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Dinitrogen tetroxide , commonly referred to as nitrogen tetroxide ( NTO ), and occasionally (usually among ex-USSR/Russian rocket engineers) as amyl , is the chemical compound N 2 O 4 . It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide . Its molar mass is 92.011 g/mol.

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61-492: The Hwasong-14 ( Korean :  《화성-14》형 ; Hanja :  火星 14型 ; lit.   Mars Type 14), also known under alternative US designation codename KN-20 , is a mobile intercontinental ballistic missile developed by North Korea . It had its maiden flight on 4 July 2017, which coincided with the United States' Independence Day . North Korea is the only known operator of this missile. The Hwasong-14

122-641: A foreign language ) is also generated by longstanding alliances, military involvement, and diplomacy, such as between South Korea–United States and China–North Korea since the end of World War II and the Korean War . Along with other languages such as Chinese and Arabic , Korean is ranked at the top difficulty level for English speakers by the United States Department of Defense . Modern Korean descends from Middle Korean , which in turn descends from Old Korean , which descends from

183-601: A petroleum benzine to a spark plug for ignition, with the engine putting out 300 pulsating explosions per minute. Paulet would go on to visit the German rocket association Verein für Raumschiffahrt (VfR) and on March 15, 1928, Valier applauded Paulet's liquid-propelled rocket design in the VfR publication Die Rakete , saying the engine had "amazing power". Paulet would soon be approached by Nazi Germany to help develop rocket technology, though he refused to assist and never shared

244-415: A 200 kg (440 lb) reentry vehicle , giving the missile its maximum range of 10,400 km (6,500 mi), enough to reach New York City but not Washington D.C. , although such a payload is much lighter than North Korea is believed to be capable of weaponizing. The missile is launched from a detachable platform on a concrete pad. This could have several operational ramifications. It may increase

305-484: A Korean influence on Khitan. The hypothesis that Korean could be related to Japanese has had some supporters due to some overlap in vocabulary and similar grammatical features that have been elaborated upon by such researchers as Samuel E. Martin and Roy Andrew Miller . Sergei Starostin (1991) found about 25% of potential cognates in the Japanese–Korean 100-word Swadesh list . Some linguists concerned with

366-480: A core vowel. The IPA symbol ⟨ ◌͈ ⟩ ( U+0348 ◌͈ COMBINING DOUBLE VERTICAL LINE BELOW ) is used to denote the tensed consonants /p͈/, /t͈/, /k͈/, /t͡ɕ͈/, /s͈/ . Its official use in the extensions to the IPA is for "strong" articulation, but is used in the literature for faucalized voice . The Korean consonants also have elements of stiff voice , but it is not yet known how typical this

427-526: A first-generation nuclear warhead to Anchorage, Alaska . But even if North Korea is now capable of fabricating a relatively light-weight, "miniaturized" atomic bomb that can survive the extreme reentry environments of long-range rocket delivery, it will, with certainty, not be able to deliver such an atomic bomb to the lower 48 states of the United States with the rocket tested on 3 July and 28 July. A first-generation North Korean nuclear missile warhead

488-545: A later founder effect diminished the internal variety of both language families. Since the establishment of two independent governments, North–South differences have developed in standard Korean, including variations in pronunciation and vocabulary chosen. However, these minor differences can be found in any of the Korean dialects , which are still largely mutually intelligible . The Chinese language , written with Chinese characters and read with Sino-Xenic pronunciations ,

549-574: A possible relationship.) Hudson & Robbeets (2020) suggested that there are traces of a pre- Nivkh substratum in Korean. According to the hypothesis, ancestral varieties of Nivkh (also known as Amuric ) were once distributed on the Korean Peninsula before the arrival of Koreanic speakers. Korean syllable structure is (C)(G)V(C), consisting of an optional onset consonant, glide /j, w, ɰ/ and final coda /p, t, k, m, n, ŋ, l/ surrounding

610-425: A so-called dissociating gas. "Cool" dinitrogen tetroxide is compressed and heated, causing it to dissociate into nitrogen dioxide at half the molecular weight. This hot nitrogen dioxide is expanded through a turbine, cooling it and lowering the pressure, and then cooled further in a heat sink, causing it to recombine into nitrogen tetroxide at the original molecular weight. It is then much easier to compress to start

671-474: A substantially reduced payload. Korean language Korean ( South Korean : 한국어 , Hanguk-eo ; North Korean : 조선어 , Chosŏnŏ ) is the native language for about 81 million people, mostly of Korean descent. It is the national language of both North Korea and South Korea . Beyond Korea, the language is recognized as a minority language in parts of China , namely Jilin , and specifically Yanbian Prefecture , and Changbai County . It

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732-632: A total flight time of approximately 47 minutes. Based on the data from the test flight, if the missile were fired at the optimal efficient trajectory, it is predicted that the maximum effective range would exceed 10,000 km (6,200 mi). If factoring in the rotation of the Earth, which may provide a range boost when travelling eastward, the Hwasong-14’s coverage area would include the US West Coast, Chicago, and possibly even New York, but only with

793-559: Is a hypergolic propellant in combination with a hydrazine -based rocket fuel . One of the earliest uses of this combination was on the Titan family of rockets used originally as ICBMs and then as launch vehicles for many spacecraft. Used on the U.S. Gemini and Apollo spacecraft and also on the Space Shuttle , it continues to be used as station-keeping propellant on most geo-stationary satellites, and many deep-space probes. It

854-641: Is also spoken by Sakhalin Koreans in parts of Sakhalin , the Russian island just north of Japan, and by the Koryo-saram in parts of Central Asia . The language has a few extinct relatives which—along with the Jeju language (Jejuan) of Jeju Island and Korean itself—form the compact Koreanic language family . Even so, Jejuan and Korean are not mutually intelligible . The linguistic homeland of Korean

915-401: Is also the primary oxidizer for Russia's Proton rocket . When used as a propellant, dinitrogen tetroxide is usually referred to simply as nitrogen tetroxide and the abbreviation NTO is extensively used. Additionally, NTO is often used with the addition of a small percentage of nitric oxide , which inhibits stress-corrosion cracking of titanium alloys, and in this form, propellant-grade NTO

976-656: Is an agglutinative language . The Korean language is traditionally considered to have nine parts of speech . Modifiers generally precede the modified words, and in the case of verb modifiers, can be serially appended. The sentence structure or basic form of a Korean sentence is subject–object–verb (SOV), but the verb is the only required and immovable element and word order is highly flexible, as in many other agglutinative languages. Question 가게에 gage-e store- LOC 가셨어요? ga-syeo-sseo-yo go- HON . PAST - CONJ - POL 가게에 가셨어요? gage-e ga-syeo-sseo-yo store-LOC go-HON.PAST-CONJ-POL 'Did [you] go to

1037-511: Is closer to a near-open central vowel ( [ɐ] ), though ⟨a⟩ is still used for tradition. Grammatical morphemes may change shape depending on the preceding sounds. Examples include -eun/-neun ( -은/-는 ) and -i/-ga ( -이/-가 ). Sometimes sounds may be inserted instead. Examples include -eul/-reul ( -을/-를 ), -euro/-ro ( -으로/-로 ), -eseo/-seo ( -에서/-서 ), -ideunji/-deunji ( -이든지/-든지 ) and -iya/-ya ( -이야/-야 ). Some verbs may also change shape morphophonemically. Korean

1098-667: Is estimated to weigh 500–600 kg (1,100–1,300 lb). Calculations of the range of the Hwasong-14 carrying such a payload vary from 6,000 km (3,700 mi), enough to reach Anchorage, to as much as 8,000 km (5,000 mi), enough to reach Honolulu, Hawaii and Seattle, Washington ; the Bulletin of the Atomic Scientists claimed the payload would need to be lighter at 300 kg (660 lb) to be able to reach Seattle. The July 2017 tests were conducted with

1159-665: Is likely a two-staged version of the Hwasong-12 first tested in May 2017. The second stage appears to have increased its range. The first stage engine appears very similar to the Hwasong-12. With a single liquid fuel engine, it has four Vernier thrusters for stability and guidance. A detailed analysis by the Bulletin of the Atomic Scientists claims that the current variant of the Hwasong-14 may not even be capable of delivering

1220-399: Is mainly reserved for specific circumstances such as newspapers, scholarly papers and disambiguation. Today Hanja is largely unused in everyday life but is still important for historical and linguistic studies. The Korean names for the language are based on the names for Korea used in both South Korea and North Korea. The English word "Korean" is derived from Goryeo , which is thought to be

1281-494: Is manufactured on a large scale via N 2 O 4 . This species reacts with water to give both nitrous acid and nitric acid : The coproduct HNO 2 upon heating disproportionates to NO and more nitric acid. When exposed to oxygen, NO is converted back into nitrogen dioxide: The resulting NO 2 and N 2 O 4 can be returned to the cycle to give the mixture of nitrous and nitric acids again. N 2 O 4 undergoes molecular autoionization to give [NO ] [NO 3 ], with

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1342-399: Is of faucalized consonants. They are produced with a partially constricted glottis and additional subglottal pressure in addition to tense vocal tract walls, laryngeal lowering, or other expansion of the larynx. /s/ is aspirated [sʰ] and becomes an alveolo-palatal [ɕʰ] before [j] or [i] for most speakers (but see North–South differences in the Korean language ). This occurs with

1403-419: Is planar with an N-N bond distance of 1.78   Å and N-O distances of 1.19   Å. The N-N distance corresponds to a weak bond, since it is significantly longer than the average N-N single bond length of 1.45   Å. This exceptionally weak σ bond (amounting to overlapping of the sp hybrid orbitals of the two NO 2 units ) results from the simultaneous delocalization of the bonding electron pair across

1464-562: Is referred to as mixed oxides of nitrogen ( MON ). Most spacecraft now use MON instead of NTO; for example, the Space Shuttle reaction control system used MON3 (NTO containing 3% NO by weight). On 24 July 1975, NTO poisoning affected three U.S. astronauts on the final descent to Earth after the Apollo-Soyuz Test Project flight. This was due to a switch accidentally left in the wrong position, which allowed

1525-593: Is similar to the upper stages designed for the Iranian space launch vehicles". The first publicly announced flight test was on 4 July 2017, to coincide with the US Independence Day celebrations. This flight had a claimed range of 933 kilometres (580 miles) eastwards into the Sea of Japan (East Sea of Korea) and reached an altitude of 2,802 kilometres (9,193,000 ft) during a 39-minute flight. This range

1586-544: Is suggested to be somewhere in contemporary Manchuria . The hierarchy of the society from which the language originates deeply influences the language, leading to a system of speech levels and honorifics indicative of the formality of any given situation. Modern Korean is written in the Korean script ( 한글 ; Hangeul in South Korea, 조선글 ; Chosŏn'gŭl in North Korea), a system developed during

1647-435: Is then purified and condensed to form dinitrogen tetroxide. Nitrogen tetroxide is used as an oxidizing agent in one of the most important rocket propellant systems because it can be stored as a liquid at room temperature. Pedro Paulet , a Peruvian polymath , reported in 1927 that he had experimented in the 1890s with a rocket engine that used spring-loaded nozzles that periodically introduced vaporized nitrogen tetroxide and

1708-747: Is well attested in Western Old Japanese and Northern Ryukyuan languages , in Eastern Old Japanese it only occurs in compounds, and it is only present in three dialects of the Southern Ryukyuan language group . Also, the doublet wo meaning "hemp" is attested in Western Old Japanese and Southern Ryukyuan languages. It is thus plausible to assume a borrowed term. (See Classification of the Japonic languages or Comparison of Japanese and Korean for further details on

1769-527: The yangban aristocracy, who looked down upon it too easy to learn. However, it gained widespread use among the common class and was widely used to print popular novels which were enjoyed by the common class. Since few people could understand official documents written in classical Chinese, Korean kings sometimes released public notices entirely written in Hangul as early as the 16th century for all Korean classes, including uneducated peasants and slaves. By

1830-622: The Hwasong-12 and -14. According to his theory an unknown number of these engines were probably acquired through illicit channels operating in Russia and/or Ukraine . North Korea’s need for an alternative to the failing Musudan and the recent appearance of the RD-250 engine along with other evidence, suggests the transfers occurred in 2015–2017. Ukraine rejected this theory claiming it was "most likely provoked by Russian secret services to cover their own crimes." Other US experts have questioned whether

1891-589: The Proto-Koreanic language , which is generally suggested to have its linguistic homeland somewhere in Manchuria . Whitman (2012) suggests that the proto-Koreans, already present in northern Korea, expanded into the southern part of the Korean Peninsula at around 300 BC and coexisted with the descendants of the Japonic Mumun cultivators (or assimilated them). Both had influence on each other and

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1952-568: The Three Kingdoms of Korea (not the ancient confederacies in the southern Korean Peninsula), while " -eo " and " -mal " mean "language" and "speech", respectively. Korean is also simply referred to as guk-eo , literally "national language". This name is based on the same Han characters ( 國語 "nation" + "language") that are also used in Taiwan and Japan to refer to their respective national languages. In North Korea and China ,

2013-414: The attitude control thrusters to fire after the cabin fresh air intake was opened, allowing NTO fumes to enter the cabin. One crew member lost consciousness during descent. Upon landing, the crew was hospitalized for five days for chemical-induced pneumonia and edema . The tendency of N 2 O 4 to reversibly break into NO 2 has led to research into its use in advanced power generation systems as

2074-473: The 15th century for that purpose, although it did not become the primary script until the 20th century. The script uses 24 basic letters ( jamo ) and 27 complex letters formed from the basic ones. When first recorded in historical texts, Korean was only a spoken language . Since the turn of the 21st century, aspects of Korean culture have spread to other countries through globalization and cultural exports . As such, interest in Korean language acquisition (as

2135-829: The 17th century, the yangban had exchanged Hangul letters with slaves, which suggests a high literacy rate of Hangul during the Joseon era. In the context of growing Korean nationalism in the 19th century, the Gabo Reform of 1894 abolished the Confucian examinations and decreed that government documents would be issued in Hangul instead of literary Chinese. Some newspapers were published entirely in Hangul, but other publications used Korean mixed script , with Hanja for Sino-Korean vocabulary and Hangul for other elements. North Korea abolished Hanja in writing in 1949, but continues to teach them in schools. Their usage in South Korea

2196-512: The Earth’s rotation. If true, then this brings the U.S. states of Alaska and Hawaii within the missile's range. Preparations for a second test flight were detected by US intelligence as early as 20 July. On 28 July, the missile was fired at 11:41 p.m local time, the first time which a night time launch was carried out. The missile was fired at a lofted trajectory with apogee of 3,700 km (2,300 mi), landing 998 km (620 mi) away with

2257-803: The Tsyklon rockets...They have these engines, they have the documentation. They can supply these engines from the finished rockets to whoever they want.” The agency also claimed that a total of 223 Tsyklon-2 and Tsyklon-3 rockets were supplied to Russia. Furthermore, he stated that North Korea cannot produce the fuel for the RD-250 ( N 2 O 4 and UDMH ), and that it must have been produced either in China or in Ukraine. According to South Korean intelligence, North Korea received 20 to 40 RD-251 engines from Russia in 2016. Arms expert Jeffrey Lewis claimed that "The second stage of North Korea's Hwasong-14 missile

2318-568: The anhydrous transition metal nitrates have striking colours. This branch of chemistry was developed by Cliff Addison and Norman Logan at the University of Nottingham in the UK during the 1960s and 1970s when highly efficient desiccants and dry boxes started to become available. In even slightly basic solvents, N 2 O 4 adds to alkenes radically, giving mixtures of nitro compounds and nitrite esters . Pure or in entirely nonbasic solvents,

2379-455: The beginnings of words. /l/ becomes alveolar flap [ɾ] between vowels, and [l] or [ɭ] at the end of a syllable or next to another /l/ . A written syllable-final ' ㄹ ', when followed by a vowel or a glide ( i.e. , when the next character starts with ' ㅇ '), migrates to the next syllable and thus becomes [ɾ] . Traditionally, /l/ was disallowed at the beginning of a word. It disappeared before [j] , and otherwise became /n/ . However,

2440-474: The entire cycle again. Such dissociative gas Brayton cycles have the potential to considerably increase efficiencies of power conversion equipment. The high molecular weight and smaller volumetric expansion ratio of nitrogen dioxide compared to steam allows the turbines to be more compact. N 2 O 4 was the main component of the "nitrin" working fluid in the decommissioned Pamir-630D portable nuclear reactor which operated from 1985 to 1987. Nitric acid

2501-490: The equilibrium towards nitrogen dioxide. Inevitably, some dinitrogen tetroxide is a component of smog containing nitrogen dioxide. Solid N 2 O 4 is white, and melts at −11.2 °C. Nitrogen tetroxide is made by the catalytic oxidation of ammonia (the Ostwald process ): steam is used as a diluent to reduce the combustion temperature. In the first step, the ammonia is oxidized into nitric oxide : Most of

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2562-649: The evidence for Elleman's theory is strong enough to back up his claims. Engine maker Yuzhnoye Design Office denied that the engines were supplied to North Korea by Ukraine. In August 2017 the State Space Agency of Ukraine claimed that the rocket engine used during 28 July 2017 North Korea's missile test was RD-250 made at a Ukrainian factory, but solely for use in Tsyklon space rockets supplied to Russia. The space agency chief said that according to Ukrainian information, “Russia today has between 7 and 20” of

2623-399: The first Korean dynasty known to Western nations. Korean people in the former USSR refer to themselves as Koryo-saram or Koryo-in (literally, " Koryo/Goryeo persons"), and call the language Koryo-mal' . Some older English sources also use the spelling "Corea" to refer to the nation, and its inflected form for the language, culture and people, "Korea" becoming more popular in

2684-412: The former nitrosonium ion being a strong oxidant. Various anhydrous transition metal nitrate complexes can be prepared from N 2 O 4 and base metal. where M = Cu , Zn , or Sn . If metal nitrates are prepared from N 2 O 4 in completely anhydrous conditions, a range of covalent metal nitrates can be formed with many transition metals. This is because there is a thermodynamic preference for

2745-458: The formula for his propellant. In early 1944, research on the usability of dinitrogen tetroxide as an oxidizing agent for rocket fuel was conducted by German scientists, although the Germans only used it to a very limited extent as an additive for S-Stoff (fuming nitric acid). It became the storable oxidizer of choice for many rockets in both the United States and USSR by the late 1950s. It

2806-479: The inflow of western loanwords changed the trend, and now word-initial /l/ (mostly from English loanwords) are pronounced as a free variation of either [ɾ] or [l] . All obstruents (plosives, affricates, fricatives) at the end of a word are pronounced with no audible release , [p̚, t̚, k̚] . Plosive sounds /p, t, k/ become nasals [m, n, ŋ] before nasal sounds. Hangul spelling does not reflect these assimilatory pronunciation rules, but rather maintains

2867-408: The issue between Japanese and Korean, including Alexander Vovin, have argued that the indicated similarities are not due to any genetic relationship , but rather to a sprachbund effect and heavy borrowing, especially from Ancient Korean into Western Old Japanese . A good example might be Middle Korean sàm and Japanese asá , meaning " hemp ". This word seems to be a cognate, but although it

2928-639: The language is most often called Joseon-mal , or more formally, Joseon-o . This is taken from the North Korean name for Korea (Joseon), a name retained from the Joseon dynasty until the proclamation of the Korean Empire , which in turn was annexed by the Empire of Japan . In mainland China , following the establishment of diplomatic relations with South Korea in 1992, the term Cháoxiǎnyǔ or

2989-455: The late 1800s. In South Korea the Korean language is referred to by many names including hanguk-eo ("Korean language"), hanguk-mal ("Korean speech") and uri-mal ("our language"); " hanguk " is taken from the name of the Korean Empire ( 대한제국 ; 大韓帝國 ; Daehan Jeguk ). The " han " ( 韓 ) in Hanguk and Daehan Jeguk is derived from Samhan , in reference to

3050-494: The nitrate ion to bond covalently with such metals rather than form an ionic structure. Such compounds must be prepared in anhydrous conditions, since the nitrate ion is a much weaker ligand than water, and if water is present the simple nitrate of the hydrated metal ion will form. The anhydrous nitrates concerned are themselves covalent, and many, e.g. anhydrous copper nitrate , are volatile at room temperature. Anhydrous titanium nitrate sublimes in vacuum at only 40 °C. Many of

3111-515: The population was illiterate. In the 15th century King Sejong the Great personally developed an alphabetic featural writing system , known today as Hangul , to promote literacy among the common people. Introduced in the document Hunminjeongeum , it was called eonmun ('colloquial script') and quickly spread nationwide to increase literacy in Korea. The Korean alphabet was denounced by

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3172-458: The reaction of concentrated nitric acid and metallic copper. This synthesis is practical in a laboratory setting. Dinitrogen tetroxide can also be produced by heating metal nitrates. The oxidation of copper by nitric acid is a complex reaction forming various nitrogen oxides of varying stability which depends on the concentration of the nitric acid, presence of oxygen, and other factors. The unstable species further react to form nitrogen dioxide which

3233-669: The short form Cháoyǔ has normally been used to refer to the standard language of North Korea and Yanbian , whereas Hánguóyǔ or the short form Hányǔ is used to refer to the standard language of South Korea. Korean is a member of the Koreanic family along with the Jeju language . Some linguists have included it in the Altaic family, but the core Altaic proposal itself has lost most of its prior support. The Khitan language has several vocabulary items similar to Korean that are not found in other Mongolian or Tungusic languages, suggesting

3294-446: The store?' Response 예/네. ye/ne AFF Dinitrogen tetroxide Dinitrogen tetroxide is a powerful oxidizer that is hypergolic (spontaneously reacts) upon contact with various forms of hydrazine , which has made the pair a common bipropellant for rockets. Dinitrogen tetroxide could be regarded as two nitro groups (-NO 2 ) bonded together. It forms an equilibrium mixture with nitrogen dioxide . The molecule

3355-441: The tense fricative and all the affricates as well. At the end of a syllable, /s/ changes to /t/ (example: beoseot ( 버섯 ) 'mushroom'). /h/ may become a bilabial [ɸ] before [o] or [u] , a palatal [ç] before [j] or [i] , a velar [x] before [ɯ] , a voiced [ɦ] between voiced sounds, and a [h] elsewhere. /p, t, t͡ɕ, k/ become voiced [b, d, d͡ʑ, ɡ] between voiced sounds. /m, n/ frequently denasalize at

3416-515: The time required to launch the Hwasong-12, and limit the number of launch locations to pre-sited and pre-constructed launch pads. Michael Elleman of IISS and the Bulletin of the Atomic Scientists both claim that available evidence clearly indicates that the engine is based on the Soviet RD-250 family of engines for the R-36 missile, and has been modified to operate as the boosting force for

3477-464: The underlying, partly historical morphology . Given this, it is sometimes hard to tell which actual phonemes are present in a certain word. The traditional prohibition of word-initial /ɾ/ became a morphological rule called "initial law" ( 두음법칙 ) in the pronunciation standards of South Korea, which pertains to Sino-Korean vocabulary. Such words retain their word-initial /ɾ/ in the pronunciation standards of North Korea. For example, ^NOTE ㅏ

3538-409: The water is condensed out, and the gases are further cooled; the nitric oxide that was produced is oxidized to nitrogen dioxide, which is then dimerized into nitrogen tetroxide: and the remainder of the water is removed as nitric acid . The gas is essentially pure nitrogen dioxide, which is condensed into dinitrogen tetroxide in a brine-cooled liquefier. Dinitrogen tetroxide can also be made through

3599-399: The whole N 2 O 4 molecule, and the considerable electrostatic repulsion of the doubly occupied molecular orbitals of each NO 2 unit. Unlike NO 2 , N 2 O 4 is diamagnetic since it has no unpaired electrons. The liquid is also colorless but can appear as a brownish yellow liquid due to the presence of NO 2 according to the following equilibrium: Higher temperatures push

3660-488: Was deliberately shortened, to avoid encroaching on other nations' territory, by 'lofting' the missile: firing it on a trajectory that was inefficiently high, rather than optimised for range. This allows the missile's performance to be tested and demonstrated, without requiring a huge test range. A prediction for the possible range, following an optimum trajectory, has been given at 6,700 kilometres (4,200 miles) or as much as 10,400 kilometres (6,500 miles) not taking into account

3721-487: Was first introduced to Korea in the 1st century BC, and remained the medium of formal writing and government until the late 19th century. Korean scholars adapted Chinese characters (known in Korean as Hanja ) to write their own language, creating scripts known as idu , hyangchal , gugyeol , and gakpil. These systems were cumbersome, due to the fundamental disparities between the Korean and Chinese languages, and accessible only to those educated in classical Chinese. Most of

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