Thiokol was an American corporation concerned initially with rubber and related chemicals, and later with rocket and missile propulsion systems. Its name is a portmanteau of the Greek words for sulfur (Greek: θεῖον , romanized: theion ) and glue (Greek: κόλλα , romanized: kolla ), an allusion to the company's initial product, Thiokol polymer .
143-662: The Thiokol Chemical Company was founded in 1929. Its initial business was a range of synthetic rubber and polymer sealants. Thiokol was a major supplier of liquid polymer sealants during World War II . When scientists at the Jet Propulsion Laboratory discovered that Thiokol's polymers made ideal binders for solid rocket fuels, Thiokol moved into the new field, opening laboratories at Elkton, Maryland , and later production facilities at Elkton and at Redstone Arsenal in Huntsville, Alabama . Huntsville produced
286-459: A catalyst . Laboratory synthesis of biopolymers, especially of proteins , is an area of intensive research. There are three main classes of biopolymers: polysaccharides , polypeptides , and polynucleotides . In living cells, they may be synthesized by enzyme-mediated processes, such as the formation of DNA catalyzed by DNA polymerase . The synthesis of proteins involves multiple enzyme-mediated processes to transcribe genetic information from
429-441: A lower critical solution temperature phase transition (LCST), at which phase separation occurs with heating. In dilute solutions, the properties of the polymer are characterized by the interaction between the solvent and the polymer. In a good solvent, the polymer appears swollen and occupies a large volume. In this scenario, intermolecular forces between the solvent and monomer subunits dominate over intramolecular interactions. In
572-575: A synthetic rubber , which they christened " Thiokol ". In 1929, Bevis Longstreth, an executive at a salt company, founded the Thiokol Corporation in Trenton, New Jersey. He became its president and general manager. Longstreth died in 1944, leaving the position of president and general manager open. William Crosby became general manager. The next year, in 1945, Charles Bartley , working for the nascent Jet Propulsion Laboratory , discovered
715-448: A Houston-based manufacturer of industrial coatings, marine decking, and subsea insulation products. In 2000, Thiokol merged with two divisions of Alcoa and with Howmet Castings and Huck Fasteners to become AIC Group (Alcoa Industrial Components). In 2001, Alliant Techsystems (ATK) Inc. (a company formed when Honeywell spun off its defense division) spent $ 2.9 billion buying Thiokol and related businesses from AIC/Alcoa. ATK built
858-502: A bad solvent or poor solvent, intramolecular forces dominate and the chain contracts. In the theta solvent , or the state of the polymer solution where the value of the second virial coefficient becomes 0, the intermolecular polymer-solvent repulsion balances exactly the intramolecular monomer-monomer attraction. Under the theta condition (also called the Flory condition), the polymer behaves like an ideal random coil . The transition between
1001-692: A contract to build the TU-122 rocket motor for the first stage of the LGM-30 Minuteman ICBM system. In 1959, Thiokol Huntsville began producing CASTOR strap-on booster rocket, used on the Atlas rocket. In 1964, the Woodbine, Georgia plant was constructed to build solid propellant motors for NASA , but the agency changed course and used liquid fuel. In 1969, Thiokol was awarded a U.S. Army contract to manufacture 750,000 Tripflares for use in
1144-628: A decade of reliance on the Russians. In 2019, NASA announced the Artemis program , intending to return to the Moon and establish a permanent human presence. This was paired with the Artemis Accords with partner nations to establish rules of behavior and norms of space commercialization on the Moon. In 2023, NASA established the Moon to Mars Program office. The office is designed to oversee
1287-408: A degree of crystallinity approaching zero or one will tend to be transparent, while polymers with intermediate degrees of crystallinity will tend to be opaque due to light scattering by crystalline or glassy regions. For many polymers, crystallinity may also be associated with decreased transparency. The space occupied by a polymer molecule is generally expressed in terms of radius of gyration , which
1430-587: A deviation from a simple linear chain. A branched polymer molecule is composed of a main chain with one or more substituent side chains or branches. Types of branched polymers include star polymers , comb polymers , polymer brushes , dendronized polymers , ladder polymers , and dendrimers . There exist also two-dimensional polymers (2DP) which are composed of topologically planar repeat units. A polymer's architecture affects many of its physical properties including solution viscosity, melt viscosity, solubility in various solvents, glass-transition temperature and
1573-688: A distinct civilian orientation, emphasizing peaceful applications in space science . It has since led most of America's space exploration programs, including Project Mercury , Project Gemini , the 1968–1972 Apollo Moon landing missions, the Skylab space station, and the Space Shuttle . Currently, NASA supports the International Space Station (ISS) along with the Commercial Crew Program , and oversees
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#17327909689251716-464: A flexible quality. Plasticizers are also put in some types of cling film to make the polymer more flexible. The attractive forces between polymer chains play a large part in determining the polymer's properties. Because polymer chains are so long, they have many such interchain interactions per molecule, amplifying the effect of these interactions on the polymer properties in comparison to attractions between conventional molecules. Different side groups on
1859-479: A given application, the properties of a polymer can be tuned or enhanced by combination with other materials, as in composites . Their application allows to save energy (lighter cars and planes, thermally insulated buildings), protect food and drinking water (packaging), save land and lower use of fertilizers (synthetic fibres), preserve other materials (coatings), protect and save lives (hygiene, medical applications). A representative, non-exhaustive list of applications
2002-402: A high surface quality and are also highly transparent so that the laser properties are dominated by the laser dye used to dope the polymer matrix. These type of lasers, that also belong to the class of organic lasers , are known to yield very narrow linewidths which is useful for spectroscopy and analytical applications. An important optical parameter in the polymer used in laser applications
2145-647: A month after the Soviet Yuri Gagarin became the first human in space, executing a full orbital spaceflight. NASA's first orbital spaceflight was conducted by John Glenn on February 20, 1962, in the Friendship 7 , making three full orbits before reentering. Glenn had to fly parts of his final two orbits manually due to an autopilot malfunction. The sixth and final Mercury mission was flown by Gordon Cooper in May 1963, performing 22 orbits over 34 hours in
2288-583: A permanently manned space station and to do it within a decade. In 1985, NASA proposed the Space Station Freedom , which both the agency and President Reagan intended to be an international program. While this would add legitimacy to the program, there were concerns within NASA that the international component would dilute its authority within the project, having never been willing to work with domestic or international partners as true equals. There
2431-401: A polymer behaves as a continuous macroscopic material. They are classified as bulk properties, or intensive properties according to thermodynamics . The bulk properties of a polymer are those most often of end-use interest. These are the properties that dictate how the polymer actually behaves on a macroscopic scale. The tensile strength of a material quantifies how much elongating stress
2574-421: A polymer is its first and most important attribute. Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer , while a polymer containing two or more types of repeat units is known as a copolymer . A terpolymer is a copolymer which contains three types of repeat units. Polystyrene
2717-433: A polymeric material can be described at different length scales, from the sub-nm length scale up to the macroscopic one. There is in fact a hierarchy of structures, in which each stage provides the foundations for the next one. The starting point for the description of the structure of a polymer is the identity of its constituent monomers. Next, the microstructure essentially describes the arrangement of these monomers within
2860-650: A possible source of antimatter at the center of the Milky Way and observing that the majority of gamma-ray bursts occur outside of the Milky Way galaxy. The Chandra X-ray Observatory was launched from the Columbia on STS-93 in 1999, observing black holes, quasars , supernova , and dark matter . It provided critical observations on the Sagittarius A* black hole at the center of the Milky Way galaxy and
3003-496: A potentially catastrophic flaw in the O-rings in cold conditions, but neither Morton Thiokol nor NASA assessed or corrected the problem. Shortly before takeoff, several Morton Thiokol engineers recommended delaying the launch until temperatures at Cape Canaveral warmed, but they were overruled by company management. In 1926, two chemists, Joseph C. Patrick and Nathan Mnookin, were trying to invent an inexpensive antifreeze . In
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#17327909689253146-536: A process called reptation in which each chain molecule is constrained by entanglements with neighboring chains to move within a virtual tube. The theory of reptation can explain polymer molecule dynamics and viscoelasticity . Depending on their chemical structures, polymers may be either semi-crystalline or amorphous. Semi-crystalline polymers can undergo crystallization and melting transitions , whereas amorphous polymers do not. In polymers, crystallization and melting do not suggest solid-liquid phase transitions, as in
3289-427: A result, they typically have lower melting temperatures than other polymers. When a polymer is dispersed or dissolved in a liquid, such as in commercial products like paints and glues, the chemical properties and molecular interactions influence how the solution flows and can even lead to self-assembly of the polymer into complex structures. When a polymer is applied as a coating, the chemical properties will influence
3432-540: A space station since the agency was created. In 1973, following the end of the Apollo lunar missions, NASA launched its first space station, Skylab , on the final launch of the Saturn V. Skylab reused a significant amount of Apollo and Saturn hardware, with a repurposed Saturn V third stage serving as the primary module for the space station. Damage to Skylab during its launch required spacewalks to be performed by
3575-456: A statistical distribution of chain lengths, the molecular weight is expressed in terms of weighted averages. The number-average molecular weight ( M n ) and weight-average molecular weight ( M w ) are most commonly reported. The ratio of these two values ( M w / M n ) is the dispersity ( Đ ), which is commonly used to express the width of the molecular weight distribution. The physical properties of polymer strongly depend on
3718-537: A tendency to form amorphous and semicrystalline structures rather than crystals . Polymers are studied in the fields of polymer science (which includes polymer chemistry and polymer physics ), biophysics and materials science and engineering . Historically, products arising from the linkage of repeating units by covalent chemical bonds have been the primary focus of polymer science. An emerging important area now focuses on supramolecular polymers formed by non-covalent links. Polyisoprene of latex rubber
3861-432: A variety of different but structurally related monomer residues; for example, polynucleotides such as DNA are composed of four types of nucleotide subunits. A polymer containing ionizable subunits (e.g., pendant carboxylic groups ) is known as a polyelectrolyte or ionomer , when the fraction of ionizable units is large or small respectively. The microstructure of a polymer (sometimes called configuration) relates to
4004-405: A wide-meshed cross-linking between the "main chains". Close-meshed crosslinking, on the other hand, leads to thermosets . Cross-links and branches are shown as red dots in the figures. Highly branched polymers are amorphous and the molecules in the solid interact randomly. An important microstructural feature of a polymer is its architecture and shape, which relates to the way branch points lead to
4147-814: Is a substance or material that consists of very large molecules, or macromolecules , that are constituted by many repeating subunits derived from one or more species of monomers . Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers . Their consequently large molecular mass , relative to small molecule compounds , produces unique physical properties including toughness , high elasticity , viscoelasticity , and
4290-479: Is a crucial physical parameter for polymer manufacturing, processing, and use. Below T g , molecular motions are frozen and polymers are brittle and glassy. Above T g , molecular motions are activated and polymers are rubbery and viscous. The glass-transition temperature may be engineered by altering the degree of branching or crosslinking in the polymer or by the addition of plasticizers . Whereas crystallization and melting are first-order phase transitions ,
4433-410: Is a long-chain n -alkane. There are also branched macromolecules with a main chain and side chains, in the case of polyethylene the side chains would be alkyl groups . In particular unbranched macromolecules can be in the solid state semi-crystalline, crystalline chain sections highlighted red in the figure below. While branched and unbranched polymers are usually thermoplastics, many elastomers have
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4576-400: Is also commonly present in polymer backbones, such as those of polyethylene glycol , polysaccharides (in glycosidic bonds ), and DNA (in phosphodiester bonds ). Polymerization is the process of combining many small molecules known as monomers into a covalently bonded chain or network. During the polymerization process, some chemical groups may be lost from each monomer. This happens in
4719-512: Is an average distance from the center of mass of the chain to the chain itself. Alternatively, it may be expressed in terms of pervaded volume , which is the volume spanned by the polymer chain and scales with the cube of the radius of gyration. The simplest theoretical models for polymers in the molten, amorphous state are ideal chains . Polymer properties depend of their structure and they are divided into classes according to their physical bases. Many physical and chemical properties describe how
4862-481: Is an example of a natural polymer, and the polystyrene of styrofoam is an example of a synthetic polymer. In biological contexts, essentially all biological macromolecules —i.e., proteins (polyamides), nucleic acids (polynucleotides), and polysaccharides —are purely polymeric, or are composed in large part of polymeric components. The term "polymer" derives from Greek πολύς (polus) 'many, much' and μέρος (meros) 'part'. The term
5005-428: Is composed only of styrene -based repeat units, and is classified as a homopolymer. Polyethylene terephthalate , even though produced from two different monomers ( ethylene glycol and terephthalic acid ), is usually regarded as a homopolymer because only one type of repeat unit is formed. Ethylene-vinyl acetate contains more than one variety of repeat unit and is a copolymer. Some biological polymers are composed of
5148-409: Is defined, for small strains , as the ratio of rate of change of stress to strain. Like tensile strength, this is highly relevant in polymer applications involving the physical properties of polymers, such as rubber bands. The modulus is strongly dependent on temperature. Viscoelasticity describes a complex time-dependent elastic response, which will exhibit hysteresis in the stress-strain curve when
5291-483: Is given below. NASA The National Aeronautics and Space Administration ( NASA / ˈ n æ s ə / ) is an independent agency of the U.S. federal government responsible for the civil space program , aeronautics research, and space research. Established in 1958 , it succeeded the National Advisory Committee for Aeronautics (NACA) to give the U.S. space development effort
5434-435: Is the change in refractive index with temperature also known as dn/dT. For the polymers mentioned here the (dn/dT) ~ −1.4 × 10 in units of K in the 297 ≤ T ≤ 337 K range. Most conventional polymers such as polyethylene are electrical insulators , but the development of polymers containing π-conjugated bonds has led to a wealth of polymer-based semiconductors , such as polythiophenes . This has led to many applications in
5577-563: Is the main constituent of wood and paper. Hemoglycin (previously termed hemolithin ) is a space polymer that is the first polymer of amino acids found in meteorites . The list of synthetic polymers , roughly in order of worldwide demand, includes polyethylene , polypropylene , polystyrene , polyvinyl chloride , synthetic rubber , phenol formaldehyde resin (or Bakelite ), neoprene , nylon , polyacrylonitrile , PVB , silicone , and many more. More than 330 million tons of these polymers are made every year (2015). Most commonly,
5720-590: The Faith 7 . The Mercury Program was wildly recognized as a resounding success, achieving its objectives to orbit a human in space, develop tracking and control systems, and identify other issues associated with human spaceflight. While much of NASA's attention turned to space, it did not put aside its aeronautics mission. Early aeronautics research attempted to build upon the X-1's supersonic flight to build an aircraft capable of hypersonic flight . The North American X-15
5863-710: The Apollo program , motors for the Pioneer , Surveyor , Viking , Voyager , and Magellan missions, updated CASTOR boosters for the Delta rocket , and the Space Shuttle Solid Rocket Booster . Reaction Motors powerplants propelled the X-1 and X-15 aircraft, and later Thiokol technologies were also used in the private Tier One crewed spaceplane . On March 1, 2006, NASA announced that Thiokol will be
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6006-756: The Army Ballistic Missile Agency would launch Explorer 1 , America's first satellite, on February 1, 1958. The Eisenhower Administration decided to split the United States' military and civil spaceflight programs, which were organized together under the Defense Department 's Advanced Research Projects Agency . NASA was established on July 29, 1958, with the signing of the National Aeronautics and Space Act and it began operations on October 1, 1958. As
6149-803: The Bell X-1 in a joint program with the U.S. Air Force . NACA's interest in space grew out of its rocketry program at the Pilotless Aircraft Research Division. The Soviet Union's launch of Sputnik 1 ushered in the Space Age and kicked off the Space Race . Despite NACA's early rocketry program, the responsibility for launching the first American satellite fell to the Naval Research Laboratory 's Project Vanguard , whose operational issues ensured
6292-662: The Big Bang , through the James Webb Space Telescope , the four Great Observatories , and associated programs. The Launch Services Program oversees launch operations for its uncrewed launches . NASA traces its roots to the National Advisory Committee for Aeronautics (NACA). Despite being the birthplace of aviation, by 1914 the United States recognized that it was far behind Europe in aviation capability. Determined to regain American leadership in aviation,
6435-622: The Big Bang . The James Webb Space Telescope , named after the NASA administrator who lead the Apollo program, is an infrared observatory launched in 2021. The James Webb Space Telescope is a direct successor to the Hubble Space Telescope, intended to observe the formation of the first galaxies. Other space telescopes include the Kepler space telescope , launched in 2009 to identify planets orbiting extrasolar stars that may be Terran and possibly harbor life. The first exoplanet that
6578-797: The Environmental Science Services Administration on a series of weather satellites and the agency launched its experimental Applications Technology Satellites into geosynchronous orbit. NASA's first dedicated Earth observation satellite, Landsat , was launched in 1972. This led to NASA and the National Oceanic and Atmospheric Administration jointly developing the Geostationary Operational Environmental Satellite and discovering Ozone depletion . NASA had been pursuing spaceplane development since
6721-691: The Europa and observed that the moon may hold ice or liquid water. A joint NASA- European Space Agency - Italian Space Agency mission, Cassini–Huygens , was sent to Saturn 's moon Titan , which, along with Mars and Europa, are the only celestial bodies in the Solar System suspected of being capable of harboring life. Cassini discovered three new moons of Saturn and the Huygens probe entered Titan's atmosphere. The mission discovered evidence of liquid hydrocarbon lakes on Titan and subsurface water oceans on
6864-722: The Johnson Space Center as the lead center for the design, development, and manufacturing of the Space Shuttle orbiter , while the Marshall Space Flight Center would lead the development of the launch system. NASA's series of lifting body aircraft, culminating in the joint NASA-U.S. Air Force Martin Marietta X-24 , directly informed the development of the Space Shuttle and future hypersonic flight aircraft. Official development of
7007-664: The Mars Global Surveyor orbiter and Mars Pathfinder , deploying the first Mars rover, Sojourner . During the early 2000s, the 2001 Mars Odyssey orbiter reached the planet and in 2004 the Sprit and Opportunity rovers landed on the Red Planet. This was followed in 2005 by the Mars Reconnaissance Orbiter and 2007 Phoenix Mars lander. The 2012 landing of Curiosity discovered that
7150-555: The Morton Salt concern, the Simoniz automotive products brand, and various chemical concerns) with the merged company called Morton Thiokol Incorporated (MTI). In 1986, an O-ring fault in an MTI SRB destroyed Space Shuttle Challenger in flight. The company was found at fault for the destruction of Challenger and deaths of the astronauts, as a direct result of pressure from NASA to launch, based on inconclusive evidence of
7293-614: The Orbiting Geophysical Observatory in the 1960s and 1970s to look down at Earth and observe its interactions with the Sun. The Uhuru satellite was the first dedicated x-ray telescope, mapping 85% of the sky and discovering a large number of black holes . Launched in the 1990s and early 2000s, the Great Observatories program are among NASA's most powerful telescopes. The Hubble Space Telescope
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#17327909689257436-658: The STS-1 mission, designed to serve as a flight test for the new spaceplane. NASA intended for the Space Shuttle to replace expendable launch systems like the Air Force's Atlas , Delta , and Titan and the European Space Agency 's Ariane . The Space Shuttle's Spacelab payload, developed by the European Space Agency, increased the scientific capabilities of shuttle missions over anything NASA
7579-635: The STS-60 mission in 1994 and the Discovery rendezvoused, but did not dock with, the Russian Mir in the STS-63 mission. This was followed by Atlantis' STS-71 mission where it accomplished the initial intended mission for the Space Shuttle, docking with a space station and transferring supplies and personnel. The Shuttle- Mir program would continue until 1998, when a series of orbital accidents on
7722-477: The Space Race when the Soviet Union gave up its lunar ambitions. As the first human to step on the surface of the Moon, Neil Armstrong uttered the now famous words: That's one small step for man, one giant leap for mankind. NASA would conduct six total lunar landings as part of the Apollo program, with Apollo 17 concluding the program in 1972. Wernher von Braun had advocated for NASA to develop
7865-620: The Space Shuttle began in 1972, with Rockwell International contracted to design the orbiter and engines, Martin Marietta for the external fuel tank , and Morton Thiokol for the solid rocket boosters . NASA acquired six orbiters: the Enterprise , Columbia , Challenger , Discovery , Atlantis , and Endeavour The Space Shuttle program also allowed NASA to make major changes to its Astronaut Corps . While almost all previous astronauts were Air Force or Naval test pilots,
8008-620: The United States Congress created the Aviation Section of the U.S. Army Signal Corps in 1914 and established NACA in 1915 to foster aeronautical research and development. Over the next forty years, NACA would conduct aeronautical research in support of the U.S. Air Force , U.S. Army , U.S. Navy , and the civil aviation sector. After the end of World War II , NACA became interested in the possibilities of guided missiles and supersonic aircraft, developing and testing
8151-793: The Vietnam War . In 1971, an explosion in the magnesium flare assembly facility at the Woodbine plant killed 29 and injured 50. In 1974, Thiokol won the contract to build the solid rocket booster (SRB) for the Space Shuttle (Nov 29, 1973). In 1975, Thiokol succeeded Sperry Rand as operator of the large Louisiana Army Ammunition Plant near Minden , Louisiana . In 1978, the company sold its ski lift division to CTEC and its snow equipment division to Logan Manufacturing Company (LMC), owned by John DeLorean . In 1980, Thiokol acquired Carlisle Chemical Company of Cincinnati, Ohio . In 1982, Thiokol merged with Morton-Norwich products (owners of
8294-405: The inner planets . Despite these successes, Congress was unwilling to fund further interplanetary missions and NASA Administrator James Webb suspended all future interplanetary probes to focus resources on the Apollo program. Following the conclusion of the Apollo program, NASA resumed launching interplanetary probes and expanded its space science program. The first planet tagged for exploration
8437-524: The 1960s, blending the administration's dual aeronautics and space missions. NASA viewed a spaceplane as part of a larger program, providing routine and economical logistical support to a space station in Earth orbit that would be used as a hub for lunar and Mars missions. A reusable launch vehicle would then have ended the need for expensive and expendable boosters like the Saturn V . In 1969, NASA designated
8580-679: The 44 commercial companies that contracted with NASA to deploy their satellites to return to expendable launch vehicles. When the Space Shuttle returned to flight with the STS-26 mission, it had undergone significant modifications to improve its reliability and safety. Following the collapse of the Soviet Union, the Russian Federation and United States initiated the Shuttle- Mir program . The first Russian cosmonaut flew on
8723-630: The Air Force as the military space lead. Plans for human spaceflight began in the U.S. Armed Forces prior to NASA's creation. The Air Force's Man in Space Soonest project formed in 1956, coupled with the Army's Project Adam, served as the foundation for Project Mercury . NASA established the Space Task Group to manage the program, which would conduct crewed sub-orbital flights with the Army's Redstone rockets and orbital flights with
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#17327909689258866-501: The Air Force's Atlas launch vehicles. While NASA intended for its first astronauts to be civilians, President Eisenhower directed that they be selected from the military. The Mercury 7 astronauts included three Air Force pilots, three Navy aviators, and one Marine Corps pilot. On May 5, 1961, Alan Shepard became the first American to enter space, performing a suborbital spaceflight in the Freedom 7 . This flight occurred less than
9009-410: The Apollo program. Despite attacks on the goal of landing astronauts on the Moon from the former president Dwight Eisenhower and 1964 presidential candidate Barry Goldwater , President Kennedy was able to protect NASA's growing budget, of which 50% went directly to human spaceflight and it was later estimated that, at its height, 5% of Americans worked on some aspect of the Apollo program. Mirroring
9152-685: The Army Ballistic Missile Agency's original Saturn I . The Apollo spacecraft was designed and built by North American Aviation , while the Apollo Lunar Module was designed and built by Grumman . To develop the spaceflight skills and equipment required for a lunar mission, NASA initiated Project Gemini . Using a modified Air Force Titan II launch vehicle, the Gemini capsule could hold two astronauts for flights of over two weeks. Gemini pioneered
9295-545: The DNA to RNA and subsequently translate that information to synthesize the specified protein from amino acids . The protein may be modified further following translation in order to provide appropriate structure and functioning. There are other biopolymers such as rubber , suberin , melanin , and lignin . Naturally occurring polymers such as cotton , starch , and rubber were familiar materials for years before synthetic polymers such as polyethene and perspex appeared on
9438-485: The Department of Defense's program management concept using redundant systems in building the first intercontinental ballistic missiles, NASA requested the Air Force assign Major General Samuel C. Phillips to the space agency where he would serve as the director of the Apollo program. Development of the Saturn V rocket was led by Wernher von Braun and his team at the Marshall Space Flight Center , derived from
9581-439: The Keplar space telescope confirmed was Kepler-22b , orbiting within the habitable zone of its star. NASA also launched a number of different satellites to study Earth, such as Television Infrared Observation Satellite (TIROS) in 1960, which was the first weather satellite. NASA and the United States Weather Bureau cooperated on future TIROS and the second generation Nimbus program of weather satellites. It also worked with
9724-448: The Martian interior. The 2021 Perseverance rover carried the first extraplanetary aircraft, a helicopter named Ingenuity . NASA also launched missions to Mercury in 2004, with the MESSENGER probe demonstrating as the first use of a solar sail . NASA also launched probes to the outer Solar System starting in the 1960s. Pioneer 10 was the first probe to the outer planets, flying by Jupiter , while Pioneer 11 provided
9867-402: The Moon and going to Mars. Embracing this approach, NASA's Commercial Crew Program started by contracting cargo delivery to the International Space Station and flew its first operational contracted mission on SpaceX Crew-1 . This marked the first time since the retirement of the Space Shuttle that NASA was able to launch its own astronauts on an American spacecraft from the United States, ending
10010-404: The Moon and returning him safely to Earth by the end of the 1960s and installed James E. Webb as NASA administrator to achieve this goal. On May 25, 1961, President Kennedy openly declared this goal in his "Urgent National Needs" speech to the United States Congress, declaring: I believe this Nation should commit itself to achieving the goal, before this decade is out, of landing a man on
10153-427: The Moon and returning him safely to Earth. No single space project in this period will be more impressive to mankind, or more important for the long-range exploration of space; and none will be so difficult or expensive to accomplish. Kennedy gave his " We choose to go to the Moon " speech the next year, on September 12, 1962 at Rice University , where he addressed the nation hoping to reinforce public support for
10296-557: The Russians be included. In 1993, the Clinton Administration announced that the Space Station Freedom would become the International Space Station in an agreement with the Russian Federation. This allowed the Russians to maintain their space program through an infusion of American currency to maintain their status as one of the two premier space programs. While the United States built and launched
10439-588: The Russians to fly to the International Space Station for four days, despite the opposition of NASA to the idea. Advocates of this new commercial approach for NASA included former astronaut Buzz Aldrin , who remarked that it would return NASA to its roots as a research and development agency, with commercial entities actually operating the space systems. Having corporations take over orbital operations would also allow NASA to focus all its efforts on deep space exploration and returning humans to
10582-422: The Solar System. Mars has long been a planet of intense fascination for NASA, being suspected of potentially having harbored life. Mariner 5 was the first NASA spacecraft to flyby Mars, followed by Mariner 6 and Mariner 7 . Mariner 9 was the first orbital mission to Mars. Launched in 1975, Viking program consisted of two landings on Mars in 1976. Follow-on missions would not be launched until 1996, with
10725-574: The Space Shuttle Columbia disaster in 2003, NASA was forced to rely on Russian Soyuz launches for its astronauts and the 2011 retirement of the Space Shuttle accelerated the station's completion. In the 1980s, right after the first flight of the Space Shuttle, NASA started a joint program with the Department of Defense to develop the Rockwell X-30 National Aerospace Plane. NASA realized that
10868-418: The Space Shuttle allowed NASA to begin recruiting more non-military scientific and technical experts. A prime example is Sally Ride , who became the first American woman to fly in space on STS-7 . This new astronaut selection process also allowed NASA to accept exchange astronauts from U.S. allies and partners for the first time. The first Space Shuttle flight occurred in 1981, when the Columbia launched on
11011-514: The Space Shuttle and expand space exploration beyond low Earth orbit. Constellation was intended to use a significant amount of former Space Shuttle equipment and return astronauts to the Moon. This program was canceled by the Obama Administration . Former astronauts Neil Armstrong , Gene Cernan , and Jim Lovell sent a letter to President Barack Obama to warn him that if the United States did not get new human spaceflight ability,
11154-554: The Space Shuttle began flying, selling it as an orbital laboratory, repair station, and a jumping off point for lunar and Mars missions. NASA found a strong advocate in President Ronald Reagan , who declared in a 1984 speech: America has always been greatest when we dared to be great. We can reach for greatness again. We can follow our dreams to distant stars, living and working in space for peaceful, economic, and scientific gain. Tonight I am directing NASA to develop
11297-686: The Space Shuttle, while a massive technological accomplishment, would not be able to live up to all its promises. Designed to be a single-stage-to-orbit spaceplane, the X-30 had both civil and military applications. With the end of the Cold War , the X-30 was canceled in 1992 before reaching flight status. Following the Space Shuttle Columbia disaster in 2003, President Bush started the Constellation program to smoothly replace
11440-483: The Space Shuttle. Due to technical challenges, the spacecraft was cancelled in 2001. Despite this, it was the first time a commercial space company directly expended a significant amount of its resources into spacecraft development. The advent of space tourism also forced NASA to challenge its assumption that only governments would have people in space. The first space tourist was Dennis Tito , an American investment manager and former aerospace engineer who contracted with
11583-507: The Space Station Freedom was controversial, with much of the debate centering on cost. Several redesigns to reduce cost were conducted in the early 1990s, stripping away much of its functions. Despite calls for Congress to terminate the program, it continued, in large part because by 1992 it had created 75,000 jobs across 39 states. By 1993, President Bill Clinton attempted to significantly reduce NASA's budget and directed costs be significantly reduced, aerospace industry jobs were not lost, and
11726-576: The Trident I and Trident II missiles. Thiokol produces powerplants for numerous U.S. military missile systems, including AIM-9 Sidewinder , AGM-88 HARM , AGM-65 Maverick , AGM-69 SRAM , and AIR-2 Genie . Thiokol also produced a variety of liquid and solid rocket motors for the US space program , including deorbit motors for the Mercury and Gemini programs, rocket stages and separation rocket motors for
11869-602: The U.S. risked become a second or third-rate space power. As early as the Reagan Administration, there had been calls for NASA to expand private sector involvement in space exploration rather than do it all in-house. In the 1990s, NASA and Lockheed Martin entered into an agreement to develop the Lockheed Martin X-33 demonstrator of the VentureStar spaceplane, which was intended to replace
12012-536: The US's premier aeronautics agency, NACA formed the core of NASA's new structure by reassigning 8,000 employees and three major research laboratories. NASA also proceeded to absorb the Naval Research Laboratory's Project Vanguard, the Army's Jet Propulsion Laboratory (JPL), and the Army Ballistic Missile Agency under Wernher von Braun . This left NASA firmly as the United States' civil space lead and
12155-708: The USAF in Alaska and other northern regions, and are now popular with private owners as dependable snowcats and for all-terrain transport. Thiokol pioneered the short-burn rocket motors used in aircraft ejection seats . The company also produced a number of the earliest practical airbag systems, building the high-speed sodium azide exothermic gas generators used to inflate the bags. Thiokol bags were first used in U.S. military aircraft, before being adapted to space exploration ( Mars Pathfinder bounced down on Mars on Thiokol airbags) and automotive airbags. Thiokol's generators form
12298-715: The XM33 Pollux, TX-18 Falcon, and TX-135 Nike-Zeus systems. It closed in 1996. In the mid-1950s the company bought extensive lands in Utah for its rocket test range. Thiokol was involved in two major accidents with loss of life. On February 3, 1971, at a Thiokol chemical plant southeast of Woodbine, Georgia , a fire entered a storage facility holding nearly five tons of ignition pellets, flares, and other highly flammable materials. The facility exploded , killing 29 people and severely wounding more than 50 others, many with severed limbs. Windows were shattered 11 miles (18 km) away and
12441-441: The adhesion of the coating and how it interacts with external materials, such as superhydrophobic polymer coatings leading to water resistance. Overall the chemical properties of a polymer are important elements for designing new polymeric material products. Polymers such as PMMA and HEMA:MMA are used as matrices in the gain medium of solid-state dye lasers , also known as solid-state dye-doped polymer lasers. These polymers have
12584-434: The backbone in a variety of ways. A copolymer containing a controlled arrangement of monomers is called a sequence-controlled polymer . Alternating, periodic and block copolymers are simple examples of sequence-controlled polymers . Tacticity describes the relative stereochemistry of chiral centers in neighboring structural units within a macromolecule. There are three types of tacticity: isotactic (all substituents on
12727-421: The case of water or other molecular fluids. Instead, crystallization and melting refer to the phase transitions between two solid states ( i.e. , semi-crystalline and amorphous). Crystallization occurs above the glass-transition temperature ( T g ) and below the melting temperature ( T m ). All polymers (amorphous or semi-crystalline) go through glass transitions . The glass-transition temperature ( T g )
12870-704: The company restructured itself to concentrate on its rocket products and related technologies. John Z. DeLorean purchased the Thiokol snowcat operation and renamed it DMC. DMC continued to manufacture snowcats until 1988, when the company was renamed LMC . LMC continued making snowcats for 12 more years but ceased operations in 2000. Thiokol produced snow vehicles with a wide range of capabilities and duties. The company also produced several utility based vehicles based on their snowcat tracked vehicle, in addition to larger snow grooming machines suitable for use on steep ski-slopes. Thiokol machines were used in ski resorts, operated by
13013-476: The continuously linked backbone of a polymer used for the preparation of plastics consists mainly of carbon atoms. A simple example is polyethylene ('polythene' in British English), whose repeat unit or monomer is ethylene . Many other structures do exist; for example, elements such as silicon form familiar materials such as silicones, examples being Silly Putty and waterproof plumbing sealant. Oxygen
13156-402: The core of more than 60% of airbags sold worldwide. Polymer A polymer is a substance composed of macromolecules. A macromolecule is a molecule of high relative molecular mass, the structure of which essentially comprises the multiple repetition of units derived, actually or conceptually, from molecules of low relative molecular mass. A polymer ( / ˈ p ɒ l ɪ m ər / )
13299-399: The course of an experiment involving ethylene dichloride and sodium polysulfide , they created a gum whose outstanding characteristic was a terrible odor. The substance clogged a sink in the laboratory, and none of the solvents used to remove it were successful. The frustrated chemists realized that the resistance of the material to any kind of solvent was a useful property. They had invented
13442-536: The degree of crystallinity may be expressed in terms of a weight fraction or volume fraction of crystalline material. Few synthetic polymers are entirely crystalline. The crystallinity of polymers is characterized by their degree of crystallinity, ranging from zero for a completely non-crystalline polymer to one for a theoretical completely crystalline polymer. Polymers with microcrystalline regions are generally tougher (can be bent more without breaking) and more impact-resistant than totally amorphous polymers. Polymers with
13585-862: The development of the Orion spacecraft and the Space Launch System for the lunar Artemis program . NASA's science division is focused on better understanding Earth through the Earth Observing System ; advancing heliophysics through the efforts of the Science Mission Directorate 's Heliophysics Research Program; exploring bodies throughout the Solar System with advanced robotic spacecraft such as New Horizons and planetary rovers such as Perseverance ; and researching astrophysics topics, such as
13728-400: The driving force for mixing is usually entropy , not interaction energy. In other words, miscible materials usually form a solution not because their interaction with each other is more favorable than their self-interaction, but because of an increase in entropy and hence free energy associated with increasing the amount of volume available to each component. This increase in entropy scales with
13871-593: The explosion was heard for 50 miles (80 km) around. Georgia law prevented the employees from suing their employer because they were covered by workers' compensation insurance. On January 28, 1986, the Space Shuttle Challenger exploded 73 seconds into its flight , killing all seven crew members. An investigation found the cause to be two failed O-ring seals in the Space Shuttle's right solid rocket booster , which had been manufactured by Morton Thiokol. Test data from as early as 1977 had revealed
14014-419: The failure of O-rings on the solid rocket boosters when subject to freezing temperatures. (See Space Shuttle Challenger disaster ). In 1989, Morton Thiokol split, with most of the chemical concern going with Morton but the propulsion systems division became Thiokol Inc. Then in 1998, Thiokol changed its name to Cordant Technologies. Also in 1998, Thiokol branded polymer products purchased by PolySpec L.P.,
14157-417: The field of organic electronics . Nowadays, synthetic polymers are used in almost all walks of life. Modern society would look very different without them. The spreading of polymer use is connected to their unique properties: low density, low cost, good thermal/electrical insulation properties, high resistance to corrosion, low-energy demanding polymer manufacture and facile processing into final products. For
14300-420: The first close up view of the planet. Both probes became the first objects to leave the Solar System. The Voyager program launched in 1977, conducting flybys of Jupiter and Saturn , Neptune , and Uranus on a trajectory to leave the Solar System. The Galileo spacecraft, deployed from the Space Shuttle flight STS-34 , was the first spacecraft to orbit Jupiter, discovering evidence of subsurface oceans on
14443-515: The first crew to make it habitable and operational. Skylab hosted nine missions and was decommissioned in 1974 and deorbited in 1979, two years prior to the first launch of the Space Shuttle and any possibility of boosting its orbit. In 1975, the Apollo–Soyuz mission was the first ever international spaceflight and a major diplomatic accomplishment between the Cold War rivals, which also marked
14586-402: The first humans to see the Earth as a globe in space, the first to witness an Earthrise , and the first to see and manually photograph the far side of the Moon. The first lunar landing was conducted by Apollo 11. Commanded by Neil Armstrong with astronauts Buzz Aldrin and Michael Collins , Apollo 11 was one of the most significant missions in NASA's history, marking the end of
14729-527: The free energy of mixing for polymer solutions and thereby making solvation less favorable, and thereby making the availability of concentrated solutions of polymers far rarer than those of small molecules. Furthermore, the phase behavior of polymer solutions and mixtures is more complex than that of small molecule mixtures. Whereas most small molecule solutions exhibit only an upper critical solution temperature phase transition (UCST), at which phase separation occurs with cooling, polymer mixtures commonly exhibit
14872-401: The glass transition is not. The glass transition shares features of second-order phase transitions (such as discontinuity in the heat capacity, as shown in the figure), but it is generally not considered a thermodynamic transition between equilibrium states. In general, polymeric mixtures are far less miscible than mixtures of small molecule materials. This effect results from the fact that
15015-415: The individual chains more strongly in position and resist deformations and matrix breakup, both at higher stresses and higher temperatures. Copolymers are classified either as statistical copolymers, alternating copolymers, block copolymers, graft copolymers or gradient copolymers. In the schematic figure below, Ⓐ and Ⓑ symbolize the two repeat units . Monomers within a copolymer may be organized along
15158-451: The last flight of the Apollo capsule. Flown in 1975, a U.S. Apollo spacecraft docked with a Soviet Soyuz capsule. During the 1960s, NASA started its space science and interplanetary probe program. The Mariner program was its flagship program, launching probes to Venus , Mars , and Mercury in the 1960s. The Jet Propulsion Laboratory was the lead NASA center for robotic interplanetary exploration, making significant discoveries about
15301-451: The latter case, increasing the polymer chain length 10-fold would increase the viscosity over 1000 times. Increasing chain length furthermore tends to decrease chain mobility, increase strength and toughness, and increase the glass-transition temperature (T g ). This is a result of the increase in chain interactions such as van der Waals attractions and entanglements that come with increased chain length. These interactions tend to fix
15444-436: The length (or equivalently, the molecular weight) of the polymer chain. One important example of the physical consequences of the molecular weight is the scaling of the viscosity (resistance to flow) in the melt. The influence of the weight-average molecular weight ( M w {\displaystyle M_{w}} ) on the melt viscosity ( η {\displaystyle \eta } ) depends on whether
15587-417: The load is removed. Dynamic mechanical analysis or DMA measures this complex modulus by oscillating the load and measuring the resulting strain as a function of time. Transport properties such as diffusivity describe how rapidly molecules move through the polymer matrix. These are very important in many applications of polymers for films and membranes. The movement of individual macromolecules occurs by
15730-434: The majority of the International Space Station, Russia, Canada, Japan, and the European Space Agency all contributed components. Despite NASA's insistence that costs would be kept at a budget of $ 17.4, they kept rising and NASA had to transfer funds from other programs to keep the International Space Station solvent. Ultimately, the total cost of the station was $ 150 billion, with the United States paying for two-thirds.Following
15873-436: The market. Many commercially important polymers are synthesized by chemical modification of naturally occurring polymers. Prominent examples include the reaction of nitric acid and cellulose to form nitrocellulose and the formation of vulcanized rubber by heating natural rubber in the presence of sulfur . Ways in which polymers can be modified include oxidation , cross-linking , and end-capping . The structure of
16016-413: The material will endure before failure. This is very important in applications that rely upon a polymer's physical strength or durability. For example, a rubber band with a higher tensile strength will hold a greater weight before snapping. In general, tensile strength increases with polymer chain length and crosslinking of polymer chains. Young's modulus quantifies the elasticity of the polymer. It
16159-634: The moon of Enceladus , which could harbor life. Finally launched in 2006, the New Horizons mission was the first spacecraft to visit Pluto and the Kuiper Belt . Beyond interplanetary probes, NASA has launched many space telescopes . Launched in the 1960s, the Orbiting Astronomical Observatory were NASA's first orbital telescopes, providing ultraviolet, gamma-ray, x-ray, and infrared observations. NASA launched
16302-444: The number of particles (or moles) being mixed. Since polymeric molecules are much larger and hence generally have much higher specific volumes than small molecules, the number of molecules involved in a polymeric mixture is far smaller than the number in a small molecule mixture of equal volume. The energetics of mixing, on the other hand, is comparable on a per volume basis for polymeric and small molecule mixtures. This tends to increase
16445-719: The partially negatively charged oxygen atoms in C=O groups on another. These strong hydrogen bonds, for example, result in the high tensile strength and melting point of polymers containing urethane or urea linkages. Polyesters have dipole-dipole bonding between the oxygen atoms in C=O groups and the hydrogen atoms in H-C groups. Dipole bonding is not as strong as hydrogen bonding, so a polyester's melting point and strength are lower than Kevlar 's ( Twaron ), but polyesters have greater flexibility. Polymers with non-polar units such as polyethylene interact only through weak Van der Waals forces . As
16588-422: The physical arrangement of monomer residues along the backbone of the chain. These are the elements of polymer structure that require the breaking of a covalent bond in order to change. Various polymer structures can be produced depending on the monomers and reaction conditions: A polymer may consist of linear macromolecules containing each only one unbranched chain. In the case of unbranched polyethylene, this chain
16731-399: The polymer and create gaps between polymer chains for greater mobility and fewer interchain interactions. A good example of the action of plasticizers is related to polyvinylchlorides or PVCs. A uPVC, or unplasticized polyvinylchloride, is used for things such as pipes. A pipe has no plasticizers in it, because it needs to remain strong and heat-resistant. Plasticized PVC is used in clothing for
16874-426: The polymer at the scale of a single chain. The microstructure determines the possibility for the polymer to form phases with different arrangements, for example through crystallization , the glass transition or microphase separation . These features play a major role in determining the physical and chemical properties of a polymer. The identity of the repeat units (monomer residues, also known as "mers") comprising
17017-543: The polymer can lend the polymer to ionic bonding or hydrogen bonding between its own chains. These stronger forces typically result in higher tensile strength and higher crystalline melting points. The intermolecular forces in polymers can be affected by dipoles in the monomer units. Polymers containing amide or carbonyl groups can form hydrogen bonds between adjacent chains; the partially positively charged hydrogen atoms in N-H groups of one chain are strongly attracted to
17160-403: The polymer is above or below the onset of entanglements . Below the entanglement molecular weight , η ∼ M w 1 {\displaystyle \eta \sim {M_{w}}^{1}} , whereas above the entanglement molecular weight, η ∼ M w 3.4 {\displaystyle \eta \sim {M_{w}}^{3.4}} . In
17303-583: The polymerization of PET polyester . The monomers are terephthalic acid (HOOC—C 6 H 4 —COOH) and ethylene glycol (HO—CH 2 —CH 2 —OH) but the repeating unit is —OC—C 6 H 4 —COO—CH 2 —CH 2 —O—, which corresponds to the combination of the two monomers with the loss of two water molecules. The distinct piece of each monomer that is incorporated into the polymer is known as a repeat unit or monomer residue. Synthetic methods are generally divided into two categories, step-growth polymerization and chain polymerization . The essential difference between
17446-536: The prime contractor for the new Crew Launch Vehicle (CLV), to be known as the Ares I , which will put the Orion spacecraft (formerly known as the "Crew Exploration Vehicle") into low Earth orbit , along with the five-segment SRBs for the heavy-lift Cargo Launch Vehicle (CaLV), known as the Ares V . In addition to ski lifts, Thiokol produced a range of equipment for ski resorts including snowcats and snow grooming vehicles. These businesses were spun off in 1978 when
17589-625: The radiation levels on Mars were equal to those on the International Space Station , greatly increasing the possibility of Human exploration, and observed the key chemical ingredients for life to occur. In 2013, the Mars Atmosphere and Volatile Evolution ( MAVEN ) mission observed the Martian upper atmosphere and space environment and in 2018, the Interior exploration using Seismic Investigations Geodesy, and Heat Transport ( InSight ) studied
17732-437: The same side), atactic (random placement of substituents), and syndiotactic (alternating placement of substituents). Polymer morphology generally describes the arrangement and microscale ordering of polymer chains in space. The macroscopic physical properties of a polymer are related to the interactions between the polymer chains. When applied to polymers, the term crystalline has a somewhat ambiguous usage. In some cases,
17875-507: The satellites were repaired and relaunched. Despite ushering in a new era of spaceflight, where NASA was contracting launch services to commercial companies, the Space Shuttle was criticized for not being as reusable and cost-effective as advertised. In 1986, Challenger disaster on the STS-51L mission resulted in the loss of the spacecraft and all seven astronauts on launch, grounding the entire space shuttle fleet for 36 months and forced
18018-676: The separation of dark and regular matter during galactic collisions. Finally, the Spitzer Space Telescope is an infrared telescope launched in 2003 from a Delta II rocket. It is in a trailing orbit around the Sun, following the Earth and discovered the existence of brown dwarf stars . Other telescopes, such as the Cosmic Background Explorer and the Wilkinson Microwave Anisotropy Probe , provided evidence to support
18161-508: The setback caused by the Apollo 1 fire, which killed three astronauts, the program proceeded. Apollo 8 was the first crewed spacecraft to leave low Earth orbit and the first human spaceflight to reach the Moon . The crew orbited the Moon ten times on December 24 and 25, 1968, and then traveled safely back to Earth . The three Apollo 8 astronauts— Frank Borman , James Lovell , and William Anders —were
18304-512: The size of individual polymer coils in solution. A variety of techniques may be employed for the synthesis of a polymeric material with a range of architectures, for example living polymerization . A common means of expressing the length of a chain is the degree of polymerization , which quantifies the number of monomers incorporated into the chain. As with other molecules, a polymer's size may also be expressed in terms of molecular weight . Since synthetic polymerization techniques typically yield
18447-549: The space shuttle be retired. In 2006, the Space Shuttle returned to flight, conducting several mission to service the Hubble Space Telescope , but was retired following the STS-135 resupply mission to the International Space Station in 2011. NASA never gave up on the idea of a space station after Skylab's reentry in 1979. The agency began lobbying politicians to support building a larger space station as soon as
18590-481: The space station spelled an end to the program. In 2003, a second space shuttle was destroyed when the Columbia was destroyed upon reentry during the STS-107 mission, resulting in the loss of the spacecraft and all seven astronauts. This accident marked the beginning of the retiring of the Space Shuttle program, with President George W. Bush directing that upon the completion of the International Space Station,
18733-448: The states is known as a coil–globule transition . Inclusion of plasticizers tends to lower T g and increase polymer flexibility. Addition of the plasticizer will also modify dependence of the glass-transition temperature T g on the cooling rate. The mobility of the chain can further change if the molecules of plasticizer give rise to hydrogen bonding formation. Plasticizers are generally small molecules that are chemically similar to
18876-686: The term crystalline finds identical usage to that used in conventional crystallography . For example, the structure of a crystalline protein or polynucleotide, such as a sample prepared for x-ray crystallography , may be defined in terms of a conventional unit cell composed of one or more polymer molecules with cell dimensions of hundreds of angstroms or more. A synthetic polymer may be loosely described as crystalline if it contains regions of three-dimensional ordering on atomic (rather than macromolecular) length scales, usually arising from intramolecular folding or stacking of adjacent chains. Synthetic polymers may consist of both crystalline and amorphous regions;
19019-481: The third stage of the Trident missile and had earlier bought Hercules Aerospace Co., builder of the second stage. With the purchase of Thiokol, makers of the missile's first stage, ATK controlled the lion's share of the US solid rocket-fuel market. In 2005, ATK-Thiokol won the contract to produce the Ares I launch vehicle first stage for NASA 's Project Constellation . In 2006, Alliant Techsystems (ATK) Inc.
19162-555: The two is that in chain polymerization, monomers are added to the chain one at a time only, such as in polystyrene , whereas in step-growth polymerization chains of monomers may combine with one another directly, such as in polyester . Step-growth polymerization can be divided into polycondensation , in which low-molar-mass by-product is formed in every reaction step, and polyaddition . Newer methods, such as plasma polymerization do not fit neatly into either category. Synthetic polymerization reactions may be carried out with or without
19305-579: The use of fuel cells instead of batteries, and conducted the first American spacewalks and rendezvous operations . The Ranger Program was started in the 1950s as a response to Soviet lunar exploration, however most missions ended in failure. The Lunar Orbiter program had greater success, mapping the surface in preparation for Apollo landings and measured Selenography , conducted meteoroid detection, and measured radiation levels. The Surveyor program conducted uncrewed lunar landings and takeoffs, as well as taking surface and regolith observations. Despite
19448-668: The use of thiokol as a stabilizer in solid-fuel rockets . In 1948, a plant in Elkton, Maryland was opened, producing solid rocket motors. In 1949, Thiokol produced the TX-18 Falcon missile, the world's first solid-fueled missile system. In 1957, anticipating the forthcoming Minuteman contract, the company built its plant at Brigham City, Utah, and Thiokol Huntsville began building XM33 Pollux missiles. In 1958, Thiokol merged with Reaction Motors Inc. (RMI), makers of liquid propellant rocket motor systems. Also in 1958, Thiokol received
19591-461: Was Venus , sharing many similar characteristics to Earth. First visited by American Mariner 2 spacecraft, Venus was observed to be a hot and inhospitable planet. Follow-on missions included the Pioneer Venus project in the 1970s and Magellan , which performed radar mapping of Venus' surface in the 1980s and 1990s. Future missions were flybys of Venus, on their way to other destinations in
19734-434: Was a joint NASA–U.S. Air Force program, with the hypersonic test aircraft becoming the first non-dedicated spacecraft to cross from the atmosphere to outer space. The X-15 also served as a testbed for Apollo program technologies, as well as ramjet and scramjet propulsion. Escalations in the Cold War between the United States and Soviet Union prompted President John F. Kennedy to charge NASA with landing an American on
19877-683: Was able to previously accomplish. NASA launched its first commercial satellites on the STS-5 mission and in 1984, the STS-41-C mission conducted the world's first on-orbit satellite servicing mission when the Challenger captured and repaired the malfunctioning Solar Maximum Mission satellite. It also had the capability to return malfunctioning satellite to Earth, like it did with the Palapa B2 and Westar 6 satellites. Once returned to Earth,
20020-472: Was also a concern with sharing sensitive space technologies with the Europeans, which had the potential to dilute America's technical lead. Ultimately, an international agreement to develop the Space Station Freedom program would be signed with thirteen countries in 1985, including the European Space Agency member states, Canada , and Japan . Despite its status as the first international space program,
20163-605: Was coined in 1833 by Jöns Jacob Berzelius , though with a definition distinct from the modern IUPAC definition. The modern concept of polymers as covalently bonded macromolecular structures was proposed in 1920 by Hermann Staudinger , who spent the next decade finding experimental evidence for this hypothesis. Polymers are of two types: naturally occurring and synthetic or man made . Natural polymeric materials such as hemp , shellac , amber , wool , silk , and natural rubber have been used for centuries. A variety of other natural polymers exist, such as cellulose , which
20306-497: Was launched in 1990 on STS-31 from the Discovery and could view galaxies 15 billion light years away. A major defect in the telescope's mirror could have crippled the program, had NASA not used computer enhancement to compensate for the imperfection and launched five Space Shuttle servicing flights to replace the damaged components. The Compton Gamma Ray Observatory was launched from the Atlantis on STS-37 in 1991, discovering
20449-583: Was renamed ATK-Thiokol to ATK Launch Systems Group. In 2014, Orbital ATK was formed from the merger of Orbital Sciences Corporation and parts of Alliant Techsystems. In 2018, Orbital ATK was purchased by Northrop Grumman . Products made by the aerospace divisions of RMI and Thiokol include motors used in Subroc , the Pershing missile , the Peacekeeper missile , Poseidon missile , Minuteman missile , and
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