The Mercedes-Benz C111 was a series of experimental automobiles produced by Daimler-Benz in the 1960s and 1970s. The company was experimenting with new engine technologies, including Wankel engines , diesel engines , and turbochargers , and used the basic C111 platform as a testbed. Other experimental features included multi-link rear suspension , gull-wing doors and a luxurious interior with leather trim and air conditioning .
113-529: The first version of the C111 was completed in 1969, and presented at the 1969 IAA in Frankfurt. The car used a fiberglass body shell and with a mid-mounted three-rotor direct fuel injected Wankel engine (code named M950F ). The next C111 appeared in 1970; it was shown at the 1970 Geneva International Motor Show . It used a four-rotor engine producing 260 kW (349 hp). The car reportedly could reach
226-465: A de facto official language of Namibia after the end of German colonial rule alongside English and Afrikaans , and had de jure co-official status from 1984 until its independence from South Africa in 1990. However, the Namibian government perceived Afrikaans and German as symbols of apartheid and colonialism, and decided English would be the sole official language upon independence, stating that it
339-424: A glass with no true melting point, can be used as a glass fiber for fiberglass but has the drawback that it must be worked at very high temperatures. In order to lower the necessary work temperature, other materials are introduced as "fluxing agents" (i.e., components to lower the melting point). Ordinary A-glass ("A" for "alkali-lime") or soda lime glass, crushed and ready to be remelted, as so-called cullet glass,
452-402: A second language , and 75–100 million as a foreign language . This would imply the existence of approximately 175–220 million German speakers worldwide. German sociolinguist Ulrich Ammon estimated a number of 289 million German foreign language speakers without clarifying the criteria by which he classified a speaker. As of 2012 , about 90 million people, or 16% of
565-842: A thermoset polymer matrix —most often based on thermosetting polymers such as epoxy , polyester resin , or vinyl ester resin —or a thermoplastic . Cheaper and more flexible than carbon fiber , it is stronger than many metals by weight, non- magnetic , non- conductive , transparent to electromagnetic radiation , can be molded into complex shapes, and is chemically inert under many circumstances. Applications include aircraft, boats, automobiles, bath tubs and enclosures, swimming pools , hot tubs , septic tanks , water tanks , roofing, pipes, cladding, orthopedic casts , surfboards , and external door skins. Other common names for fiberglass are glass-reinforced plastic ( GRP ), glass-fiber reinforced plastic ( GFRP ) or GFK (from German : Glasfaserverstärkter Kunststoff ). Because glass fiber itself
678-612: A "commonly used" language and the Pan South African Language Board is obligated to promote and ensure respect for it. Cameroon was also a colony of the German Empire from the same period (1884 to 1916). However, German was replaced by French and English, the languages of the two successor colonial powers, after its loss in World War I . Nevertheless, since the 21st century, German has become
791-556: A 5 mg/m total limit. As of 2001, the Hazardous Substances Ordinance in Germany dictates a maximum occupational exposure limit of 86 mg/m . In certain concentrations, a potentially explosive mixture may occur. Further manufacture of GRP components (grinding, cutting, sawing) creates fine dust and chips containing glass filaments, as well as tacky dust, in quantities high enough to affect health and
904-828: A BMEP of 1.68 MPa, resulting in a maximum torque of 401 N·m at 3600 min. It enabled the C ;111 III to reach a top speed of 338 km/h (210 mph) at the Nardò Ring in 1978, and also to average a 16 l/100 km fuel consumption at an average speed of 325 km/h. The engine was fitted with an M-type inline injection pump of Bosch's PE series with a maximum injection pressure of 40 MPa. A later 4.5 L twin KKK-turbocharged V8 version that produced 368 kW (493 hp; 500 PS) at 6000/min set another record, with an average lap-speed of 403.78 km/h (250.958 mph). This
1017-621: A November, 2011 modification to its Proposition 65 listing to include only "Glass wool fibers (inhalable and biopersistent)." Therefore a cancer warning label for biosoluble fiber glass home and building insulation is no longer required under federal or California law. As of 2012, the North American Insulation Manufacturers Association stated that fiberglass is safe to manufacture, install and use when recommended work practices are followed to reduce temporary mechanical irritation. As of 2012,
1130-439: A binder. It is typically processed using the hand lay-up technique, where sheets of material are placed on a mold and brushed with resin. Because the binder dissolves in resin, the material easily conforms to different shapes when wetted out. After the resin cures, the hardened product can be taken from the mold and finished. Using chopped strand mat gives the fiberglass isotropic in-plane material properties. A coating or primer
1243-417: A chemical solution. The individual filaments are now bundled in large numbers to provide a roving . The diameter of the filaments, and the number of filaments in the roving, determine its weight , typically expressed in one of two measurement systems: These rovings are then either used directly in a composite application such as pultrusion , filament winding (pipe), gun roving (where an automated gun chops
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#17327838405501356-401: A combined stream from a chopper gun. Workers roll out the spray-up to compact the laminate. Wood, foam or other core material may then be added, and a secondary spray-up layer imbeds the core between the laminates. The part is then cured, cooled, and removed from the reusable mold. Pultrusion is a manufacturing method used to make strong, lightweight composite materials. In pultrusion, material
1469-549: A different turbocharger without a wastegate, which allowed an increased pressure ratio of 3.3. Daimler-Benz also added an intercooler that significantly improved the engine's thermal efficiency. The C 111 III prototype that was completed in 1978, had a more aerodynamic bodywork that gave it an air drag coefficient of 0.195. It had a modified 3-litre version of the Mercedes-Benz OM ;617 five-cylinder Diesel, now producing 170 kW (228 hp), and
1582-559: A greater need for regularity in written conventions. While the major changes of the MHG period were socio-cultural, High German was still undergoing significant linguistic changes in syntax, phonetics, and morphology as well (e.g. diphthongization of certain vowel sounds: hus (OHG & MHG "house") → haus (regionally in later MHG)→ Haus (NHG), and weakening of unstressed short vowels to schwa [ə]: taga (OHG "days")→ tage (MHG)). A great wealth of texts survives from
1695-430: A liner to prevent gas leakage or as a barrier to protect the composite from the fluid to be stored. Filament winding is well suited to automation, and there are many applications, such as pipe and small pressure vessels that are wound and cured without any human intervention. The controlled variables for winding are fiber type, resin content, wind angle, tow or bandwidth and thickness of the fiber bundle. The angle at which
1808-437: A mid-mounted 6.0 L V12 engine . After accepting 700 deposits, the company decided not to proceed with production. Fiberglass Fiberglass ( American English ) or fibreglass ( Commonwealth English ) is a common type of fiber-reinforced plastic using glass fiber . The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth . The plastic matrix may be
1921-458: A native tongue today, mostly descendants of German colonial settlers . The period of German colonialism in Namibia also led to the evolution of a Standard German-based pidgin language called " Namibian Black German ", which became a second language for parts of the indigenous population. Although it is nearly extinct today, some older Namibians still have some knowledge of it. German remained
2034-696: A popular foreign language among pupils and students, with 300,000 people learning or speaking German in Cameroon in 2010 and over 230,000 in 2020. Today Cameroon is one of the African countries outside Namibia with the highest number of people learning German. In the United States, German is the fifth most spoken language in terms of native and second language speakers after English, Spanish , French , and Chinese (with figures for Cantonese and Mandarin combined), with over 1 million total speakers. In
2147-936: A post-exposure recovery period." Historic reviews of the epidemiology studies had been conducted by Harvard's Medical and Public Health Schools in 1995, the National Academy of Sciences in 2000, the Agency for Toxic Substances and Disease Registry ("ATSDR") in 2004, and the National Toxicology Program in 2011. which reached the same conclusion as IARC that there is no evidence of increased risk from occupational exposure to glass wool fibers. Genetic and toxic effects are exerted through production of reactive oxygen species , which can damage DNA, and cause chromosomal aberrations , nuclear abnormalities, mutations, gene amplification in proto-oncogenes , and cell transformation in mammalian cells. There
2260-483: A result, the surviving texts are written in highly disparate regional dialects and exhibit significant Latin influence, particularly in vocabulary. At this point monasteries, where most written works were produced, were dominated by Latin, and German saw only occasional use in official and ecclesiastical writing. While there is no complete agreement over the dates of the Middle High German (MHG) period, it
2373-642: A speed of 300 km/h (186 mph). The company decided not to adopt the Wankel engine and turned to diesel experiments for the second and third C111s. The C111-IID's engine was a Mercedes-Benz OM 617, and produced 140 kW (188 hp) at 4200 min. It was based on the Mercedes-Benz 85 kW variant of the OM ;617 used in the Mercedes-Benz W ;116 S-Class, but had
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#17327838405502486-415: A thermoplastic inner tank which acts as a preform during construction. Much more reliable tanks are made using woven mat or filament wound fiber, with the fiber orientation at right angles to the hoop stress imposed in the sidewall by the contents. Such tanks tend to be used for chemical storage because the plastic liner (often polypropylene ) is resistant to a wide range of corrosive chemicals. Fiberglass
2599-427: Is a fabrication technique mainly used for manufacturing open (cylinders) or closed-end structures (pressure vessels or tanks). The process involves winding filaments under tension over a male mandrel. The mandrel rotates while a wind eye on a carriage moves horizontally, laying down fibers in the desired pattern. The most common filaments are carbon or glass fiber and are coated with synthetic resin as they are wound. Once
2712-601: Is a recognized minority language in the following countries: In France, the High German varieties of Alsatian and Moselle Franconian are identified as " regional languages ", but the European Charter for Regional or Minority Languages of 1998 has not yet been ratified by the government. Namibia also was a colony of the German Empire, from 1884 to 1915. About 30,000 people still speak German as
2825-551: Is also indirect, inflammation-driven genotoxicity through reactive oxygen species by inflammatory cells . The longer and thinner as well as the more durable (biopersistent) fibers were, the more potent they were in damage. In the US, fine mineral fiber emissions have been regulated by the EPA , but respirable fibers (“particulates not otherwise regulated”) are regulated by Occupational Safety and Health Administration (OSHA); OSHA has set
2938-612: Is also notable for its broad spectrum of dialects , with many varieties existing in Europe and other parts of the world. Some of these non-standard varieties have become recognized and protected by regional or national governments. Since 2004, heads of state of the German-speaking countries have met every year, and the Council for German Orthography has been the main international body regulating German orthography . German
3051-432: Is also used for septic tanks . Glass-reinforced plastics are also used to produce house building components such as roofing laminate, door surrounds, over-door canopies, window canopies and dormers, chimneys, coping systems, and heads with keystones and sills. The material's reduced weight and easier handling, compared to wood or metal, allows faster installation. Mass-produced fiberglass brick-effect panels can be used in
3164-558: Is an Indo-European language that belongs to the West Germanic group of the Germanic languages . The Germanic languages are traditionally subdivided into three branches: North Germanic , East Germanic , and West Germanic . The first of these branches survives in modern Danish , Swedish , Norwegian , Faroese , and Icelandic , all of which are descended from Old Norse . The East Germanic languages are now extinct, and Gothic
3277-401: Is applied to the chosen mold to allow the finished product to be cleanly removed from the mold. Resin—typically a 2-part thermoset polyester, vinyl, or epoxy—is mixed with its hardener and applied to the surface. Sheets of fiberglass matting are laid into the mold, then more resin mixture is added using a brush or roller. The material must conform to the mold, and air must not be trapped between
3390-479: Is applied to the roving to help protect the glass filaments for processing and manipulation and to ensure proper bonding to the resin matrix, thus allowing for the transfer of shear loads from the glass fibers to the thermoset plastic. Without this bonding, the fibers can 'slip' in the matrix causing localized failure. An individual structural glass fiber is both stiff and strong in tension and compression —that is, along its axis. Although it might be assumed that
3503-483: Is called pultrusion . The manufacturing process for glass fibers suitable for reinforcement uses large furnaces to gradually melt the silica sand, limestone , kaolin clay , fluorspar , colemanite , dolomite and other minerals until a liquid forms. It is then extruded through bushings ( spinneret ), which are bundles of very small orifices (typically 5–25 micrometres in diameter for E-Glass, 9 micrometres for S-Glass). These filaments are then sized (coated) with
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3616-478: Is called the "German Sprachraum ". German is the official language of the following countries: German is a co-official language of the following countries: Although expulsions and (forced) assimilation after the two World wars greatly diminished them, minority communities of mostly bilingual German native speakers exist in areas both adjacent to and detached from the Sprachraum. Within Europe, German
3729-430: Is complicated by the existence of several varieties whose status as separate "languages" or "dialects" is disputed for political and linguistic reasons, including quantitatively strong varieties like certain forms of Alemannic and Low German . With the inclusion or exclusion of certain varieties, it is estimated that approximately 90–95 million people speak German as a first language , 10–25 million speak it as
3842-529: Is credited with producing the first composite boat in 1937 but did not proceed further at the time because of the brittle nature of the plastic used. In 1939 Russia was reported to have constructed a passenger boat of plastic materials, and the United States a fuselage and wings of an aircraft. The first car to have a fiberglass body was a 1946 prototype of the Stout Scarab , but the model did not enter production. Unlike glass fibers used for insulation, for
3955-401: Is essentially an entire two-dimensional plane; with woven fabrics or unidirectional layers, directionality of stiffness and strength can be more precisely controlled within the plane. A fiberglass component is typically of a thin "shell" construction, sometimes filled on the inside with structural foam, as in the case of surfboards. The component may be of nearly arbitrary shape, limited only by
4068-535: Is generally seen as ending when the 1346–53 Black Death decimated Europe's population. Modern High German begins with the Early New High German (ENHG) period, which Wilhelm Scherer dates 1350–1650, terminating with the end of the Thirty Years' War . This period saw the further displacement of Latin by German as the primary language of courtly proceedings and, increasingly, of literature in
4181-611: Is generally seen as lasting from 1050 to 1350. This was a period of significant expansion of the geographical territory occupied by Germanic tribes, and consequently of the number of German speakers. Whereas during the Old High German period the Germanic tribes extended only as far east as the Elbe and Saale rivers, the MHG period saw a number of these tribes expanding beyond this eastern boundary into Slavic territory (known as
4294-565: Is less closely related to languages based on Low Franconian dialects (e.g., Dutch and Afrikaans), Low German or Low Saxon dialects (spoken in northern Germany and southern Denmark ), neither of which underwent the High German consonant shift. As has been noted, the former of these dialect types is Istvaeonic and the latter Ingvaeonic, whereas the High German dialects are all Irminonic; the differences between these languages and standard German are therefore considerable. Also related to German are
4407-435: Is one of the major languages of the world . German is the second-most widely spoken Germanic language , after English, both as a first and as a second language . German is also widely taught as a foreign language , especially in continental Europe (where it is the third most taught foreign language after English and French), and in the United States. Overall, German is the fourth most commonly learned second language, and
4520-597: Is one of the three biggest newspapers in Namibia and the only German-language daily in Africa. An estimated 12,000 people speak German or a German variety as a first language in South Africa, mostly originating from different waves of immigration during the 19th and 20th centuries. One of the largest communities consists of the speakers of "Nataler Deutsch", a variety of Low German concentrated in and around Wartburg . The South African constitution identifies German as
4633-401: Is partly derived from Latin and Greek , along with fewer words borrowed from French and Modern English . English, however, is the main source of more recent loanwords . German is a pluricentric language ; the three standardized variants are German , Austrian , and Swiss Standard German . Standard German is sometimes called High German , which refers to its regional origin. German
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4746-513: Is pulled through forming machinery using either a hand-over-hand method or a continuous-roller method (as opposed to extrusion , where the material is pushed through dies). In fiberglass pultrusion, fibers (the glass material) are pulled from spools through a device that coats them with a resin. They are then typically heat-treated and cut to length. Fiberglass produced this way can be made in a variety of shapes and cross-sections, such as W or S cross-sections. People can be exposed to fiberglass in
4859-639: Is required, such as equipment cabinets and steel support structures, due to the ease with which it can be molded and painted to blend with existing structures and surfaces. Other uses include sheet-form electrical insulators and structural components commonly found in power-industry products. Because of fiberglass's lightweight and durability, it is often used in protective equipment such as helmets. Many sports use fiberglass protective gear, such as goaltenders' and catchers' masks. Storage tanks can be made of fiberglass with capacities up to about 300 tonnes . Smaller tanks can be made with chopped strand mat cast over
4972-510: Is sometimes referred to as "fiberglass", the composite is also called fiberglass-reinforced plastic ( FRP ). This article uses "fiberglass" to refer to the complete fiber-reinforced composite material, rather than only to the glass fiber within it. Glass fibers have been produced for centuries, but the earliest patent was awarded to the Prussian inventor Hermann Hammesfahr (1845–1914) in the U.S. in 1880. Mass production of glass strands
5085-402: Is that the resins used are subject to contraction during the curing process. For polyester this contraction is often 5–6%; for epoxy, about 2%. Because the fibers do not contract, this differential can create changes in the shape of the part during curing. Distortions can appear hours, days, or weeks after the resin has set. While this distortion can be minimized by symmetric use of the fibers in
5198-525: Is the Sachsenspiegel , the first book of laws written in Middle Low German ( c. 1220 ). The abundance and especially the secular character of the literature of the MHG period demonstrate the beginnings of a standardized written form of German, as well as the desire of poets and authors to be understood by individuals on supra-dialectal terms. The Middle High German period
5311-578: Is the only language in this branch which survives in written texts. The West Germanic languages, however, have undergone extensive dialectal subdivision and are now represented in modern languages such as English, German, Dutch , Yiddish , Afrikaans , and others. Within the West Germanic language dialect continuum, the Benrath and Uerdingen lines (running through Düsseldorf - Benrath and Krefeld - Uerdingen , respectively) serve to distinguish
5424-485: Is understood in all areas where German is spoken. Approximate distribution of native German speakers (assuming a rounded total of 95 million) worldwide: As a result of the German diaspora , as well as the popularity of German taught as a foreign language , the geographical distribution of German speakers (or "Germanophones") spans all inhabited continents. However, an exact, global number of native German speakers
5537-464: Is used when tensile strength (high modulus) is important and is thus an important building and aircraft epoxy composite (it is called R-glass, "R" for "reinforcement" in Europe). C-glass ("C" for "chemical resistance") and T-glass ("T" is for "thermal insulator"—a North American variant of C-glass) are resistant to chemical attack; both are often found in insulation-grades of blown fiberglass. Fiberglass
5650-433: Is versatile because it is lightweight, strong, weather-resistant, and can have a variety of surface textures. During World War II, fiberglass was developed as a replacement for the molded plywood used in aircraft radomes (fiberglass being transparent to microwaves ). Its first main civilian application was for the building of boats and sports car bodies, where it gained acceptance in the 1950s. Its use has broadened to
5763-689: The Ostsiedlung ). With the increasing wealth and geographic spread of the Germanic groups came greater use of German in the courts of nobles as the standard language of official proceedings and literature. A clear example of this is the mittelhochdeutsche Dichtersprache employed in the Hohenstaufen court in Swabia as a standardized supra-dialectal written language. While these efforts were still regionally bound, German began to be used in place of Latin for certain official purposes, leading to
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#17327838405505876-639: The Alamanni , Bavarian, and Thuringian groups, all belonging to the Elbe Germanic group ( Irminones ), which had settled in what is now southern-central Germany and Austria between the second and sixth centuries, during the great migration. In general, the surviving texts of Old High German (OHG) show a wide range of dialectal diversity with very little written uniformity. The early written tradition of OHG survived mostly through monasteries and scriptoria as local translations of Latin originals; as
5989-568: The Czech Republic ( North Bohemia ), Poland ( Upper Silesia ), Slovakia ( Košice Region , Spiš , and Hauerland ), Denmark ( North Schleswig ), Romania and Hungary ( Sopron ). Overseas, sizeable communities of German-speakers are found in Brazil ( Blumenau and Pomerode ), South Africa ( Kroondal ), Namibia , among others, some communities have decidedly Austrian German or Swiss German characters (e.g. Pozuzo , Peru). German
6102-537: The Early Middle Ages . German is an inflected language , with four cases for nouns, pronouns, and adjectives (nominative, accusative, genitive, dative); three genders (masculine, feminine, neuter) and two numbers (singular, plural). It has strong and weak verbs . The majority of its vocabulary derives from the ancient Germanic branch of the Indo-European language family, while a smaller share
6215-480: The European Union 's population, spoke German as their mother tongue, making it the second most widely spoken language on the continent after Russian and the second biggest language in terms of overall speakers (after English), as well as the most spoken native language. The area in central Europe where the majority of the population speaks German as a first language and has German as a (co-)official language
6328-671: The European Union . It is the most widely spoken and official (or co-official) language in Germany , Austria , Switzerland , Liechtenstein , and the Italian autonomous province of South Tyrol . It is also an official language of Luxembourg , Belgium and the Italian autonomous region of Friuli-Venezia Giulia , as well as a recognized national language in Namibia . There are also notable German-speaking communities in France ( Alsace ),
6441-522: The German states . While these states were still part of the Holy Roman Empire , and far from any form of unification, the desire for a cohesive written language that would be understandable across the many German-speaking principalities and kingdoms was stronger than ever. As a spoken language German remained highly fractured throughout this period, with a vast number of often mutually incomprehensible regional dialects being spoken throughout
6554-746: The Holy Roman Emperor Maximilian I , and the other being Meißner Deutsch , used in the Electorate of Saxony in the Duchy of Saxe-Wittenberg . Alongside these courtly written standards, the invention of the printing press led to the development of a number of printers' languages ( Druckersprachen ) aimed at making printed material readable and understandable across as many diverse dialects of German as possible. The greater ease of production and increased availability of written texts brought about increased standardisation in
6667-573: The International Agency for Research on Cancer (IARC) as "not classifiable as to carcinogenicity to humans" ( IARC group 3 ). "Epidemiologic studies published during the 15 years since the previous IARC monographs review of these fibers in 1988 provide no evidence of increased risks of lung cancer or mesothelioma (cancer of the lining of the body cavities) from occupational exposures during the manufacture of these materials, and inadequate evidence overall of any cancer risk." In June 2011,
6780-666: The Old High German language in several Elder Futhark inscriptions from as early as the sixth century AD (such as the Pforzen buckle ), the Old High German period is generally seen as beginning with the Abrogans (written c. 765–775 ), a Latin-German glossary supplying over 3,000 Old High German words with their Latin equivalents. After the Abrogans , the first coherent works written in Old High German appear in
6893-676: The Sprachraum in Europe. German is used in a wide variety of spheres throughout the country, especially in business, tourism, and public signage, as well as in education, churches (most notably the German-speaking Evangelical Lutheran Church in Namibia (GELK) ), other cultural spheres such as music, and media (such as German language radio programs by the Namibian Broadcasting Corporation ). The Allgemeine Zeitung
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#17327838405507006-550: The Standard German language in its written form, and the Duden Handbook was declared its standard definition. Punctuation and compound spelling (joined or isolated compounds) were not standardized in the process. The Deutsche Bühnensprache ( lit. ' German stage language ' ) by Theodor Siebs had established conventions for German pronunciation in theatres , three years earlier; however, this
7119-513: The Upper German dialects spoken in the southern German-speaking countries , such as Swiss German ( Alemannic dialects ) and the various Germanic dialects spoken in the French region of Grand Est , such as Alsatian (mainly Alemannic, but also Central–and Upper Franconian dialects) and Lorraine Franconian (Central Franconian). After these High German dialects, standard German
7232-469: The pagan Germanic tradition. Of particular interest to scholars, however, has been the Hildebrandslied , a secular epic poem telling the tale of an estranged father and son unknowingly meeting each other in battle. Linguistically, this text is highly interesting due to the mixed use of Old Saxon and Old High German dialects in its composition. The written works of this period stem mainly from
7345-723: The Empire. Its use indicated that the speaker was a merchant or someone from an urban area, regardless of nationality. Prague (German: Prag ) and Budapest ( Buda , German: Ofen ), to name two examples, were gradually Germanized in the years after their incorporation into the Habsburg domain; others, like Pressburg ( Pozsony , now Bratislava), were originally settled during the Habsburg period and were primarily German at that time. Prague, Budapest, Bratislava, and cities like Zagreb (German: Agram ) or Ljubljana (German: Laibach ), contained significant German minorities. In
7458-555: The European Union and Germany have classified synthetic glass fibers as possibly or probably carcinogenic, but fibers can be exempt from this classification if they pass specific tests. A 2012 health hazard review for the European Commission stated that inhalation of fiberglass at concentrations of 3, 16 and 30 mg/m3 "did not induce fibrosis nor tumours except transient lung inflammation that disappeared after
7571-748: The Frisian languages— North Frisian (spoken in Nordfriesland ), Saterland Frisian (spoken in Saterland ), and West Frisian (spoken in Friesland )—as well as the Anglic languages of English and Scots. These Anglo-Frisian dialects did not take part in the High German consonant shift, and the Anglic languages also adopted much vocabulary from both Old Norse and the Norman language . The history of
7684-536: The German language begins with the High German consonant shift during the Migration Period , which separated Old High German dialects from Old Saxon . This sound shift involved a drastic change in the pronunciation of both voiced and voiceless stop consonants ( b , d , g , and p , t , k , respectively). The primary effects of the shift were the following below. While there is written evidence of
7797-451: The German states; the invention of the printing press c. 1440 and the publication of Luther's vernacular translation of the Bible in 1534, however, had an immense effect on standardizing German as a supra-dialectal written language. The ENHG period saw the rise of several important cross-regional forms of chancery German, one being gemeine tiutsch , used in the court of
7910-681: The Germanic dialects that were affected by the High German consonant shift (south of Benrath) from those that were not (north of Uerdingen). The various regional dialects spoken south of these lines are grouped as High German dialects, while those spoken to the north comprise the Low German and Low Franconian dialects. As members of the West Germanic language family, High German, Low German, and Low Franconian have been proposed to be further distinguished historically as Irminonic , Ingvaeonic , and Istvaeonic , respectively. This classification indicates their historical descent from dialects spoken by
8023-655: The Irminones (also known as the Elbe group), Ingvaeones (or North Sea Germanic group), and Istvaeones (or Weser–Rhine group). Standard German is based on a combination of Thuringian - Upper Saxon and Upper Franconian dialects, which are Central German and Upper German dialects belonging to the High German dialect group. German is therefore closely related to the other languages based on High German dialects, such as Luxembourgish (based on Central Franconian dialects ) and Yiddish . Also closely related to Standard German are
8136-518: The MHG period. Significantly, these texts include a number of impressive secular works, such as the Nibelungenlied , an epic poem telling the story of the dragon -slayer Siegfried ( c. thirteenth century ), and the Iwein , an Arthurian verse poem by Hartmann von Aue ( c. 1203 ), lyric poems , and courtly romances such as Parzival and Tristan . Also noteworthy
8249-573: The US National Toxicology Program (NTP) removed from its Report on Carcinogens all biosoluble glass wool used in home and building insulation and for non-insulation products. However, NTP still considers fibrous glass dust to be "reasonably anticipated [as] a human carcinogen (Certain Glass Wool Fibers (Inhalable))". Similarly, California's Office of Environmental Health Hazard Assessment (OEHHA) published
8362-458: The air near manufacturing facilities or when they are near building fires or implosions . The American Lung Association advises that fiberglass insulation should never be left exposed in an occupied area. Since work practices are not always followed, and fiberglass is often left exposed in basements that later become occupied, people can get exposed. No readily usable biological or clinical indices of exposure exist. Fiberglass will irritate
8475-599: The automotive and sport equipment sectors. In the production of some products, such as aircraft, carbon fiber is now used instead of fiberglass, which is stronger by volume and weight. Advanced manufacturing techniques such as pre-pregs and fiber rovings extend fiberglass's applications and the tensile strength possible with fiber-reinforced plastics. Fiberglass is also used in the telecommunications industry for shrouding antennas , due to its RF permeability and low signal attenuation properties. It may also be used to conceal other equipment where no signal permeability
8588-550: The complexity and tolerances of the mold used for manufacturing the shell. The mechanical functionality of materials is heavily reliant on the combined performances of both the resin (AKA matrix) and fibers. For example, in severe temperature conditions (over 180 °C), the resin component of the composite may lose its functionality, partially due to bond deterioration of resin and fiber. However, GFRPs can still show significant residual strength after experiencing high temperatures (200 °C). One notable feature of fiberglass
8701-412: The construction of composite housing, and can include insulation to reduce heat loss. In rod pumping applications, fiberglass rods are often used for their high tensile strength to weight ratio. Fiberglass rods provide an advantage over steel rods because they stretch more elastically (lower Young's modulus ) than steel for a given weight, meaning more oil can be lifted from the hydrocarbon reservoir to
8814-973: The design, a certain amount of internal stress is created; and if it becomes too great, cracks form. The most common types of glass fiber used in fiberglass is E-glass , which is alumino-borosilicate glass with less than 1% w/w alkali oxides, mainly used for glass-reinforced plastics. Other types of glass used are A-glass ( A lkali-lime glass with little or no boron oxide), E-CR-glass ( E lectrical/ C hemical R esistance; alumino-lime silicate with less than 1% w/w alkali oxides, with high acid resistance), C-glass (alkali-lime glass with high boron oxide content, used for glass staple fibers and insulation), D-glass (borosilicate glass, named for its low D ielectric constant), R-glass (alumino silicate glass without MgO and CaO with high mechanical requirements as R einforcement), and S-glass (alumino silicate glass without CaO but with high MgO content with high tensile strength). Pure silica (silicon dioxide), when cooled as fused quartz into
8927-430: The development of non-local forms of language and exposed all speakers to forms of German from outside their own area. With Luther's rendering of the Bible in the vernacular, German asserted itself against the dominance of Latin as a legitimate language for courtly, literary, and now ecclesiastical subject-matter. His Bible was ubiquitous in the German states: nearly every household possessed a copy. Nevertheless, even with
9040-456: The dialect so as to make the work as natural and accessible to German speakers as possible. Copies of Luther's Bible featured a long list of glosses for each region, translating words which were unknown in the region into the regional dialect. Luther said the following concerning his translation method: One who would talk German does not ask the Latin how he shall do it; he must ask the mother in
9153-433: The early 1940s, and many sailing vessels made after 1950 were built using the fiberglass lay-up process . As of 2022, boats continue to be made with fiberglass, though more advanced techniques such as vacuum bag moulding are used in the construction process. Though most bullet-resistant armours are made using different textiles, fiberglass composites have been shown to be effective as ballistic armor. Filament winding
9266-519: The eastern provinces of Banat , Bukovina , and Transylvania (German: Banat, Buchenland, Siebenbürgen ), German was the predominant language not only in the larger towns—like Temeschburg ( Timișoara ), Hermannstadt ( Sibiu ), and Kronstadt ( Brașov )—but also in many smaller localities in the surrounding areas. In 1901, the Second Orthographic Conference ended with a (nearly) complete standardization of
9379-562: The eyes, skin, and the respiratory system. Hence, symptoms can include itchy eyes, skin, nose, sore throat, hoarseness, dyspnea (breathing difficulty) and cough. Peak alveolar deposition was observed in rodents and humans for fibers with diameters of 1 to 2 μm. In animal experiments, adverse lung effects such as lung inflammation and lung fibrosis have occurred, and increased incidences of mesothelioma , pleural sarcoma , and lung carcinoma had been found with intrapleural or intratracheal instillations in rats. As of 2001, in humans only
9492-563: The fiber has an effect on the properties of the final product. A high angle "hoop" will provide circumferential or "burst" strength, while lower angle patterns (polar or helical) will provide greater longitudinal tensile strength. Products currently being produced using this technique range from pipes, golf clubs, Reverse Osmosis Membrane Housings, oars, bicycle forks, bicycle rims, power and transmission poles, pressure vessels to missile casings, aircraft fuselages and lamp posts and yacht masts. A release agent, usually in either wax or liquid form,
9605-434: The fiber is weak in compression, it is actually only the long aspect ratio of the fiber which makes it seem so; i.e., because a typical fiber is long and narrow, it buckles easily. On the other hand, the glass fiber is weak in shear—that is, across its axis. Therefore, if a collection of fibers can be arranged permanently in a preferred direction within a material, and if they can be prevented from buckling in compression,
9718-415: The fiberglass and the mold. Additional resin is applied and possibly additional sheets of fiberglass. Hand pressure, vacuum or rollers are used to be sure the resin saturates and fully wets all layers, and that any air pockets are removed. The work must be done quickly before the resin starts to cure unless high-temperature resins are used which will not cure until the part is warmed in an oven. In some cases,
9831-420: The final structure to be strong, the fiber's surfaces must be almost entirely free of defects, as this permits the fibers to reach gigapascal tensile strengths . If a bulk piece of glass were defect-free, it would be as strong as glass fibers; however, it is generally impractical to produce and maintain bulk material in a defect-free state outside of laboratory conditions. The process of manufacturing fiberglass
9944-547: The functionality of machines and equipment. The installation of effective extraction and filtration equipment is required to ensure safety and efficiency. German language German (German: Deutsch , pronounced [dɔʏtʃ] ) is a West Germanic language in the Indo-European language family , mainly spoken in Western and Central Europe . It is the most spoken native language within
10057-459: The gas content of the material was replaced by plastic. This reduced the insulation properties to values typical of the plastic, but now for the first time, the composite showed great strength and promise as a structural and building material. Many glass fiber composites continued to be called "fiberglass" (as a generic name) and the name was also used for the low-density glass wool product containing gas instead of plastic. Ray Greene of Owens Corning
10170-473: The glass into short lengths and drops it into a jet of resin, projected onto the surface of a mold), or in an intermediary step, to manufacture fabrics such as chopped strand mat (CSM) (made of randomly oriented small cut lengths of fiber all bonded together), woven fabrics, knit fabrics or unidirectional fabrics. Chopped strand mat (CSM) is a form of reinforcement used in fiberglass. It consists of glass fibers laid randomly across each other and held together by
10283-435: The home, the children on the streets, the common man in the market-place and note carefully how they talk, then translate accordingly. They will then understand what is said to them because it is German. When Christ says ' ex abundantia cordis os loquitur ,' I would translate, if I followed the papists, aus dem Überflusz des Herzens redet der Mund . But tell me is this talking German? What German understands such stuff? No,
10396-481: The influence of Luther's Bible as an unofficial written standard, a widely accepted standard for written German did not appear until the middle of the eighteenth century. German was the language of commerce and government in the Habsburg Empire , which encompassed a large area of Central and Eastern Europe . Until the mid-nineteenth century, it was essentially the language of townspeople throughout most of
10509-441: The legal limit ( permissible exposure limit ) for fiberglass exposure in the workplace as 15 mg/m total and 5 mg/m in respiratory exposure over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 3 fibers/cm (less than 3.5 micrometers in diameter and greater than 10 micrometers in length) as a time-weighted average over an 8-hour workday, and
10622-413: The mandrel is completely covered to the desired thickness, the resin is cured; often the mandrel is placed in an oven to achieve this, though sometimes radiant heaters are used with the mandrel still turning in the machine. Once the resin has cured, the mandrel is removed, leaving the hollow final product. For some products such as gas bottles, the 'mandrel' is a permanent part of the finished product forming
10735-449: The material will be preferentially strong in that direction. Furthermore, by laying multiple layers of fiber on top of one another, with each layer oriented in various preferred directions, the material's overall stiffness and strength can be efficiently controlled. In fiberglass, it is the plastic matrix which permanently constrains the structural glass fibers to directions chosen by the designer. With chopped strand mat, this directionality
10848-586: The more biopersistent materials like ceramic fibres, which are used industrially as insulation in high-temperature environments such as blast furnaces , and certain special-purpose glass wools not used as insulating materials remain classified as possible carcinogens ( IARC Group 2B ). The more commonly used glass fibre wools including insulation glass wool , rock wool and slag wool are considered not classifiable as to carcinogenicity to humans ( IARC Group 3 ). In October 2001, all fiberglass wools commonly used for thermal and acoustical insulation were reclassified by
10961-402: The mother in the home and the plain man would say, Wesz das Herz voll ist, des gehet der Mund über . Luther's translation of the Bible into High German was also decisive for the German language and its evolution from Early New High German to modern Standard German. The publication of Luther's Bible was a decisive moment in the spread of literacy in early modern Germany , and promoted
11074-653: The ninth century, chief among them being the Muspilli , Merseburg charms , and Hildebrandslied , and other religious texts (the Georgslied , Ludwigslied , Evangelienbuch , and translated hymns and prayers). The Muspilli is a Christian poem written in a Bavarian dialect offering an account of the soul after the Last Judgment , and the Merseburg charms are transcriptions of spells and charms from
11187-462: The pronunciation of the ending -ig as [ɪk] instead of [ɪç]. In Northern Germany, High German was a foreign language to most inhabitants, whose native dialects were subsets of Low German. It was usually encountered only in writing or formal speech; in fact, most of High German was a written language, not identical to any spoken dialect, throughout the German-speaking area until well into the 19th century. However, wider standardization of pronunciation
11300-546: The states of North Dakota and South Dakota , German is the most common language spoken at home after English. As a legacy of significant German immigration to the country , German geographical names can be found throughout the Midwest region , such as New Ulm and Bismarck (North Dakota's state capital), plus many other regions. A number of German varieties have developed in the country and are still spoken today, such as Pennsylvania Dutch and Texas German . In Brazil,
11413-628: The surface with each stroke, all while reducing the load on the pumping unit. Fiberglass rods must be kept in tension, however, as they frequently part if placed in even a small amount of compression. The buoyancy of the rods within a fluid amplifies this tendency. GRP and GRE pipe can be used in a variety of above- and below-ground systems, including those for desalination, water treatment, water distribution networks, chemical process plants, water used for firefighting, hot and cold drinking water, wastewater/sewage, municipal waste and liquified petroleum gas . Fiberglass composite boats have been made since
11526-500: The third most commonly learned second language in the United States in K-12 education. The language has been influential in the fields of philosophy, theology, science, and technology. It is the second most commonly used language in science and the third most widely used language on websites . The German-speaking countries are ranked fifth in terms of annual publication of new books, with one-tenth of all books (including e-books) in
11639-482: The work is covered with plastic sheets and vacuum is drawn on the work to remove air bubbles and press the fiberglass to the shape of the mold. The fiberglass spray lay-up process is similar to the hand lay-up process but differs in the application of the fiber and resin to the mold. Spray-up is an open-molding composites fabrication process where resin and reinforcements are sprayed onto a mold. The resin and glass may be applied separately or simultaneously "chopped" in
11752-415: The workplace during its fabrication, installation or removal, by breathing it in, by skin contact, or by eye contact. Furthermore, in the manufacturing process of fiberglass, styrene vapors are released while the resins are cured. These are also irritating to mucous membranes and respiratory tract. The general population can get exposed to fibreglass from insulation and building materials or from fibers in
11865-555: The world being published in German. German is most closely related to other West Germanic languages, namely Afrikaans , Dutch , English , the Frisian languages , and Scots . It also contains close similarities in vocabulary to some languages in the North Germanic group , such as Danish , Norwegian , and Swedish . Modern German gradually developed from Old High German , which in turn developed from Proto-Germanic during
11978-600: The written form of German. One of the central events in the development of ENHG was the publication of Luther's translation of the Bible into High German (the New Testament was published in 1522; the Old Testament was published in parts and completed in 1534). Luther based his translation primarily on the Meißner Deutsch of Saxony , spending much time among the population of Saxony researching
12091-495: Was accidentally discovered in 1932 when Games Slayter , a researcher at Owens-Illinois , directed a jet of compressed air at a stream of molten glass and produced fibers. A patent for this method of producing glass wool was first applied for in 1933. Owens joined with the Corning company in 1935 and the method was adapted by Owens Corning to produce its patented "Fiberglas" (spelled with one "s") in 1936. Originally, Fiberglas
12204-429: Was a "neutral" language as there were virtually no English native speakers in Namibia at that time. German, Afrikaans, and several indigenous languages thus became "national languages" by law, identifying them as elements of the cultural heritage of the nation and ensuring that the state acknowledged and supported their presence in the country. Today, Namibia is considered to be the only German-speaking country outside of
12317-425: Was a glass wool with fibers entrapping a great deal of gas, making it useful as an insulator, especially at high temperatures. A suitable resin for combining the fiberglass with a plastic to produce a composite material was developed in 1936 by DuPont . The first ancestor of modern polyester resins is Cyanamid 's resin of 1942. Peroxide curing systems were used by then. With the combination of fiberglass and resin
12430-576: Was achieved by Hans Liebold in 1 minute, 56.67 seconds on May 5, 1979. Total production was 16 cars: 13 first and second generation Wankel engined cars, two diesel engined third generation cars used in the Nardò record attempt, and a single V8 engined fourth generation car. Mercedes-Benz introduced the C112 at the Frankfurt Motor Show in 1991 as a proposed production sports car. The car used
12543-547: Was an artificial standard that did not correspond to any traditional spoken dialect. Rather, it was based on the pronunciation of German in Northern Germany, although it was subsequently regarded often as a general prescriptive norm, despite differing pronunciation traditions especially in the Upper-German-speaking regions that still characterise the dialect of the area today – especially
12656-492: Was established on the basis of public speaking in theatres and the media during the 20th century and documented in pronouncing dictionaries. Official revisions of some of the rules from 1901 were not issued until the controversial German orthography reform of 1996 was made the official standard by governments of all German-speaking countries. Media and written works are now almost all produced in Standard German which
12769-443: Was the first type of glass used for fiberglass. E-glass ("E" because of initial Electrical application), is alkali-free and was the first glass formulation used for continuous filament formation. It now makes up most of the fiberglass production in the world, and also is the single largest consumer of boron minerals globally. It is susceptible to chloride ion attack and is a poor choice for marine applications. S-glass ("S" for "stiff")
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