , is plumbane . Plumbane may be obtained in a reaction between metallic lead and atomic hydrogen. Two simple derivatives, tetramethyllead and tetraethyllead , are the best-known organolead compounds. These compounds are relatively stable: tetraethyllead only starts to decompose if heated or if exposed to sunlight or ultraviolet light. With sodium metal, lead readily forms an equimolar alloy that reacts with alkyl halides to form organometallic compounds such as tetraethyllead. The oxidizing nature of many organolead compounds

9700-421: The smoke into a chimney. These were typically much wider than modern chimneys and started relatively high above the fire, meaning more heat could escape into the room. Because the air going up the shaft was cooler, these could be made of less fireproof materials. Another step in the development of chimneys was the use of built-in ovens which allowed the household to bake at home. Industrial chimneys became common in

9800-404: The use of non-structural gas vent pipe allows a flue gas conduit to be installed around obstructions and through walls. Most modern high-efficiency heating appliances do not require a chimney. Such appliances are generally installed near an external wall, and a noncombustible wall thimble allows a vent pipe to run directly through the external wall. On a pitched roof where a chimney penetrates

9900-403: The very rare cluster decay of radium-223, one of the daughter products of natural uranium-235, and the decay chain of neptunium-237, traces of which are produced by neutron capture in uranium ores. Lead-213 also occurs in the decay chain of neptunium-237. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in

10000-534: Was used to make sling bullets from the 5th century BC. In Roman times, lead sling bullets were amply used, and were effective at a distance of between 100 and 150 meters. The Balearic slingers , used as mercenaries in Carthaginian and Roman armies, were famous for their shooting distance and accuracy. Lead was used for making water pipes in the Roman Empire ; the Latin word for the metal, plumbum ,

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