The Sherman Silver Purchase Act was a United States federal law enacted on July 14, 1890.
100-508: The measure did not authorize the free and unlimited coinage of silver that the Free Silver supporters wanted. It increased the amount of silver the government was required to purchase on a recurrent monthly basis to 4.5 million ounces. The Sherman Silver Purchase Act had been passed in response to the growing complaints of farmers' and miners' interests. Farmers had immense debts that could not be paid off due to deflation , and they urged
200-486: A bullet cast from silver is often supposed in such folklore the only weapon that is effective against a werewolf , witch , or other monsters . From this the idiom of a silver bullet developed into figuratively referring to any simple solution with very high effectiveness or almost miraculous results, as in the widely discussed software engineering paper " No Silver Bullet ." Other powers attributed to silver include detection of poison and facilitation of passage into
300-496: A covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of silver. Silver has a brilliant, white, metallic luster that can take a high polish , and which is so characteristic that the name of the metal itself has become a color name . Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm. At wavelengths shorter than 450 nm, silver's reflectivity
400-546: A French Jesuit who spent most of his life in India, had specifically demonstrated the analogy between Sanskrit and European languages. According to current academic consensus, Jones's famous work of 1786 was less accurate than his predecessors', as he erroneously included Egyptian , Japanese and Chinese in the Indo-European languages, while omitting Hindi . In 1818, Danish linguist Rasmus Christian Rask elaborated
500-677: A PIE homeland, the Kurgan and Anatolian hypotheses are the ones most widely accepted, and also the ones most debated against each other. Following the publication of several studies on ancient DNA in 2015, Colin Renfrew, the original author and proponent of the Anatolian hypothesis, has accepted the reality of migrations of populations speaking one or several Indo-European languages from the Pontic steppe towards Northwestern Europe. The table lists
600-517: A Senate/House conference committee to settle differences between the Senate and House versions of the Act, Sherman was instrumental in getting the conference committee to reach agreement on a final draft of the Act. Nonetheless, once agreement on the final version was reached in the conference committee, Sherman found that he disagreed with many sections of the act. So tepid was Sherman's support that when he
700-450: A colorant in stained glass , and in specialized confectionery. Its compounds are used in photographic and X-ray film. Dilute solutions of silver nitrate and other silver compounds are used as disinfectants and microbiocides ( oligodynamic effect ), added to bandages , wound-dressings, catheters , and other medical instruments . Silver is similar in its physical and chemical properties to its two vertical neighbours in group 11 of
800-549: A conventional mark of reconstructed words, such as * wódr̥ , * ḱwn̥tós , or * tréyes ; these forms are the reconstructed ancestors of the modern English words water , hound , and three , respectively. No direct evidence of PIE exists; scholars have reconstructed PIE from its present-day descendants using the comparative method . For example, compare the pairs of words in Italian and English: piede and foot , padre and father , pesce and fish . Since there
900-453: A detailed, though conservative, overview of the lexical knowledge accumulated by 1959. Jerzy Kuryłowicz's 1956 Apophonie gave a better understanding of Indo-European ablaut . From the 1960s, knowledge of Anatolian became robust enough to establish its relationship to PIE. Scholars have proposed multiple hypotheses about when, where, and by whom PIE was spoken. The Kurgan hypothesis , first put forward in 1956 by Marija Gimbutas , has become
1000-627: A language. From the 1870s, the Neogrammarians proposed that sound laws have no exceptions, as illustrated by Verner's law , published in 1876, which resolved apparent exceptions to Grimm's law by exploring the role of accent (stress) in language change. August Schleicher 's A Compendium of the Comparative Grammar of the Indo-European, Sanskrit, Greek and Latin Languages (1874–77) represented an early attempt to reconstruct
1100-592: A non-Indo-European Wanderwort . Some scholars have thus proposed a Paleo-Hispanic origin, pointing to the Basque form zilharr as an evidence. The chemical symbol Ag is from the Latin word for silver , argentum (compare Ancient Greek ἄργυρος , árgyros ), from the Proto-Indo-European root * h₂erǵ- (formerly reconstructed as *arǵ- ), meaning ' white ' or ' shining ' . This
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#17327656178921200-614: A reward for betrayal, references the bribe Judas Iscariot is said in the New Testament to have taken from Jewish leaders in Jerusalem to turn Jesus of Nazareth over to soldiers of the high priest Caiaphas. Ethically, silver also symbolizes greed and degradation of consciousness; this is the negative aspect, the perverting of its value. The abundance of silver in the Earth's crust is 0.08 parts per million , almost exactly
1300-629: A scale unparalleled before the discovery of the New World . Reaching a peak production of 200 tonnes per year, an estimated silver stock of 10,000 tonnes circulated in the Roman economy in the middle of the second century AD, five to ten times larger than the combined amount of silver available to medieval Europe and the Abbasid Caliphate around AD 800. The Romans also recorded the extraction of silver in central and northern Europe in
1400-613: A thousand years. According to the prevailing Kurgan hypothesis , the original homeland of the Proto-Indo-Europeans may have been in the Pontic–Caspian steppe of eastern Europe. The linguistic reconstruction of PIE has provided insight into the pastoral culture and patriarchal religion of its speakers. As speakers of Proto-Indo-European became isolated from each other through the Indo-European migrations ,
1500-567: Is cognate with Old High German silabar ; Gothic silubr ; or Old Norse silfr , all ultimately deriving from Proto-Germanic *silubra . The Balto-Slavic words for silver are rather similar to the Germanic ones (e.g. Russian серебро [ serebró ], Polish srebro , Lithuanian sidãbras ), as is the Celtiberian form silabur . They may have a common Indo-European origin, although their morphology rather suggest
1600-465: Is the difluoride , AgF 2 , which can be obtained from the elements under heat. A strong yet thermally stable and therefore safe fluorinating agent, silver(II) fluoride is often used to synthesize hydrofluorocarbons . In stark contrast to this, all four silver(I) halides are known. The fluoride , chloride , and bromide have the sodium chloride structure, but the iodide has three known stable forms at different temperatures; that at room temperature
1700-470: Is Ag 3 O which behaves as a metallic conductor. Silver(I) sulfide , Ag 2 S, is very readily formed from its constituent elements and is the cause of the black tarnish on some old silver objects. It may also be formed from the reaction of hydrogen sulfide with silver metal or aqueous Ag ions. Many non-stoichiometric selenides and tellurides are known; in particular, AgTe ~3 is a low-temperature superconductor . The only known dihalide of silver
1800-551: Is a chemical element ; it has symbol Ag (from Latin argentum 'silver', derived from Proto-Indo-European *h₂erǵ ' shiny, white ' ) and atomic number 47. A soft, white, lustrous transition metal , it exhibits the highest electrical conductivity , thermal conductivity , and reflectivity of any metal . Silver is found in the Earth's crust in the pure, free elemental form (" native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite . Most silver
1900-422: Is a consistent correspondence of the initial consonants ( p and f ) that emerges far too frequently to be coincidental, one can infer that these languages stem from a common parent language . Detailed analysis suggests a system of sound laws to describe the phonetic and phonological changes from the hypothetical ancestral words to the modern ones. These laws have become so detailed and reliable as to support
2000-438: Is because its filled 4d shell is not very effective in shielding the electrostatic forces of attraction from the nucleus to the outermost 5s electron, and hence silver is near the bottom of the electrochemical series ( E (Ag /Ag) = +0.799 V). In group 11, silver has the lowest first ionization energy (showing the instability of the 5s orbital), but has higher second and third ionization energies than copper and gold (showing
2100-572: Is believed to have had an elaborate system of morphology that included inflectional suffixes (analogous to English child, child's, children, children's ) as well as ablaut (vowel alterations, as preserved in English sing, sang, sung, song ) and accent . PIE nominals and pronouns had a complex system of declension , and verbs similarly had a complex system of conjugation . The PIE phonology , particles , numerals , and copula are also well-reconstructed. Asterisks are used by linguists as
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#17327656178922200-549: Is higher than that of lead (1.87), and its electron affinity of 125.6 kJ/mol is much higher than that of hydrogen (72.8 kJ/mol) and not much less than that of oxygen (141.0 kJ/mol). Due to its full d-subshell, silver in its main +1 oxidation state exhibits relatively few properties of the transition metals proper from groups 4 to 10, forming rather unstable organometallic compounds , forming linear complexes showing very low coordination numbers like 2, and forming an amphoteric oxide as well as Zintl phases like
2300-428: Is inferior to that of aluminium and drops to zero near 310 nm. Very high electrical and thermal conductivity are common to the elements in group 11, because their single s electron is free and does not interact with the filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The thermal conductivity of silver is among the highest of all materials, although
2400-536: Is known to have some of the largest silver deposits in the world. Proto-Indo-European Pontic Steppe Caucasus East Asia Eastern Europe Northern Europe Pontic Steppe Northern/Eastern Steppe Europe South Asia Steppe Europe Caucasus India Indo-Aryans Iranians East Asia Europe East Asia Europe Indo-Aryan Iranian Indo-Aryan Iranian Others European Proto-Indo-European ( PIE )
2500-413: Is much less stable, fuming in moist air and reacting with glass. Silver(II) complexes are more common. Like the valence isoelectronic copper(II) complexes, they are usually square planar and paramagnetic, which is increased by the greater field splitting for 4d electrons than for 3d electrons. Aqueous Ag , produced by oxidation of Ag by ozone, is a very strong oxidising agent, even in acidic solutions: it
2600-410: Is not reversible because the silver atom liberated is typically found at a crystal defect or an impurity site, so that the electron's energy is lowered enough that it is "trapped". White silver nitrate , AgNO 3 , is a versatile precursor to many other silver compounds, especially the halides, and is much less sensitive to light. It was once called lunar caustic because silver was called luna by
2700-424: Is pale yellow, becoming purplish on exposure to light; it projects slightly from the surface of the artifact or coin. The precipitation of copper in ancient silver can be used to date artifacts, as copper is nearly always a constituent of silver alloys. Silver metal is attacked by strong oxidizers such as potassium permanganate ( KMnO 4 ) and potassium dichromate ( K 2 Cr 2 O 7 ), and in
2800-402: Is produced as a byproduct of copper , gold, lead , and zinc refining . Silver has long been valued as a precious metal . Silver metal is used in many bullion coins , sometimes alongside gold : while it is more abundant than gold, it is much less abundant as a native metal . Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of
2900-415: Is rare in the periodic table. The atomic weight is 107.8682(2) u ; this value is very important because of the importance of silver compounds, particularly halides, in gravimetric analysis . Both isotopes of silver are produced in stars via the s-process (slow neutron capture), as well as in supernovas via the r-process (rapid neutron capture). Twenty-eight radioisotopes have been characterized,
3000-536: Is reflected in the relative decomposition temperatures of AgMe (−50 °C) and CuMe (−15 °C) as well as those of PhAg (74 °C) and PhCu (100 °C). The C–Ag bond is stabilized by perfluoroalkyl ligands, for example in AgCF(CF 3 ) 2 . Alkenylsilver compounds are also more stable than their alkylsilver counterparts. Silver- NHC complexes are easily prepared, and are commonly used to prepare other NHC complexes by displacing labile ligands. For example,
3100-472: Is stabilized in phosphoric acid due to complex formation. Peroxodisulfate oxidation is generally necessary to give the more stable complexes with heterocyclic amines , such as [Ag(py) 4 ] and [Ag(bipy) 2 ] : these are stable provided the counterion cannot reduce the silver back to the +1 oxidation state. [AgF 4 ] is also known in its violet barium salt, as are some silver(II) complexes with N - or O -donor ligands such as pyridine carboxylates. By far
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3200-413: Is the cubic zinc blende structure. They can all be obtained by the direct reaction of their respective elements. As the halogen group is descended, the silver halide gains more and more covalent character, solubility decreases, and the colour changes from the white chloride to the yellow iodide as the energy required for ligand-metal charge transfer (X Ag → XAg) decreases. The fluoride is anomalous, as
3300-424: Is the reconstructed common ancestor of the Indo-European language family . No direct record of Proto-Indo-European exists; its proposed features have been derived by linguistic reconstruction from documented Indo-European languages. Far more work has gone into reconstructing PIE than any other proto-language , and it is the best understood of all proto-languages of its age. The majority of linguistic work during
3400-726: Is used in vacuum brazing . The two metals are completely miscible as liquids but not as solids; their importance in industry comes from the fact that their properties tend to be suitable over a wide range of variation in silver and copper concentration, although most useful alloys tend to be richer in silver than the eutectic mixture (71.9% silver and 28.1% copper by weight, and 60.1% silver and 28.1% copper by atom). Most other binary alloys are of little use: for example, silver–gold alloys are too soft and silver– cadmium alloys too toxic. Ternary alloys have much greater importance: dental amalgams are usually silver–tin–mercury alloys, silver–copper–gold alloys are very important in jewellery (usually on
3500-482: Is usually obtained by reacting silver or silver monofluoride with the strongest known oxidizing agent, krypton difluoride . Silver and gold have rather low chemical affinities for oxygen, lower than copper, and it is therefore expected that silver oxides are thermally quite unstable. Soluble silver(I) salts precipitate dark-brown silver(I) oxide , Ag 2 O, upon the addition of alkali. (The hydroxide AgOH exists only in solution; otherwise it spontaneously decomposes to
3600-558: The Indian subcontinent became aware of similarities between Indo-Iranian languages and European languages, and as early as 1653, Marcus Zuerius van Boxhorn had published a proposal for a proto-language ("Scythian") for the following language families: Germanic , Romance , Greek , Baltic , Slavic , Celtic , and Iranian . In a memoir sent to the Académie des Inscriptions et Belles-Lettres in 1767, Gaston-Laurent Coeurdoux ,
3700-848: The Koenigs–Knorr reaction . In the Fétizon oxidation , silver carbonate on celite acts as an oxidising agent to form lactones from diols . It is also employed to convert alkyl bromides into alcohols . Silver fulminate , AgCNO, a powerful, touch-sensitive explosive used in percussion caps , is made by reaction of silver metal with nitric acid in the presence of ethanol . Other dangerously explosive silver compounds are silver azide , AgN 3 , formed by reaction of silver nitrate with sodium azide , and silver acetylide , Ag 2 C 2 , formed when silver reacts with acetylene gas in ammonia solution. In its most characteristic reaction, silver azide decomposes explosively, releasing nitrogen gas: given
3800-545: The Lahn region, Siegerland , Silesia , Hungary , Norway , Steiermark , Schwaz , and the southern Black Forest . Most of these ores were quite rich in silver and could simply be separated by hand from the remaining rock and then smelted; some deposits of native silver were also encountered. Many of these mines were soon exhausted, but a few of them remained active until the Industrial Revolution , before which
3900-591: The Neogrammarian hypothesis : the Indo-European sound laws apply without exception. William Jones , an Anglo-Welsh philologist and puisne judge in Bengal , caused an academic sensation when in 1786 he postulated the common ancestry of Sanskrit , Greek , Latin , Gothic , the Celtic languages , and Old Persian , but he was not the first to state such a hypothesis. In the 16th century, European visitors to
4000-666: The mythical realm of fairies . Silver production has also inspired figurative language. Clear references to cupellation occur throughout the Old Testament of the Bible , such as in Jeremiah 's rebuke to Judah: "The bellows are burned, the lead is consumed of the fire; the founder melteth in vain: for the wicked are not plucked away. Reprobate silver shall men call them, because the Lord hath rejected them." (Jeremiah 6:19–20) Jeremiah
4100-433: The periodic table : copper , and gold . Its 47 electrons are arranged in the configuration [Kr]4d 5s , similarly to copper ([Ar]3d 4s ) and gold ([Xe]4f 5d 6s ); group 11 is one of the few groups in the d-block which has a completely consistent set of electron configurations. This distinctive electron configuration, with a single electron in the highest occupied s subshell over a filled d subshell, accounts for many of
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4200-435: The platinum complexes (though they are formed more readily than those of the analogous gold complexes): they are also quite unsymmetrical, showing the weak π bonding in group 11. Ag–C σ bonds may also be formed by silver(I), like copper(I) and gold(I), but the simple alkyls and aryls of silver(I) are even less stable than those of copper(I) (which tend to explode under ambient conditions). For example, poor thermal stability
4300-526: The post-transition metals . Unlike the preceding transition metals, the +1 oxidation state of silver is stable even in the absence of π-acceptor ligands . Silver does not react with air, even at red heat, and thus was considered by alchemists as a noble metal , along with gold. Its reactivity is intermediate between that of copper (which forms copper(I) oxide when heated in air to red heat) and gold. Like copper, silver reacts with sulfur and its compounds; in their presence, silver tarnishes in air to form
4400-542: The 1890s from 80 cents to approximately 50 cents increased public anxiety on their continued ability to convert silver dollars and banknotes into gold. The result was a run on the Treasury's gold stock and the onset of the Panic of 1893 . President Grover Cleveland summoned an emergency session of Congress on August 7, 1893, for the repeal of the act to prevent the further depletion of the government's gold reserves. In 1890,
4500-478: The 19th century was devoted to the reconstruction of PIE and its daughter languages , and many of the modern techniques of linguistic reconstruction (such as the comparative method ) were developed as a result. PIE is hypothesized to have been spoken as a single language from approximately 4500 BCE to 2500 BCE during the Late Neolithic to Early Bronze Age , though estimates vary by more than
4600-731: The 19th century, primary production of silver moved to North America, particularly Canada , Mexico , and Nevada in the United States : some secondary production from lead and zinc ores also took place in Europe, and deposits in Siberia and the Russian Far East as well as in Australia were mined. Poland emerged as an important producer during the 1970s after the discovery of copper deposits that were rich in silver, before
4700-576: The Greek and Roman civilizations, silver coins were a staple of the economy: the Greeks were already extracting silver from galena by the 7th century BC, and the rise of Athens was partly made possible by the nearby silver mines at Laurium , from which they extracted about 30 tonnes a year from 600 to 300 BC. The stability of the Roman currency relied to a high degree on the supply of silver bullion, mostly from Spain, which Roman miners produced on
4800-569: The North Adriatic region are sometimes classified as Italic. Albanian and Greek are the only surviving Indo-European descendants of a Paleo-Balkan language area, named for their occurrence in or in the vicinity of the Balkan peninsula . Most of the other languages of this area—including Illyrian , Thracian , and Dacian —do not appear to be members of any other subfamilies of PIE, but are so poorly attested that proper classification of them
4900-638: The Pontic–Caspian steppe and into eastern Europe. Other theories include the Anatolian hypothesis , which posits that PIE spread out from Anatolia with agriculture beginning c. 7500–6000 BCE, the Armenian hypothesis , the Paleolithic continuity paradigm , and the indigenous Aryans theory. The last two of these theories are not regarded as credible within academia. Out of all the theories for
5000-631: The President's approval. Under the Act, the federal government purchased millions of ounces of silver, with issues of paper currency. It became the second-largest buyer in the world, after the British Crown in India, where the Indian rupee was backed by silver rather than gold. Instead of the $ 2 million to $ 4 million that had been required by the Bland–Allison Act of 1878, the US government
5100-526: The Proto-Indo-European and Proto-Kartvelian languages due to early language contact , as well as some morphological similarities—notably the Indo-European ablaut , which is remarkably similar to the root ablaut system reconstructible for Proto-Kartvelian. The Lusitanian language was a marginally attested language spoken in areas near the border between present-day Portugal and Spain . The Venetic and Liburnian languages known from
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#17327656178925200-557: The ancient alchemists, who believed that silver was associated with the Moon. It is often used for gravimetric analysis, exploiting the insolubility of the heavier silver halides which it is a common precursor to. Silver nitrate is used in many ways in organic synthesis , e.g. for deprotection and oxidations. Ag binds alkenes reversibly, and silver nitrate has been used to separate mixtures of alkenes by selective absorption. The resulting adduct can be decomposed with ammonia to release
5300-637: The black silver sulfide (copper forms the green sulfate instead, while gold does not react). While silver is not attacked by non-oxidizing acids, the metal dissolves readily in hot concentrated sulfuric acid , as well as dilute or concentrated nitric acid . In the presence of air, and especially in the presence of hydrogen peroxide , silver dissolves readily in aqueous solutions of cyanide . The three main forms of deterioration in historical silver artifacts are tarnishing, formation of silver chloride due to long-term immersion in salt water, as well as reaction with nitrate ions or oxygen. Fresh silver chloride
5400-712: The centre of production returned to the Americas the following decade. Today, Peru and Mexico are still among the primary silver producers, but the distribution of silver production around the world is quite balanced and about one-fifth of the silver supply comes from recycling instead of new production. Silver plays a certain role in mythology and has found various usage as a metaphor and in folklore. The Greek poet Hesiod 's Works and Days (lines 109–201) lists different ages of man named after metals like gold, silver, bronze and iron to account for successive ages of humanity. Ovid 's Metamorphoses contains another retelling of
5500-546: The common origin of Sanskrit, Persian, Greek, Latin, and German. In 1833, he began publishing the Comparative Grammar of Sanskrit, Zend , Greek, Latin, Lithuanian, Old Slavic, Gothic, and German . In 1822, Jacob Grimm formulated what became known as Grimm's law as a general rule in his Deutsche Grammatik . Grimm showed correlations between the Germanic and other Indo-European languages and demonstrated that sound change systematically transforms all words of
5600-434: The dominant producers of silver until around the beginning of the 18th century, particularly Peru , Bolivia , Chile , and Argentina : the last of these countries later took its name from that of the metal that composed so much of its mineral wealth. The silver trade gave way to a global network of exchange . As one historian put it, silver "went round the world and made the world go round." Much of this silver ended up in
5700-582: The effects of hypothetical sounds which no longer exist in all languages documented prior to the excavation of cuneiform tablets in Anatolian. This theory was first proposed by Ferdinand de Saussure in 1879 on the basis of internal reconstruction only, and progressively won general acceptance after Jerzy Kuryłowicz 's discovery of consonantal reflexes of these reconstructed sounds in Hittite. Julius Pokorny 's Indogermanisches etymologisches Wörterbuch ('Indo-European Etymological Dictionary', 1959) gave
5800-411: The elements in groups 10–14 (except boron and carbon ) have very complex Ag–M phase diagrams and form the most commercially important alloys; and the remaining elements on the periodic table have no consistency in their Ag–M phase diagrams. By far the most important such alloys are those with copper: most silver used for coinage and jewellery is in reality a silver–copper alloy, and the eutectic mixture
5900-529: The exceptions are the nitrate, perchlorate, and fluoride. The tetracoordinate tetrahedral aqueous ion [Ag(H 2 O) 4 ] is known, but the characteristic geometry for the Ag cation is 2-coordinate linear. For example, silver chloride dissolves readily in excess aqueous ammonia to form [Ag(NH 3 ) 2 ] ; silver salts are dissolved in photography due to the formation of the thiosulfate complex [Ag(S 2 O 3 ) 2 ] ; and cyanide extraction for silver (and gold) works by
6000-534: The fluoride ion is so small that it has a considerable solvation energy and hence is highly water-soluble and forms di- and tetrahydrates. The other three silver halides are highly insoluble in aqueous solutions and are very commonly used in gravimetric analytical methods. All four are photosensitive (though the monofluoride is so only to ultraviolet light), especially the bromide and iodide which photodecompose to silver metal, and thus were used in traditional photography . The reaction involved is: The process
6100-523: The formation of the complex [Ag(CN) 2 ] . Silver cyanide forms the linear polymer {Ag–C≡N→Ag–C≡N→}; silver thiocyanate has a similar structure, but forms a zigzag instead because of the sp - hybridized sulfur atom. Chelating ligands are unable to form linear complexes and thus silver(I) complexes with them tend to form polymers; a few exceptions exist, such as the near-tetrahedral diphosphine and diarsine complexes [Ag(L–L) 2 ] . Under standard conditions, silver does not form simple carbonyls, due to
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#17327656178926200-412: The free alkene. Yellow silver carbonate , Ag 2 CO 3 can be easily prepared by reacting aqueous solutions of sodium carbonate with a deficiency of silver nitrate. Its principal use is for the production of silver powder for use in microelectronics. It is reduced with formaldehyde , producing silver free of alkali metals: Silver carbonate is also used as a reagent in organic synthesis such as
6300-573: The gold-rich side) and have a vast range of hardnesses and colours, silver–copper–zinc alloys are useful as low-melting brazing alloys, and silver–cadmium– indium (involving three adjacent elements on the periodic table) is useful in nuclear reactors because of its high thermal neutron capture cross-section , good conduction of heat, mechanical stability, and resistance to corrosion in hot water. The word silver appears in Old English in various spellings, such as seolfor and siolfor . It
6400-564: The government to increase the demand for silver. Originally, the bill was simply known as the Silver Purchase Act of 1890. Only after the bill was signed into law did it become the "Sherman Silver Purchase Act." Senator John Sherman , an Ohio Republican and chairman of the Senate Finance Committee, was not the author of the bill, but once both houses of Congress had passed the Act and the Act had been sent to
6500-484: The government to pass the Sherman Silver Purchase Act to boost the economy and cause inflation , allowing them to pay their debts with cheaper dollars. Mining companies, meanwhile, had extracted vast quantities of silver from western mines. The resulting oversupply drove down the price of their product, often to below the point at which the silver could be profitably extracted. They hoped to enlist
6600-514: The hands of the Chinese. A Portuguese merchant in 1621 noted that silver "wanders throughout all the world... before flocking to China, where it remains as if at its natural center." Still, much of it went to Spain, allowing Spanish rulers to pursue military and political ambitions in both Europe and the Americas. "New World mines", concluded several historians, "supported the Spanish empire." In
6700-654: The main Indo-European language families, comprising the languages descended from Proto-Indo-European. Slavic: Russian , Ukrainian , Belarusian , Polish , Czech , Slovak , Sorbian , Serbo-Croatian , Bulgarian , Slovenian , Macedonian , Kashubian , Rusyn Iranic: Persian , Pashto , Balochi , Kurdish , Zaza , Ossetian , Luri , Talyshi , Tati , Gilaki , Mazandarani , Semnani , Yaghnobi ; Nuristani Commonly proposed subgroups of Indo-European languages include Italo-Celtic , Graeco-Aryan , Graeco-Armenian , Graeco-Phrygian , Daco-Thracian , and Thraco-Illyrian . There are numerous lexical similarities between
6800-618: The metal. The situation changed with the discovery of cupellation , a technique that allowed silver metal to be extracted from its ores. While slag heaps found in Asia Minor and on the islands of the Aegean Sea indicate that silver was being separated from lead as early as the 4th millennium BC , and one of the earliest silver extraction centres in Europe was Sardinia in the early Chalcolithic period , these techniques did not spread widely until later, when it spread throughout
6900-434: The most important oxidation state for silver in complexes is +1. The Ag cation is diamagnetic, like its homologues Cu and Au , as all three have closed-shell electron configurations with no unpaired electrons: its complexes are colourless provided the ligands are not too easily polarized such as I . Ag forms salts with most anions, but it is reluctant to coordinate to oxygen and thus most of these salts are insoluble in water:
7000-534: The most popular. It proposes that the original speakers of PIE were the Yamnaya culture associated with the kurgans (burial mounds) on the Pontic–Caspian steppe north of the Black Sea. According to the theory, they were nomadic pastoralists who domesticated the horse , which allowed them to migrate across Europe and Asia in wagons and chariots. By the early 3rd millennium BCE, they had expanded throughout
7100-546: The most stable being Ag with a half-life of 41.29 days, Ag with a half-life of 7.45 days, and Ag with a half-life of 3.13 hours. Silver has numerous nuclear isomers , the most stable being Ag ( t 1/2 = 418 years), Ag ( t 1/2 = 249.79 days) and Ag ( t 1/2 = 8.28 days). All of the remaining radioactive isotopes have half-lives of less than an hour, and the majority of these have half-lives of less than three minutes. Isotopes of silver range in relative atomic mass from 92.950 u ( Ag) to 129.950 u ( Ag);
7200-588: The only objects with a high-enough palladium-to-silver ratio to yield measurable variations in Ag abundance. Radiogenic Ag was first discovered in the Santa Clara meteorite in 1978. Pd– Ag correlations observed in bodies that have clearly been melted since the accretion of the Solar System must reflect the presence of unstable nuclides in the early Solar System. Silver is a rather unreactive metal. This
7300-625: The ores of copper, copper-nickel, lead, and lead-zinc obtained from Peru , Bolivia , Mexico , China , Australia , Chile , Poland and Serbia . Peru, Bolivia and Mexico have been mining silver since 1546, and are still major world producers. Top silver-producing mines are Cannington (Australia), Fresnillo (Mexico), San Cristóbal (Bolivia), Antamina (Peru), Rudna (Poland), and Penasquito (Mexico). Top near-term mine development projects through 2015 are Pascua Lama (Chile), Navidad (Argentina), Jaunicipio (Mexico), Malku Khota (Bolivia), and Hackett River (Canada). In Central Asia , Tajikistan
7400-423: The oxide.) Silver(I) oxide is very easily reduced to metallic silver, and decomposes to silver and oxygen above 160 °C. This and other silver(I) compounds may be oxidized by the strong oxidizing agent peroxodisulfate to black AgO, a mixed silver(I,III) oxide of formula Ag Ag O 2 . Some other mixed oxides with silver in non-integral oxidation states, namely Ag 2 O 3 and Ag 3 O 4 , are also known, as
7500-577: The photosensitivity of silver salts, this behaviour may be induced by shining a light on its crystals. Silver complexes tend to be similar to those of its lighter homologue copper. Silver(III) complexes tend to be rare and very easily reduced to the more stable lower oxidation states, though they are slightly more stable than those of copper(III). For instance, the square planar periodate [Ag(IO 5 OH) 2 ] and tellurate [Ag{TeO 4 (OH) 2 } 2 ] complexes may be prepared by oxidising silver(I) with alkaline peroxodisulfate . The yellow diamagnetic [AgF 4 ]
7600-961: The presence of potassium bromide ( KBr ). These compounds are used in photography to bleach silver images, converting them to silver bromide that can either be fixed with thiosulfate or redeveloped to intensify the original image. Silver forms cyanide complexes ( silver cyanide ) that are soluble in water in the presence of an excess of cyanide ions. Silver cyanide solutions are used in electroplating of silver. The common oxidation states of silver are (in order of commonness): +1 (the most stable state; for example, silver nitrate , AgNO 3 ); +2 (highly oxidising; for example, silver(II) fluoride , AgF 2 ); and even very rarely +3 (extreme oxidising; for example, potassium tetrafluoroargentate(III), KAgF 4 ). The +3 state requires very strong oxidising agents to attain, such as fluorine or peroxodisulfate , and some silver(III) compounds react with atmospheric moisture and attack glass. Indeed, silver(III) fluoride
7700-525: The price of silver dipped to $ 1.16 per ounce. By the end of the year, it had fallen to $ 0.69 . By December 1894, the price had dropped to $ 0.60 . On November 1, 1895, US mints halted production of silver coins, and the government closed the Carson City Mint . Banks discouraged the use of silver dollars. The years 1893–95 had the lowest productions of Morgan dollars for the entire series, creating several scarce coins. Silver Silver
7800-406: The primary decay mode before the most abundant stable isotope, Ag, is electron capture and the primary mode after is beta decay . The primary decay products before Ag are palladium (element 46) isotopes, and the primary products after are cadmium (element 48) isotopes. The palladium isotope Pd decays by beta emission to Ag with a half-life of 6.5 million years. Iron meteorites are
7900-426: The proto-Indo-European language. By the early 1900s, Indo-Europeanists had developed well-defined descriptions of PIE which scholars still accept today. Later, the discovery of the Anatolian and Tocharian languages added to the corpus of descendant languages. A subtle new principle won wide acceptance: the laryngeal theory , which explained irregularities in the reconstruction of Proto-Indo-European phonology as
8000-419: The reaction of the bis(NHC)silver(I) complex with bis(acetonitrile)palladium dichloride or chlorido(dimethyl sulfide)gold(I) : Silver forms alloys with most other elements on the periodic table. The elements from groups 1–3, except for hydrogen , lithium , and beryllium , are very miscible with silver in the condensed phase and form intermetallic compounds; those from groups 4–9 are only poorly miscible;
8100-512: The region and beyond. The origins of silver production in India , China , and Japan were almost certainly equally ancient, but are not well-documented due to their great age. When the Phoenicians first came to what is now Spain , they obtained so much silver that they could not fit it all on their ships, and as a result used silver to weight their anchors instead of lead. By the time of
8200-428: The regional dialects of Proto-Indo-European spoken by the various groups diverged, as each dialect underwent shifts in pronunciation (the Indo-European sound laws ), morphology, and vocabulary. Over many centuries, these dialects transformed into the known ancient Indo-European languages. From there, further linguistic divergence led to the evolution of their current descendants, the modern Indo-European languages. PIE
8300-701: The same as that of mercury . It mostly occurs in sulfide ores, especially acanthite and argentite , Ag 2 S. Argentite deposits sometimes also contain native silver when they occur in reducing environments, and when in contact with salt water they are converted to chlorargyrite (including horn silver ), AgCl, which is prevalent in Chile and New South Wales . Most other silver minerals are silver pnictides or chalcogenides ; they are generally lustrous semiconductors. Most true silver deposits, as opposed to argentiferous deposits of other metals, came from Tertiary period vulcanism. The principal sources of silver are
8400-693: The same time period. This production came to a nearly complete halt with the fall of the Roman Empire, not to resume until the time of Charlemagne : by then, tens of thousands of tonnes of silver had already been extracted. Central Europe became the centre of silver production during the Middle Ages , as the Mediterranean deposits exploited by the ancient civilisations had been exhausted. Silver mines were opened in Bohemia , Saxony , Alsace ,
8500-730: The set of correspondences in his prize essay Undersøgelse om det gamle Nordiske eller Islandske Sprogs Oprindelse ('Investigation of the Origin of the Old Norse or Icelandic Language'), where he argued that Old Norse was related to the Germanic languages, and had even suggested a relation to the Baltic, Slavic, Greek, Latin and Romance languages. In 1816, Franz Bopp published On the System of Conjugation in Sanskrit , in which he investigated
8600-440: The seven metals of antiquity , silver has had an enduring role in most human cultures. Other than in currency and as an investment medium ( coins and bullion ), silver is used in solar panels , water filtration , jewellery , ornaments, high-value tableware and utensils (hence the term " silverware "), in electrical contacts and conductors , in specialized mirrors, window coatings, in catalysis of chemical reactions, as
8700-429: The singular properties of metallic silver. Silver is a relatively soft and extremely ductile and malleable transition metal , though it is slightly less malleable than gold. Silver crystallizes in a face-centered cubic lattice with bulk coordination number 12, where only the single 5s electron is delocalized, similarly to copper and gold. Unlike metals with incomplete d-shells, metallic bonds in silver are lacking
8800-422: The stability of the 4d orbitals), so that the chemistry of silver is predominantly that of the +1 oxidation state, reflecting the increasingly limited range of oxidation states along the transition series as the d-orbitals fill and stabilize. Unlike copper , for which the larger hydration energy of Cu as compared to Cu is the reason why the former is the more stable in aqueous solution and solids despite lacking
8900-445: The stable filled d-subshell of the latter, with silver this effect is swamped by its larger second ionisation energy. Hence, Ag is the stable species in aqueous solution and solids, with Ag being much less stable as it oxidizes water. Most silver compounds have significant covalent character due to the small size and high first ionization energy (730.8 kJ/mol) of silver. Furthermore, silver's Pauling electronegativity of 1.93
9000-411: The story, containing an illustration of silver's metaphorical use of signifying the second-best in a series, better than bronze but worse than gold: But when good Saturn , banish'd from above, Was driv'n to Hell, the world was under Jove . Succeeding times a silver age behold, Excelling brass, but more excell'd by gold. In folklore, silver was commonly thought to have mystic powers: for example,
9100-463: The structure of the silver is largely unchanged while the electron concentration rises as more zinc is added. Increasing the electron concentration further leads to body-centred cubic (electron concentration 1.5), complex cubic (1.615), and hexagonal close-packed phases (1.75). Naturally occurring silver is composed of two stable isotopes , Ag and Ag, with Ag being slightly more abundant (51.839% natural abundance ). This almost equal abundance
9200-432: The surface of conductors rather than through the interior. During World War II in the US, 13540 tons of silver were used for the electromagnets in calutrons for enriching uranium , mainly because of the wartime shortage of copper. Silver readily forms alloys with copper, gold, and zinc . Zinc-silver alloys with low zinc concentration may be considered as face-centred cubic solid solutions of zinc in silver, as
9300-540: The thermal conductivity of carbon (in the diamond allotrope ) and superfluid helium-4 are higher. The electrical conductivity of silver is the highest of all metals, greater even than copper. Silver also has the lowest contact resistance of any metal. Silver is rarely used for its electrical conductivity, due to its high cost, although an exception is in radio-frequency engineering , particularly at VHF and higher frequencies where silver plating improves electrical conductivity because those currents tend to flow on
9400-458: The weakness of the Ag–C bond. A few are known at very low temperatures around 6–15 K, such as the green, planar paramagnetic Ag(CO) 3 , which dimerizes at 25–30 K, probably by forming Ag–Ag bonds. Additionally, the silver carbonyl [Ag(CO)] [B(OTeF 5 ) 4 ] is known. Polymeric AgLX complexes with alkenes and alkynes are known, but their bonds are thermodynamically weaker than even those of
9500-447: The world production of silver was around a meagre 50 tonnes per year. In the Americas, high temperature silver-lead cupellation technology was developed by pre-Inca civilizations as early as AD 60–120; silver deposits in India, China, Japan, and pre-Columbian America continued to be mined during this time. With the discovery of America and the plundering of silver by the Spanish conquistadors, Central and South America became
9600-413: Was also aware of sheet silver, exemplifying the malleability and ductility of the metal: "Silver spread into plates is brought from Tarshish, and gold from Uphaz, the work of the workman, and of the hands of the founder: blue and purple is their clothing: they are all the work of cunning men." (Jeremiah 10:9) Silver also has more negative cultural meanings: the idiom thirty pieces of silver , referring to
9700-593: Was asked his opinion of the act by President Benjamin Harrison , Sherman ventured only that the bill was "safe" and would cause no harm if the President signed it. The act was enacted in tandem with the McKinley Tariff of 1890. William McKinley , an Ohio Republican and chairman of the House Ways and Means Committee , worked with John Sherman to create a package that could both pass the Senate and receive
9800-510: Was more often used ornamentally or as money. Since silver is more reactive than gold, supplies of native silver were much more limited than those of gold. For example, silver was more expensive than gold in Egypt until around the fifteenth century BC: the Egyptians are thought to have separated gold from silver by heating the metals with salt, and then reducing the silver chloride produced to
9900-463: Was now required to purchase 4.5 million ounces of silver bullion every month. The law required the Treasury to buy the silver with a special issue of Treasury (Coin) Notes that could be redeemed for either silver or gold. The result was the substantial expansion in the volume of circulating dollars without a proportionate growth in the gold stock. The crash in the silver dollar's bullion value in
10000-457: Was the usual Proto-Indo-European word for the metal, whose reflexes are missing in Germanic and Balto-Slavic. Silver was known in prehistoric times: the three metals of group 11, copper, silver, and gold, occur in the elemental form in nature and were probably used as the first primitive forms of money as opposed to simple bartering. Unlike copper, silver did not lead to the growth of metallurgy , on account of its low structural strength; it
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