A thimble is a small pitted cup worn on the finger that protects it from being pricked or poked by a needle while sewing . The Old English word þȳmel , the ancestor of thimble, is derived from Old English þūma , the ancestor of the English word thumb .
162-553: As the purpose of a thimble is to prevent discomfort while sewing by providing a barrier between fingertips and the blunt end of a needle, it is likely that the earliest thimbles were created closely following the invention of sewing. According to the United Kingdom Detector Finds Database, thimbles dating to the 10th century have been found in England, and thimbles were in widespread use there by
324-486: A bullet cast from silver is often supposed in such folklore the only weapon that is effective against a werewolf , witch , or other monsters . From this the idiom of a silver bullet developed into figuratively referring to any simple solution with very high effectiveness or almost miraculous results, as in the widely discussed software engineering paper " No Silver Bullet ." Other powers attributed to silver include detection of poison and facilitation of passage into
486-419: A color name . Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm. At wavelengths shorter than 450 nm, silver's reflectivity is inferior to that of aluminium and drops to zero near 310 nm. Very high electrical and thermal conductivity are common to the elements in group 11, because their single s electron is free and does not interact with
648-470: A precious metal . Silver metal is used in many bullion coins , sometimes alongside gold : while it is more abundant than gold, it is much less abundant as a native metal . Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of the seven metals of antiquity , silver has had an enduring role in most human cultures. Other than in currency and as an investment medium ( coins and bullion ), silver
810-631: A Catholic aristocrat exiled to Spain and secretary to King Philip II. Three letters exist today describing the interview, detailing what Arthur proclaimed to be the story of his life, from birth in the royal palace to the time of his arrival in Spain. However, this failed to convince the Spaniards: Englefield admitted to King Philip that Arthur's "claim at present amounts to nothing", but suggested that "he should not be allowed to get away, but [...] kept very secure." The King agreed, and Arthur
972-410: A body politic to govern, so shall I desire you all ... to be assistant to me, that I with my ruling and you with your service may make a good account to Almighty God and leave some comfort to our posterity on earth. I mean to direct all my actions by good advice and counsel. As her triumphal progress wound through the city on the eve of the coronation ceremony , she was welcomed wholeheartedly by
1134-592: A non-Indo-European Wanderwort . Some scholars have thus proposed a Paleo-Hispanic origin, pointing to the Basque form zilharr as an evidence. The chemical symbol Ag is from the Latin word for silver , argentum (compare Ancient Greek ἄργυρος , árgyros ), from the Proto-Indo-European root * h₂erǵ- (formerly reconstructed as *arǵ- ), meaning ' white ' or ' shining ' . This
1296-427: A person has three thimbles given to them, they will never be married. Most of these thimble makers no longer create thimbles. Thimblettes (also known as rubber finger, rubber thimbles and finger cones) are soft thimbles, made predominately of rubber, used primarily for leafing through or counting documents, bank notes, tickets, or forms. They also protect against paper cuts as a secondary function. Unlike thimbles,
1458-600: A queen, having reigned such a time, lived and died a virgin". Later on, poets and writers took up the theme and developed an iconography that exalted Elizabeth. Public tributes to the Virgin by 1578 acted as a coded assertion of opposition to the queen's marriage negotiations with the Duke of Alençon. Ultimately, Elizabeth would insist she was married to her kingdom and subjects, under divine protection. In 1599, she spoke of "all my husbands, my good people". This claim of virginity
1620-583: A result, the Parliament of 1559 started to legislate for a church based on the Protestant settlement of Edward VI , with the monarch as its head, but with many Catholic elements, such as vestments . The House of Commons backed the proposals strongly, but the bill of supremacy met opposition in the House of Lords , particularly from the bishops. Elizabeth was fortunate that many bishoprics were vacant at
1782-614: A reward for betrayal, references the bribe Judas Iscariot is said in the New Testament to have taken from Jewish leaders in Jerusalem to turn Jesus of Nazareth over to soldiers of the high priest Caiaphas. Ethically, silver also symbolizes greed and degradation of consciousness; this is the negative aspect, the perverting of its value. The abundance of silver in the Earth's crust is 0.08 parts per million , almost exactly
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#17327823090071944-629: A scale unparalleled before the discovery of the New World . Reaching a peak production of 200 tonnes per year, an estimated silver stock of 10,000 tonnes circulated in the Roman economy in the middle of the second century AD, five to ten times larger than the combined amount of silver available to medieval Europe and the Abbasid Caliphate around AD 800. The Romans also recorded the extraction of silver in central and northern Europe in
2106-458: A short-tempered, sometimes indecisive ruler, who enjoyed more than her fair share of luck. Towards the end of her reign, a series of economic and military problems weakened her popularity. Elizabeth is acknowledged as a charismatic performer ("Gloriana") and a dogged survivor ("Good Queen Bess") in an era when government was ramshackle and limited, and when monarchs in neighbouring countries faced internal problems that jeopardised their thrones. After
2268-481: A silver breastplate over a white velvet dress, she addressed them in her Speech to the Troops at Tilbury : My loving people, we have been persuaded by some that are careful of our safety, to take heed how we commit ourself to armed multitudes for fear of treachery; but I assure you, I do not desire to live to distrust my faithful and loving people ... I know I have the body but of a weak and feeble woman, but I have
2430-407: A single electron in the highest occupied s subshell over a filled d subshell, accounts for many of the singular properties of metallic silver. Silver is a relatively soft and extremely ductile and malleable transition metal , though it is slightly less malleable than gold. Silver crystallizes in a face-centered cubic lattice with bulk coordination number 12, where only the single 5s electron
2592-417: A sort broken our commandment in a cause that so greatly touches us in honour ... And therefore our express pleasure and commandment is that, all delays and excuses laid apart, you do presently upon the duty of your allegiance obey and fulfill whatsoever the bearer hereof shall direct you to do in our name. Whereof fail you not, as you will answer the contrary at your utmost peril. Elizabeth's "commandment"
2754-653: A sympathetic teacher who believed that learning should be engaging. Current knowledge of Elizabeth's schooling and precocity comes largely from Ascham's memoirs. By the time her formal education ended in 1550, Elizabeth was one of the best educated women of her generation. At the end of her life, she was believed to speak the Welsh , Cornish , Scottish , and Irish languages in addition to those mentioned above. The Venetian ambassador stated in 1603 that she "possessed [these] languages so thoroughly that each appeared to be her native tongue". Historian Mark Stoyle suggests that she
2916-528: A talented and skilful tutor, she also progressed in French and Greek. By the age of 12, she was able to translate her stepmother Catherine Parr 's religious work Prayers or Meditations from English into Italian, Latin, and French, which she presented to her father as a New Year's gift. From her teenage years and throughout her life, she translated works in Latin and Greek by numerous classical authors, including
3078-503: A thousand pieces". However, after Parr discovered the pair in an embrace, she ended this state of affairs. In May 1548, Elizabeth was sent away. Thomas Seymour nevertheless continued scheming to control the royal family and tried to have himself appointed the governor of the King's person. When Parr died after childbirth on 5 September 1548, he renewed his attentions towards Elizabeth, intent on marrying her. Her governess Kat Ashley , who
3240-567: Is cognate with Old High German silabar ; Gothic silubr ; or Old Norse silfr , all ultimately deriving from Proto-Germanic *silubra . The Balto-Slavic words for silver are rather similar to the Germanic ones (e.g. Russian серебро [ serebró ], Polish srebro , Lithuanian sidãbras ), as is the Celtiberian form silabur . They may have a common Indo-European origin, although their morphology rather suggest
3402-465: Is the difluoride , AgF 2 , which can be obtained from the elements under heat. A strong yet thermally stable and therefore safe fluorinating agent, silver(II) fluoride is often used to synthesize hydrofluorocarbons . In stark contrast to this, all four silver(I) halides are known. The fluoride , chloride , and bromide have the sodium chloride structure, but the iodide has three known stable forms at different temperatures; that at room temperature
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#17327823090073564-470: Is Ag 3 O which behaves as a metallic conductor. Silver(I) sulfide , Ag 2 S, is very readily formed from its constituent elements and is the cause of the black tarnish on some old silver objects. It may also be formed from the reaction of hydrogen sulfide with silver metal or aqueous Ag ions. Many non-stoichiometric selenides and tellurides are known; in particular, AgTe ~3 is a low-temperature superconductor . The only known dihalide of silver
3726-438: Is because its filled 4d shell is not very effective in shielding the electrostatic forces of attraction from the nucleus to the outermost 5s electron, and hence silver is near the bottom of the electrochemical series ( E (Ag /Ag) = +0.799 V). In group 11, silver has the lowest first ionization energy (showing the instability of the 5s orbital), but has higher second and third ionization energies than copper and gold (showing
3888-425: Is delocalized, similarly to copper and gold. Unlike metals with incomplete d-shells, metallic bonds in silver are lacking a covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of silver. Silver has a brilliant, white, metallic luster that can take a high polish , and which is so characteristic that the name of the metal itself has become
4050-537: Is guilty". Seymour was beheaded on 20 March 1549. Edward VI died on 6 July 1553, aged 15. His will ignored the Succession to the Crown Act 1543 , excluded both Mary and Elizabeth from the succession, and instead declared as his heir Lady Jane Grey, granddaughter of Henry VIII's younger sister Mary Tudor, Queen of France . Jane was proclaimed queen by the privy council , but her support quickly crumbled, and she
4212-549: Is higher than that of lead (1.87), and its electron affinity of 125.6 kJ/mol is much higher than that of hydrogen (72.8 kJ/mol) and not much less than that of oxygen (141.0 kJ/mol). Due to its full d-subshell, silver in its main +1 oxidation state exhibits relatively few properties of the transition metals proper from groups 4 to 10, forming rather unstable organometallic compounds , forming linear complexes showing very low coordination numbers like 2, and forming an amphoteric oxide as well as Zintl phases like
4374-413: Is much less stable, fuming in moist air and reacting with glass. Silver(II) complexes are more common. Like the valence isoelectronic copper(II) complexes, they are usually square planar and paramagnetic, which is increased by the greater field splitting for 4d electrons than for 3d electrons. Aqueous Ag , produced by oxidation of Ag by ozone, is a very strong oxidising agent, even in acidic solutions: it
4536-410: Is not reversible because the silver atom liberated is typically found at a crystal defect or an impurity site, so that the electron's energy is lowered enough that it is "trapped". White silver nitrate , AgNO 3 , is a versatile precursor to many other silver compounds, especially the halides, and is much less sensitive to light. It was once called lunar caustic because silver was called luna by
4698-424: Is pale yellow, becoming purplish on exposure to light; it projects slightly from the surface of the artifact or coin. The precipitation of copper in ancient silver can be used to date artifacts, as copper is nearly always a constituent of silver alloys. Silver metal is attacked by strong oxidizers such as potassium permanganate ( KMnO 4 ) and potassium dichromate ( K 2 Cr 2 O 7 ), and in
4860-415: Is rare in the periodic table. The atomic weight is 107.8682(2) u ; this value is very important because of the importance of silver compounds, particularly halides, in gravimetric analysis . Both isotopes of silver are produced in stars via the s-process (slow neutron capture), as well as in supernovas via the r-process (rapid neutron capture). Twenty-eight radioisotopes have been characterized,
5022-536: Is reflected in the relative decomposition temperatures of AgMe (−50 °C) and CuMe (−15 °C) as well as those of PhAg (74 °C) and PhCu (100 °C). The C–Ag bond is stabilized by perfluoroalkyl ligands, for example in AgCF(CF 3 ) 2 . Alkenylsilver compounds are also more stable than their alkylsilver counterparts. Silver- NHC complexes are easily prepared, and are commonly used to prepare other NHC complexes by displacing labile ligands. For example,
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5184-430: Is similar in its physical and chemical properties to its two vertical neighbours in group 11 of the periodic table : copper , and gold . Its 47 electrons are arranged in the configuration [Kr]4d 5s , similarly to copper ([Ar]3d 4s ) and gold ([Xe]4f 5d 6s ); group 11 is one of the few groups in the d-block which has a completely consistent set of electron configurations. This distinctive electron configuration, with
5346-472: Is stabilized in phosphoric acid due to complex formation. Peroxodisulfate oxidation is generally necessary to give the more stable complexes with heterocyclic amines , such as [Ag(py) 4 ] and [Ag(bipy) 2 ] : these are stable provided the counterion cannot reduce the silver back to the +1 oxidation state. [AgF 4 ] is also known in its violet barium salt, as are some silver(II) complexes with N - or O -donor ligands such as pyridine carboxylates. By far
5508-413: Is the cubic zinc blende structure. They can all be obtained by the direct reaction of their respective elements. As the halogen group is descended, the silver halide gains more and more covalent character, solubility decreases, and the colour changes from the white chloride to the yellow iodide as the energy required for ligand-metal charge transfer (X Ag → XAg) decreases. The fluoride is anomalous, as
5670-401: Is used for light work, such as sewing canvas together and roping palm which is built for heavier work, such as sewing canvas and rope together. This item consists of a pitted hard plate set into a stiff leather band that is worn around the palm of the hand, with the plate resting against the first joint of the thumb . It is used by grasping a needle between the thumb and indexing finger, with
5832-614: Is used in solar panels , water filtration , jewellery , ornaments, high-value tableware and utensils (hence the term " silverware "), in electrical contacts and conductors , in specialized mirrors, window coatings, in catalysis of chemical reactions, as a colorant in stained glass , and in specialized confectionery. Its compounds are used in photographic and X-ray film. Dilute solutions of silver nitrate and other silver compounds are used as disinfectants and microbiocides ( oligodynamic effect ), added to bandages , wound-dressings, catheters , and other medical instruments . Silver
5994-726: Is used in vacuum brazing . The two metals are completely miscible as liquids but not as solids; their importance in industry comes from the fact that their properties tend to be suitable over a wide range of variation in silver and copper concentration, although most useful alloys tend to be richer in silver than the eutectic mixture (71.9% silver and 28.1% copper by weight, and 60.1% silver and 28.1% copper by atom). Most other binary alloys are of little use: for example, silver–gold alloys are too soft and silver– cadmium alloys too toxic. Ternary alloys have much greater importance: dental amalgams are usually silver–tin–mercury alloys, silver–copper–gold alloys are very important in jewellery (usually on
6156-482: Is usually obtained by reacting silver or silver monofluoride with the strongest known oxidizing agent, krypton difluoride . Silver and gold have rather low chemical affinities for oxygen, lower than copper, and it is therefore expected that silver oxides are thermally quite unstable. Soluble silver(I) salts precipitate dark-brown silver(I) oxide , Ag 2 O, upon the addition of alkali. (The hydroxide AgOH exists only in solution; otherwise it spontaneously decomposes to
6318-660: The Pro Marcello of Cicero , the De consolatione philosophiae of Boethius , a treatise by Plutarch , and the Annals of Tacitus . A translation of Tacitus from Lambeth Palace Library, one of only four surviving English translations from the early modern era, was confirmed as Elizabeth's own in 2019, after a detailed analysis of the handwriting and paper was undertaken. After Grindal died in 1548, Elizabeth received her education under her brother Edward's tutor, Roger Ascham ,
6480-480: The British government and melted down to buy hospital equipment. In the 1930s and 1940s glass-topped thimbles were used for advertising . Leaving a sandalwood thimble in a fabric store was a common practice for keeping moths away. Thimbles have also been used as love-tokens and to commemorate important events. People who collect thimbles are known as digitabulists . One superstition about thimbles says that if
6642-643: The Dorcas , and these are now popular with collectors. There is a small display of his work in Bankfield Museum , Halifax , England . Early American thimbles made of whale bone or tooth featuring miniature scrimshaw designs are considered valuable collectibles. Such rare thimbles are prominently featured in a number of New England Whaling Museums. During the First World War , silver thimbles were collected from "those who had nothing to give" by
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6804-848: The Koenigs–Knorr reaction . In the Fétizon oxidation , silver carbonate on celite acts as an oxidising agent to form lactones from diols . It is also employed to convert alkyl bromides into alcohols . Silver fulminate , AgCNO, a powerful, touch-sensitive explosive used in percussion caps , is made by reaction of silver metal with nitric acid in the presence of ethanol . Other dangerously explosive silver compounds are silver azide , AgN 3 , formed by reaction of silver nitrate with sodium azide , and silver acetylide , Ag 2 C 2 , formed when silver reacts with acetylene gas in ammonia solution. In its most characteristic reaction, silver azide decomposes explosively, releasing nitrogen gas: given
6966-545: The Lahn region, Siegerland , Silesia , Hungary , Norway , Steiermark , Schwaz , and the southern Black Forest . Most of these ores were quite rich in silver and could simply be separated by hand from the remaining rock and then smelted; some deposits of native silver were also encountered. Many of these mines were soon exhausted, but a few of them remained active until the Industrial Revolution , before which
7128-749: The Spanish ships to the northeast. The Armada straggled home to Spain in shattered remnants, after disastrous losses on the coast of Ireland (after some ships had tried to struggle back to Spain via the North Sea , and then back south past the west coast of Ireland). Unaware of the Armada's fate, English militias mustered to defend the country under the Earl of Leicester's command. Leicester invited Elizabeth to inspect her troops at Tilbury in Essex on 8 August. Wearing
7290-680: The Spanish Netherlands . In December 1584, an alliance between Philip II and the French Catholic League at Joinville undermined the ability of Anjou's brother, Henry III of France , to counter Spanish domination of the Netherlands. It also extended Spanish influence along the channel coast of France, where the Catholic League was strong, and exposed England to invasion. The siege of Antwerp in
7452-470: The Tower of London . Elizabeth fervently protested her innocence. Though it is unlikely that she had plotted with the rebels, some of them were known to have approached her. Mary's closest confidant, Emperor Charles's ambassador Simon Renard , argued that her throne would never be safe while Elizabeth lived; and Lord Chancellor Stephen Gardiner , worked to have Elizabeth put on trial. Elizabeth's supporters in
7614-482: The crucifix ), and downplayed the role of sermons in defiance of a key Protestant belief. Elizabeth and her advisers perceived the threat of a Catholic crusade against heretical England. The Queen therefore sought a Protestant solution that would not offend Catholics too greatly while addressing the desires of English Protestants, but she would not tolerate the Puritans , who were pushing for far-reaching reforms. As
7776-666: The mythical realm of fairies . Silver production has also inspired figurative language. Clear references to cupellation occur throughout the Old Testament of the Bible , such as in Jeremiah 's rebuke to Judah: "The bellows are burned, the lead is consumed of the fire; the founder melteth in vain: for the wicked are not plucked away. Reprobate silver shall men call them, because the Lord hath rejected them." (Jeremiah 6:19–20) Jeremiah
7938-435: The platinum complexes (though they are formed more readily than those of the analogous gold complexes): they are also quite unsymmetrical, showing the weak π bonding in group 11. Ag–C σ bonds may also be formed by silver(I), like copper(I) and gold(I), but the simple alkyls and aryls of silver(I) are even less stable than those of copper(I) (which tend to explode under ambient conditions). For example, poor thermal stability
8100-526: The post-transition metals . Unlike the preceding transition metals, the +1 oxidation state of silver is stable even in the absence of π-acceptor ligands . Silver does not react with air, even at red heat, and thus was considered by alchemists as a noble metal , along with gold. Its reactivity is intermediate between that of copper (which forms copper(I) oxide when heated in air to red heat) and gold. Like copper, silver reacts with sulfur and its compounds; in their presence, silver tarnishes in air to form
8262-719: The succession question became a heated issue in Parliament. Members urged the Queen to marry or nominate an heir, to prevent a civil war upon her death. She refused to do either. In April she prorogued the Parliament, which did not reconvene until she needed its support to raise taxes in 1566. Having previously promised to marry, she told an unruly House: I will never break the word of a prince spoken in public place, for my honour's sake. And therefore I say again, I will marry as soon as I can conveniently, if God take not him away with whom I mind to marry, or myself, or else some other great let [obstruction] happen. By 1570, senior figures in
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#17327823090078424-426: The 14th century. Although there are isolated examples of thimbles made of precious metals— Elizabeth I is said to have given one of her ladies-in-waiting a thimble set with precious stones—the vast majority of metal thimbles were made of brass . Medieval thimbles were either cast brass or made from hammered sheet. Early centers of thimble production were those places known for brass-working, starting with Nuremberg in
8586-513: The 15th century, and moving to Holland by the 17th. In 1693, a Dutch thimble manufacturer named John Lofting established a thimble manufactory in Islington, in London, England, expanding British thimble production to new heights. He later moved his mill to Buckinghamshire to take advantage of water-powered production, resulting in a capacity to produce more than two million thimbles per year. By
8748-731: The 19th century, primary production of silver moved to North America, particularly Canada , Mexico , and Nevada in the United States : some secondary production from lead and zinc ores also took place in Europe, and deposits in Siberia and the Russian Far East as well as in Australia were mined. Poland emerged as an important producer during the 1970s after the discovery of copper deposits that were rich in silver, before
8910-474: The Babington Plot. Elizabeth's proclamation of the sentence announced that "the said Mary, pretending title to the same Crown, had compassed and imagined within the same realm diverse things tending to the hurt, death and destruction of our royal person." On 8 February 1587, Mary was beheaded at Fotheringhay Castle , Northamptonshire. After the execution, Elizabeth claimed that she had not intended for
9072-573: The Catholic enemies of England, they detained her in England, where she was imprisoned for the next nineteen years. Mary was soon the focus for rebellion. In 1569 there was a major Catholic rising in the North ; the goal was to free Mary, marry her to Thomas Howard, Duke of Norfolk , and put her on the English throne. After the rebels' defeat, over 750 of them were executed on Elizabeth's orders. In
9234-635: The Catholics to retake the port. Elizabeth's intention had been to exchange Le Havre for Calais , lost to France in January 1558. Only through the activities of her fleets did Elizabeth pursue an aggressive policy. This paid off in the war against Spain , 80% of which was fought at sea. She knighted Francis Drake after his circumnavigation of the globe from 1577 to 1580, and he won fame for his raids on Spanish ports and fleets. An element of piracy and self-enrichment drove Elizabethan seafarers, over whom
9396-553: The English throne, but from the Ridolfi Plot of 1571 (which caused Mary's suitor, the Duke of Norfolk, to lose his head) to the Babington Plot of 1586, Elizabeth's spymaster Francis Walsingham and the royal council keenly assembled a case against her. At first, Elizabeth resisted calls for Mary's death. By late 1586, she had been persuaded to sanction Mary's trial and execution on the evidence of letters written during
9558-535: The English throne. The marriage was the first of a series of errors of judgement by Mary that handed the victory to the Scottish Protestants and to Elizabeth. Darnley quickly became unpopular and was murdered in February 1567 by conspirators almost certainly led by James Hepburn, Earl of Bothwell . Shortly afterwards, on 15 May 1567, Mary married Bothwell, arousing suspicions that she had been party to
9720-576: The Greek and Roman civilizations, silver coins were a staple of the economy: the Greeks were already extracting silver from galena by the 7th century BC, and the rise of Athens was partly made possible by the nearby silver mines at Laurium , from which they extracted about 30 tonnes a year from 600 to 300 BC. The stability of the Roman currency relied to a high degree on the supply of silver bullion, mostly from Spain, which Roman miners produced on
9882-587: The Queen had little control. After the occupation and loss of Le Havre in 1562–1563, Elizabeth avoided military expeditions on the continent until 1585, when she sent an English army to aid the Protestant Dutch rebels against Philip II. This followed the deaths in 1584 of the Queen's allies William the Silent , Prince of Orange, and the Duke of Anjou, and the surrender of a series of Dutch towns to Alexander Farnese, Duke of Parma , Philip's governor of
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#173278230900710044-710: The Spanish fleet of war ships intended for the Enterprise of England , as Philip II had decided to take the war to England. On 12 July 1588, the Spanish Armada, a great fleet of ships, set sail for the channel, planning to ferry a Spanish invasion force under the Duke of Parma to the coast of southeast England from the Netherlands. The armada was defeated by a combination of miscalculation, misfortune, and an attack of English fire ships off Gravelines at midnight on 28–29 July (7–8 August New Style), which dispersed
10206-754: The UK when many companies made special thimbles to commemorate the Great Exhibition held in the Crystal Palace in Hyde Park , London . In the 19th century, many thimbles were made from silver ; however, it was found that silver is too soft a metal and can be easily punctured by most needles. Charles Horner solved the problem by creating thimbles consisting of a steel core covered inside and out by silver, so that they retained their aesthetics but were now more practical and durable. He called his thimble
10368-449: The US, 13540 tons of silver were used for the electromagnets in calutrons for enriching uranium , mainly because of the wartime shortage of copper. Silver readily forms alloys with copper, gold, and zinc . Zinc-silver alloys with low zinc concentration may be considered as face-centred cubic solid solutions of zinc in silver, as the structure of the silver is largely unchanged while
10530-557: The ancient alchemists, who believed that silver was associated with the Moon. It is often used for gravimetric analysis, exploiting the insolubility of the heavier silver halides which it is a common precursor to. Silver nitrate is used in many ways in organic synthesis , e.g. for deprotection and oxidations. Ag binds alkenes reversibly, and silver nitrate has been used to separate mixtures of alkenes by selective absorption. The resulting adduct can be decomposed with ammonia to release
10692-470: The apex or along the outer rim. Rarer works from thimble makers utilized diamonds , sapphires , or rubies . Cabochon adornments are sometimes made of cinnabar , agate , moonstone , or amber . Thimble artists would also utilize enameling, or the Guilloché techniques advanced by Peter Carl Fabergé . Originally, thimbles were used simply solely for pushing a needle through fabric or leather as it
10854-540: The autumn of 1559, several foreign suitors were vying for Elizabeth's hand; their impatient envoys engaged in ever more scandalous talk and reported that a marriage with her favourite was not welcome in England: "There is not a man who does not cry out on him and her with indignation ... she will marry none but the favoured Robert." Amy Dudley died in September 1560, from a fall from a flight of stairs and, despite
11016-690: The belief that the revolt had been successful, Pope Pius V issued a bull in 1570, titled Regnans in Excelsis , which declared "Elizabeth, the pretended Queen of England and the servant of crime" to be excommunicated and a heretic , releasing all her subjects from any allegiance to her. Catholics who obeyed her orders were threatened with excommunication . The papal bull provoked legislative initiatives against Catholics by Parliament, which were, however, mitigated by Elizabeth's intervention. In 1581, to convert English subjects to Catholicism with "the intent" to withdraw them from their allegiance to Elizabeth
11178-637: The black silver sulfide (copper forms the green sulfate instead, while gold does not react). While silver is not attacked by non-oxidizing acids, the metal dissolves readily in hot concentrated sulfuric acid , as well as dilute or concentrated nitric acid . In the presence of air, and especially in the presence of hydrogen peroxide , silver dissolves readily in aqueous solutions of cyanide . The three main forms of deterioration in historical silver artifacts are tarnishing, formation of silver chloride due to long-term immersion in salt water, as well as reaction with nitrate ions or oxygen. Fresh silver chloride
11340-530: The cause, Leicester's own shortcomings as a political and military leader, and the faction-ridden and chaotic situation of Dutch politics led to the failure of the campaign. Leicester finally resigned his command in December 1587. Meanwhile, Francis Drake had undertaken a major voyage against Spanish ports and ships in the Caribbean in 1585 and 1586. In 1587 he made a successful raid on Cádiz , destroying
11502-522: The centre of [Elizabeth's] emotional life", as historian Susan Doran has described the situation. He died shortly after the defeat of the Spanish Armada in 1588. After Elizabeth's own death, a note from him was found among her most personal belongings, marked "his last letter" in her handwriting. Marriage negotiations constituted a key element in Elizabeth's foreign policy. She turned down
11664-712: The centre of production returned to the Americas the following decade. Today, Peru and Mexico are still among the primary silver producers, but the distribution of silver production around the world is quite balanced and about one-fifth of the silver supply comes from recycling instead of new production. Silver plays a certain role in mythology and has found various usage as a metaphor and in folklore. The Greek poet Hesiod 's Works and Days (lines 109–201) lists different ages of man named after metals like gold, silver, bronze and iron to account for successive ages of humanity. Ovid 's Metamorphoses contains another retelling of
11826-487: The citizens and greeted by orations and pageants, most with a strong Protestant flavour. Elizabeth's open and gracious responses endeared her to the spectators, who were "wonderfully ravished". The following day, 15 January 1559, a date chosen by her astrologer John Dee , Elizabeth was crowned and anointed by Owen Oglethorpe , the Catholic bishop of Carlisle , in Westminster Abbey . She was then presented for
11988-467: The coroner's inquest finding of accident, many people suspected her husband of having arranged her death so that he could marry the Queen. Elizabeth seriously considered marrying Dudley for some time. However, William Cecil , Nicholas Throckmorton , and some conservative peers made their disapproval unmistakably clear. There were even rumours that the nobility would rise if the marriage took place. Among other marriage candidates being considered for
12150-530: The crown to a Protestant cousin, Lady Jane Grey , and ignoring the claims of his two half-sisters, the Catholic Mary and the younger Elizabeth, in spite of statutes to the contrary. Edward's will was set aside within weeks of his death and Mary became queen, deposing and executing Jane. During Mary's reign, Elizabeth was imprisoned for nearly a year on suspicion of supporting Protestant rebels. Upon her half-sister's death in 1558, Elizabeth succeeded to
12312-434: The dominant producers of silver until around the beginning of the 18th century, particularly Peru , Bolivia , Chile , and Argentina : the last of these countries later took its name from that of the metal that composed so much of its mineral wealth. The silver trade gave way to a global network of exchange . As one historian put it, silver "went round the world and made the world go round." Much of this silver ended up in
12474-408: The electron concentration rises as more zinc is added. Increasing the electron concentration further leads to body-centred cubic (electron concentration 1.5), complex cubic (1.615), and hexagonal close-packed phases (1.75). Naturally occurring silver is composed of two stable isotopes , Ag and Ag, with Ag being slightly more abundant (51.839% natural abundance ). This almost equal abundance
12636-411: The elements in groups 10–14 (except boron and carbon ) have very complex Ag–M phase diagrams and form the most commercially important alloys; and the remaining elements on the periodic table have no consistency in their Ag–M phase diagrams. By far the most important such alloys are those with copper: most silver used for coinage and jewellery is in reality a silver–copper alloy, and the eutectic mixture
12798-712: The end of the 18th century, thimble making had moved to Birmingham, and shifted to the "deep drawing" method of manufacture, which alternated hammering of sheet metals with annealing, and produced a thinner-skinned thimble with a taller shape. At the same time, cheaper sources of silver from the Americas made silver thimbles a popular item for the first time. Thimbles are usually made from metal , leather , rubber , wood , and even glass or china . Early thimbles were sometimes made from whale bone , horn , or ivory . Natural sources were also utilized such as Connemara marble , bog oak or mother of pearl .. Advanced thimblemakers enhanced thimbles with semi-precious stones to adorn
12960-545: The enemy". He enraged Elizabeth by accepting the post of Governor-General from the Dutch States General . Elizabeth saw this as a Dutch ploy to force her to accept sovereignty over the Netherlands, which so far she had always declined. She wrote to Leicester: We could never have imagined (had we not seen it fall out in experience) that a man raised up by ourself and extraordinarily favoured by us, above any other subject of this land, would have in so contemptible
13122-529: The exceptions are the nitrate, perchlorate, and fluoride. The tetracoordinate tetrahedral aqueous ion [Ag(H 2 O) 4 ] is known, but the characteristic geometry for the Ag cation is 2-coordinate linear. For example, silver chloride dissolves readily in excess aqueous ammonia to form [Ag(NH 3 ) 2 ] ; silver salts are dissolved in photography due to the formation of the thiosulfate complex [Ag(S 2 O 3 ) 2 ] ; and cyanide extraction for silver (and gold) works by
13284-467: The eye end of the needle against the pitted plate, and pushing the needle with the entire arm. Most palms are hand specific to give the user a better fit. This design permits the sewer to exert a great amount of force when pushing thick needles through very tough materials such as sail cloth, canvas or leather. In the Parker Brothers board game Monopoly , first created in 1904, the thimble
13446-422: The filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The thermal conductivity of silver is among the highest of all materials, although the thermal conductivity of carbon (in the diamond allotrope ) and superfluid helium-4 are higher. The electrical conductivity of silver is the highest of all metals, greater even than copper. Silver also has
13608-424: The final stages of Mary's apparent pregnancy . If Mary and her child died, Elizabeth would become queen, but if Mary gave birth to a healthy child, Elizabeth's chances of becoming queen would recede sharply. When it became clear that Mary was not pregnant, no one believed any longer that she could have a child. Elizabeth's succession seemed assured. King Philip, who ascended the Spanish throne in 1556, acknowledged
13770-534: The fluoride ion is so small that it has a considerable solvation energy and hence is highly water-soluble and forms di- and tetrahydrates. The other three silver halides are highly insoluble in aqueous solutions and are very commonly used in gravimetric analytical methods. All four are photosensitive (though the monofluoride is so only to ultraviolet light), especially the bromide and iodide which photodecompose to silver metal, and thus were used in traditional photography . The reaction involved is: The process
13932-547: The focus of plots against her predecessor. Elizabeth's unmarried status inspired a cult of virginity related to that of the Virgin Mary . In poetry and portraiture, she was depicted as a virgin, a goddess, or both, not as a normal woman. At first, only Elizabeth made a virtue of her ostensible virginity: in 1559, she told the Commons, "And, in the end, this shall be for me sufficient, that a marble stone shall declare that
14094-523: The formation of the complex [Ag(CN) 2 ] . Silver cyanide forms the linear polymer {Ag–C≡N→Ag–C≡N→}; silver thiocyanate has a similar structure, but forms a zigzag instead because of the sp - hybridized sulfur atom. Chelating ligands are unable to form linear complexes and thus silver(I) complexes with them tend to form polymers; a few exceptions exist, such as the near-tetrahedral diphosphine and diarsine complexes [Ag(L–L) 2 ] . Under standard conditions, silver does not form simple carbonyls, due to
14256-412: The free alkene. Yellow silver carbonate , Ag 2 CO 3 can be easily prepared by reacting aqueous solutions of sodium carbonate with a deficiency of silver nitrate. Its principal use is for the production of silver powder for use in microelectronics. It is reduced with formaldehyde , producing silver free of alkali metals: Silver carbonate is also used as a reagent in organic synthesis such as
14418-573: The gold-rich side) and have a vast range of hardnesses and colours, silver–copper–zinc alloys are useful as low-melting brazing alloys, and silver–cadmium– indium (involving three adjacent elements on the periodic table) is useful in nuclear reactors because of its high thermal neutron capture cross-section , good conduction of heat, mechanical stability, and resistance to corrosion in hot water. The word silver appears in Old English in various spellings, such as seolfor and siolfor . It
14580-455: The government privately accepted that Elizabeth would never marry or name a successor. William Cecil was already seeking solutions to the succession problem. For her failure to marry, Elizabeth was often accused of irresponsibility. Her silence, however, strengthened her own political security: she knew that if she named an heir, her throne would be vulnerable to a coup; she remembered the way that "a second person, as I have been" had been used as
14742-464: The government, including William Paget, 1st Baron Paget , convinced Mary to spare her sister in the absence of hard evidence against her. Instead, on 22 May, Elizabeth was moved from the Tower to Woodstock Palace , where she was to spend almost a year under house arrest in the charge of Henry Bedingfeld . Crowds cheered her all along the way. On 17 April 1555, Elizabeth was recalled to court to attend
14904-496: The hand of Philip, her half-sister's widower, early in 1559 but for several years entertained the proposal of King Eric XIV of Sweden . Earlier in Elizabeth's life, a Danish match for her had been discussed; Henry VIII had proposed one with the Danish prince Adolf, Duke of Holstein-Gottorp , in 1545, and Edward Seymour, Duke of Somerset, suggested a marriage with Prince Frederick (later Frederick II) several years later, but
15066-447: The hands of King Philip II of Spain, marriage offered the chance of an heir. However, the choice of a husband might also provoke political instability or even insurrection. In the spring of 1559, it became evident that Elizabeth was in love with her childhood friend Robert Dudley . It was said that his wife Amy was suffering from a "malady in one of her breasts" and that the Queen would like to marry Robert if his wife should die. By
15228-459: The hands of the Chinese. A Portuguese merchant in 1621 noted that silver "wanders throughout all the world... before flocking to China, where it remains as if at its natural center." Still, much of it went to Spain, allowing Spanish rulers to pursue military and political ambitions in both Europe and the Americas. "New World mines", concluded several historians, "supported the Spanish empire." In
15390-454: The heart and stomach of a king, and of a King of England too, and think foul scorn that Parma or Spain, or any Prince of Europe should dare to invade the borders of my realm. Silver Silver is a chemical element ; it has symbol Ag (from Latin argentum 'silver', derived from Proto-Indo-European *h₂erǵ ' shiny, white ' ) and atomic number 47. A soft, white, lustrous transition metal , it exhibits
15552-412: The highest electrical conductivity , thermal conductivity , and reflectivity of any metal . Silver is found in the Earth's crust in the pure, free elemental form (" native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite . Most silver is produced as a byproduct of copper , gold, lead , and zinc refining . Silver has long been valued as
15714-407: The lowest contact resistance of any metal. Silver is rarely used for its electrical conductivity, due to its high cost, although an exception is in radio-frequency engineering , particularly at VHF and higher frequencies where silver plating improves electrical conductivity because those currents tend to flow on the surface of conductors rather than through the interior. During World War II in
15876-618: The metal. The situation changed with the discovery of cupellation , a technique that allowed silver metal to be extracted from its ores. While slag heaps found in Asia Minor and on the islands of the Aegean Sea indicate that silver was being separated from lead as early as the 4th millennium BC , and one of the earliest silver extraction centres in Europe was Sardinia in the early Chalcolithic period , these techniques did not spread widely until later, when it spread throughout
16038-446: The middle of that century, a machine was invented to do the job. A thimble with an irregular pattern of dimples was likely made before the 1850s. Another consequence of the mechanization of thimble production is that the shape and the thickness of the metal changed. Early thimbles tend to be quite thick and to have a pronounced dome on the top. The metal on later ones is thinner and the top is flatter. Collecting thimbles became popular in
16200-461: The monarch as the supreme governor or risk disqualification from office; the heresy laws were repealed, to avoid a repeat of the persecution of dissenters by Mary. At the same time, a new Act of Uniformity was passed, which made attendance at church and the use of the 1559 Book of Common Prayer (an adapted version of the 1552 prayer book ) compulsory, though the penalties for recusancy , or failure to attend and conform, were not extreme. From
16362-434: The most important oxidation state for silver in complexes is +1. The Ag cation is diamagnetic, like its homologues Cu and Au , as all three have closed-shell electron configurations with no unpaired electrons: its complexes are colourless provided the ligands are not too easily polarized such as I . Ag forms salts with most anions, but it is reluctant to coordinate to oxygen and thus most of these salts are insoluble in water:
16524-546: The most stable being Ag with a half-life of 41.29 days, Ag with a half-life of 7.45 days, and Ag with a half-life of 3.13 hours. Silver has numerous nuclear isomers , the most stable being Ag ( t 1/2 = 418 years), Ag ( t 1/2 = 249.79 days) and Ag ( t 1/2 = 8.28 days). All of the remaining radioactive isotopes have half-lives of less than an hour, and the majority of these have half-lives of less than three minutes. Isotopes of silver range in relative atomic mass from 92.950 u ( Ag) to 129.950 u ( Ag);
16686-623: The murder of her husband. Elizabeth confronted Mary about the marriage, writing to her: How could a worse choice be made for your honour than in such haste to marry such a subject, who besides other and notorious lacks, public fame has charged with the murder of your late husband, besides the touching of yourself also in some part, though we trust in that behalf falsely. These events led rapidly to Mary's defeat and imprisonment in Lochleven Castle . The Scottish lords forced her to abdicate in favour of her one-year-old son, James VI . James
16848-693: The negotiations had abated in 1551. In the years around 1559, a Dano-English Protestant alliance was considered, and to counter Sweden's proposal, King Frederick II proposed to Elizabeth in late 1559. For several years, she seriously negotiated to marry Philip's cousin Charles II, Archduke of Austria . By 1569, relations with the Habsburgs had deteriorated. Elizabeth considered marriage to two French Valois princes in turn, first Henry, Duke of Anjou , and then from 1572 to 1581 his brother Francis, Duke of Anjou , formerly Duke of Alençon. This last proposal
17010-589: The new political reality and cultivated his sister-in-law. She was a better ally than the chief alternative, Mary, Queen of Scots , who had grown up in France and was betrothed to Francis, Dauphin of France . When his wife fell ill in 1558, Philip sent the Count of Feria to consult with Elizabeth. This interview was conducted at Hatfield House , where she had returned to live in October 1555. By October 1558, Elizabeth
17172-588: The only objects with a high-enough palladium-to-silver ratio to yield measurable variations in Ag abundance. Radiogenic Ag was first discovered in the Santa Clara meteorite in 1978. Pd– Ag correlations observed in bodies that have clearly been melted since the accretion of the Solar System must reflect the presence of unstable nuclides in the early Solar System. Silver is a rather unreactive metal. This
17334-625: The ores of copper, copper-nickel, lead, and lead-zinc obtained from Peru , Bolivia , Mexico , China , Australia , Chile , Poland and Serbia . Peru, Bolivia and Mexico have been mining silver since 1546, and are still major world producers. Top silver-producing mines are Cannington (Australia), Fresnillo (Mexico), San Cristóbal (Bolivia), Antamina (Peru), Rudna (Poland), and Penasquito (Mexico). Top near-term mine development projects through 2015 are Pascua Lama (Chile), Navidad (Argentina), Jaunicipio (Mexico), Malku Khota (Bolivia), and Hackett River (Canada). In Central Asia , Tajikistan
17496-423: The oxide.) Silver(I) oxide is very easily reduced to metallic silver, and decomposes to silver and oxygen above 160 °C. This and other silver(I) compounds may be oxidized by the strong oxidizing agent peroxodisulfate to black AgO, a mixed silver(I,III) oxide of formula Ag Ag O 2 . Some other mixed oxides with silver in non-integral oxidation states, namely Ag 2 O 3 and Ag 3 O 4 , are also known, as
17658-436: The people's acceptance, amidst a deafening noise of organs, fifes, trumpets, drums, and bells. Although Elizabeth was welcomed as queen in England, the country was still in a state of anxiety over the perceived Catholic threat at home and overseas, as well as the choice of whom she would marry. Elizabeth's personal religious convictions have been much debated by scholars. She was a Protestant, but kept Catholic symbols (such as
17820-577: The photosensitivity of silver salts, this behaviour may be induced by shining a light on its crystals. Silver complexes tend to be similar to those of its lighter homologue copper. Silver(III) complexes tend to be rare and very easily reduced to the more stable lower oxidation states, though they are slightly more stable than those of copper(III). For instance, the square planar periodate [Ag(IO 5 OH) 2 ] and tellurate [Ag{TeO 4 (OH) 2 } 2 ] complexes may be prepared by oxidising silver(I) with alkaline peroxodisulfate . The yellow diamagnetic [AgF 4 ]
17982-402: The phrase "just a thimbleful". Prostitutes used them in the practice of thimble-knocking where they would tap on a window to announce their presence. Thimble-knocking also refers to the practice of Victorian schoolmistresses who would tap on the heads of unruly pupils with dames thimbles. Before the 18th century, the small dimples on the outside of a thimble were made by hand punching, but in
18144-961: The presence of potassium bromide ( KBr ). These compounds are used in photography to bleach silver images, converting them to silver bromide that can either be fixed with thiosulfate or redeveloped to intensify the original image. Silver forms cyanide complexes ( silver cyanide ) that are soluble in water in the presence of an excess of cyanide ions. Silver cyanide solutions are used in electroplating of silver. The common oxidation states of silver are (in order of commonness): +1 (the most stable state; for example, silver nitrate , AgNO 3 ); +2 (highly oxidising; for example, silver(II) fluoride , AgF 2 ); and even very rarely +3 (extreme oxidising; for example, potassium tetrafluoroargentate(III), KAgF 4 ). The +3 state requires very strong oxidising agents to attain, such as fluorine or peroxodisulfate , and some silver(III) compounds react with atmospheric moisture and attack glass. Indeed, silver(III) fluoride
18306-406: The primary decay mode before the most abundant stable isotope, Ag, is electron capture and the primary mode after is beta decay . The primary decay products before Ag are palladium (element 46) isotopes, and the primary products after are cadmium (element 48) isotopes. The palladium isotope Pd decays by beta emission to Ag with a half-life of 6.5 million years. Iron meteorites are
18468-435: The queen, Robert Dudley continued to be regarded as a possible candidate for nearly another decade. Elizabeth was extremely jealous of his affections, even when she no longer meant to marry him herself. She raised Dudley to the peerage as Earl of Leicester in 1564. In 1578, he finally married Lettice Knollys , to whom the queen reacted with repeated scenes of displeasure and lifelong hatred. Still, Dudley always "remained at
18630-419: The reaction of the bis(NHC)silver(I) complex with bis(acetonitrile)palladium dichloride or chlorido(dimethyl sulfide)gold(I) : Silver forms alloys with most other elements on the periodic table. The elements from groups 1–3, except for hydrogen , lithium , and beryllium , are very miscible with silver in the condensed phase and form intermetallic compounds; those from groups 4–9 are only poorly miscible;
18792-512: The region and beyond. The origins of silver production in India , China , and Japan were almost certainly equally ancient, but are not well-documented due to their great age. When the Phoenicians first came to what is now Spain , they obtained so much silver that they could not fit it all on their ships, and as a result used silver to weight their anchors instead of lead. By the time of
18954-424: The reins of power, the country had an established Protestant church and was run by a council of Protestant nobles supported by Elizabeth. Mary refused to ratify the treaty. In 1563, Elizabeth proposed her own suitor, Robert Dudley, as a husband for Mary, without asking either of the two people concerned. Both proved unenthusiastic, and in 1565, Mary married Henry Stuart, Lord Darnley , who carried his own claim to
19116-477: The rest of her life. Thomas Seymour engaged in romps and horseplay with the 14-year-old Elizabeth, including entering her bedroom in his nightgown, tickling her, and slapping her on the buttocks. Elizabeth rose early and surrounded herself with maids to avoid his unwelcome morning visits. Parr, rather than confront her husband over his inappropriate activities, joined in. Twice she accompanied him in tickling Elizabeth, and once held her while he cut her black gown "into
19278-414: The royal succession. Eleven days after Anne Boleyn's execution, Henry married Jane Seymour . Queen Jane died the next year shortly after the birth of their son, Edward , who was the undisputed heir apparent to the throne. Elizabeth was placed in her half-brother's household and carried the chrisom , or baptismal cloth, at his christening. Elizabeth's first governess , Margaret Bryan , wrote that she
19440-701: The same as that of mercury . It mostly occurs in sulfide ores, especially acanthite and argentite , Ag 2 S. Argentite deposits sometimes also contain native silver when they occur in reducing environments, and when in contact with salt water they are converted to chlorargyrite (including horn silver ), AgCl, which is prevalent in Chile and New South Wales . Most other silver minerals are silver pnictides or chalcogenides ; they are generally lustrous semiconductors. Most true silver deposits, as opposed to argentiferous deposits of other metals, came from Tertiary period vulcanism. The principal sources of silver are
19602-693: The same time period. This production came to a nearly complete halt with the fall of the Roman Empire, not to resume until the time of Charlemagne : by then, tens of thousands of tonnes of silver had already been extracted. Central Europe became the centre of silver production during the Middle Ages , as the Mediterranean deposits exploited by the ancient civilisations had been exhausted. Silver mines were opened in Bohemia , Saxony , Alsace ,
19764-421: The short, disastrous reigns of her half-siblings, her 44 years on the throne provided welcome stability for the kingdom and helped to forge a sense of national identity. Elizabeth was born at Greenwich Palace on 7 September 1533 and was named after her grandmothers, Elizabeth of York and Lady Elizabeth Howard . She was the second child of Henry VIII of England born in wedlock to survive infancy. Her mother
19926-568: The signed execution warrant to be dispatched, and blamed her secretary, William Davison , for implementing it without her knowledge. The sincerity of Elizabeth's remorse and whether or not she wanted to delay the warrant have been called into question both by her contemporaries and later historians. Elizabeth's foreign policy was largely defensive. The exception was the English occupation of Le Havre from October 1562 to June 1563, which ended in failure when Elizabeth's Huguenot allies joined with
20088-511: The softer thimblettes become worn over time. They are considered disposable and sold in boxes. The surface is dimpled with the dimples inverted to provide better grip. Thimblettes are sized from 00 through to 3. A finger cot is a smooth rubber "glove finger" used to protect the finger or the item being handled. A variation on the thimble used by sailmakers and leather workers is the sail palm , also known as sailor's palm and sailmaker's palm . There are two variations, seaming palm which
20250-399: The son of Holy Roman Emperor Charles V and an active Catholic. Discontent spread rapidly through the country, and many looked to Elizabeth as a focus for their opposition to Mary's religious policies. In January and February 1554, Wyatt's rebellion broke out; it was soon suppressed. Elizabeth was brought to court and interrogated regarding her role, and on 18 March, she was imprisoned in
20412-509: The sovereign's "two bodies": the body natural and the body politic : My lords, the law of nature moves me to sorrow for my sister; the burden that is fallen upon me makes me amazed, and yet, considering I am God's creature, ordained to obey His appointment, I will thereto yield, desiring from the bottom of my heart that I may have assistance of His grace to be the minister of His heavenly will in this office now committed to me. And as I am but one body naturally considered, though by His permission
20574-422: The stability of the 4d orbitals), so that the chemistry of silver is predominantly that of the +1 oxidation state, reflecting the increasingly limited range of oxidation states along the transition series as the d-orbitals fill and stabilize. Unlike copper , for which the larger hydration energy of Cu as compared to Cu is the reason why the former is the more stable in aqueous solution and solids despite lacking
20736-445: The stable filled d-subshell of the latter, with silver this effect is swamped by its larger second ionisation energy. Hence, Ag is the stable species in aqueous solution and solids, with Ag being much less stable as it oxidizes water. Most silver compounds have significant covalent character due to the small size and high first ionization energy (730.8 kJ/mol) of silver. Furthermore, silver's Pauling electronegativity of 1.93
20898-553: The start did not really back this course of action. Her strategy, to support the Dutch on the surface with an English army, while beginning secret peace talks with Spain within days of Leicester's arrival in Holland, had necessarily to be at odds with Leicester's, who had set up a protectorate and was expected by the Dutch to fight an active campaign. Elizabeth, on the other hand, wanted him "to avoid at all costs any decisive action with
21060-512: The start of Elizabeth's reign it was expected that she would marry, and the question arose to whom. Although she received many offers, she never married and remained childless; the reasons for this are not clear. Historians have speculated that Thomas Seymour had put her off sexual relationships. She considered several suitors until she was about 50 years old. Her last courtship was with Francis, Duke of Anjou , 22 years her junior. While risking possible loss of power like her sister, who played into
21222-411: The story, containing an illustration of silver's metaphorical use of signifying the second-best in a series, better than bronze but worse than gold: But when good Saturn , banish'd from above, Was driv'n to Hell, the world was under Jove . Succeeding times a silver age behold, Excelling brass, but more excell'd by gold. In folklore, silver was commonly thought to have mystic powers: for example,
21384-547: The summer of 1585 by the Duke of Parma necessitated some reaction on the part of the English and the Dutch. The outcome was the Treaty of Nonsuch of August 1585, in which Elizabeth promised military support to the Dutch. The treaty marked the beginning of the Anglo-Spanish War , which lasted until the Treaty of London in 1604. The expedition was led by Elizabeth's former suitor, the Earl of Leicester. Elizabeth from
21546-539: The throne and set out to rule by good counsel. She depended heavily on a group of trusted advisers led by William Cecil , whom she created Baron Burghley . One of her first actions as queen was the establishment of an English Protestant church, of which she became the supreme governor . This era, later named the Elizabethan Religious Settlement , would evolve into the Church of England . It
21708-527: The throne. Mary was considered by many to be the heir to the English crown, being the granddaughter of Henry VIII's elder sister, Margaret . Mary boasted being "the nearest kinswoman she hath". Elizabeth was persuaded to send a force into Scotland to aid the Protestant rebels, and though the campaign was inept, the resulting Treaty of Edinburgh of July 1560 removed the French threat in the north. When Mary returned from France to Scotland in 1561 to take up
21870-586: The time, including the Archbishopric of Canterbury . This enabled supporters amongst peers to outvote the bishops and conservative peers. Nevertheless, Elizabeth was forced to accept the title of Supreme Governor of the Church of England rather than the more contentious title of Supreme Head , which many thought unacceptable for a woman to bear. The new Act of Supremacy became law on 8 May 1559. All public officials were forced to swear an oath of loyalty to
22032-458: The weakness of the Ag–C bond. A few are known at very low temperatures around 6–15 K, such as the green, planar paramagnetic Ag(CO) 3 , which dimerizes at 25–30 K, probably by forming Ag–Ag bonds. Additionally, the silver carbonyl [Ag(CO)] [B(OTeF 5 ) 4 ] is known. Polymeric AgLX complexes with alkenes and alkynes are known, but their bonds are thermodynamically weaker than even those of
22194-499: The world production of silver was around a meagre 50 tonnes per year. In the Americas, high temperature silver-lead cupellation technology was developed by pre-Inca civilizations as early as AD 60–120; silver deposits in India, China, Japan, and pre-Columbian America continued to be mined during this time. With the discovery of America and the plundering of silver by the Spanish conquistadors, Central and South America became
22356-407: Was video et taceo ("I see and keep silent"). In religion, she was relatively tolerant and avoided systematic persecution. After the pope declared her illegitimate in 1570, which in theory released English Catholics from allegiance to her, several conspiracies threatened her life, all of which were defeated with the help of her ministers' secret service, run by Sir Francis Walsingham . Elizabeth
22518-495: Was "as toward a child and as gentle of conditions as ever I knew any in my life". Catherine Champernowne , better known by her later, married name of Catherine "Kat" Ashley, was appointed as Elizabeth's governess in 1537, and she remained Elizabeth's friend until her death in 1565. Champernowne taught Elizabeth four languages: French, Dutch , Italian, and Spanish. By the time William Grindal became her tutor in 1544, Elizabeth could write English, Latin , and Italian. Under Grindal,
22680-653: Was Henry VIII's second wife, Anne Boleyn . At birth, Elizabeth was the heir presumptive to the English throne. Her elder half-sister Mary had lost her position as a legitimate heir when Henry annulled his marriage to Mary's mother, Catherine of Aragon , to marry Anne, with the intent to sire a male heir and ensure the Tudor succession. She was baptised on 10 September 1533, and her godparents were Thomas Cranmer , Archbishop of Canterbury ; Henry Courtenay, Marquess of Exeter ; Elizabeth Stafford, Duchess of Norfolk ; and Margaret Wotton, Dowager Marchioness of Dorset . A canopy
22842-405: Was already making plans for her government. Mary recognised Elizabeth as her heir on 6 November 1558, and Elizabeth became queen when Mary died on 17 November. Elizabeth became queen at the age of 25, and declared her intentions to her council and other peers who had come to Hatfield to swear allegiance. The speech contains the first record of her adoption of the medieval political theology of
23004-413: Was also aware of sheet silver, exemplifying the malleability and ductility of the metal: "Silver spread into plates is brought from Tarshish, and gold from Uphaz, the work of the workman, and of the hands of the founder: blue and purple is their clothing: they are all the work of cunning men." (Jeremiah 10:9) Silver also has more negative cultural meanings: the idiom thirty pieces of silver , referring to
23166-455: Was being sewn. Since then, however, they have gained many other uses. From the 16th century onwards silver thimbles were regarded as an ideal gift for ladies. Early Meissen porcelain and elaborate, decorated gold thimbles were also given as keepsakes and were usually quite unsuitable for sewing. This tradition has continued to the present day. In the early modern period, thimbles were used to measure spirits and gunpowder, which brought rise to
23328-430: Was carried at the ceremony over the infant by her uncle George Boleyn, Viscount Rochford ; John Hussey, Baron Hussey of Sleaford ; Lord Thomas Howard ; and William Howard, Baron Howard of Effingham . Elizabeth was two years and eight months old when her mother was beheaded on 19 May 1536, four months after Catherine of Aragon's death from natural causes. Elizabeth was declared illegitimate and deprived of her place in
23490-468: Was cautious in foreign affairs, manoeuvring between the major powers of France and Spain . She half-heartedly supported a number of ineffective, poorly resourced military campaigns in the Netherlands , France, and Ireland. By the mid-1580s, England could no longer avoid war with Spain . As she grew older, Elizabeth became celebrated for her virginity . A cult of personality grew around her which
23652-493: Was celebrated in the portraits, pageants, and literature of the day. Elizabeth's reign became known as the Elizabethan era . The period is famous for the flourishing of English drama , led by playwrights such as William Shakespeare and Christopher Marlowe , the prowess of English maritime adventurers, such as Francis Drake and Walter Raleigh , and for the defeat of the Spanish Armada . Some historians depict Elizabeth as
23814-471: Was deposed after nine days. On 3 August 1553, Mary rode triumphantly into London, with Elizabeth at her side. The show of solidarity between the sisters did not last long. Mary, a devout Catholic , was determined to crush the Protestant faith in which Elizabeth had been educated, and she ordered that everyone attend Catholic Mass; Elizabeth had to outwardly conform. Mary's initial popularity ebbed away in 1554 when she announced plans to marry Philip of Spain ,
23976-410: Was expected that Elizabeth would marry and produce an heir; however, despite numerous courtships, she never did. Because of this she is sometimes referred to as the "Virgin Queen". She was eventually succeeded by her first cousin twice removed, James VI of Scotland , the son of Mary, Queen of Scots . In government, Elizabeth was more moderate than her father and siblings had been. One of her mottoes
24138-655: Was fond of Seymour, sought to convince Elizabeth to take him as her husband. She tried to convince Elizabeth to write to Seymour and "comfort him in his sorrow", but Elizabeth claimed that Thomas was not so saddened by her stepmother's death as to need comfort. In January 1549, Seymour was arrested and imprisoned in the Tower on suspicion of conspiring to depose his brother Somerset as Protector, marry Lady Jane Grey to King Edward VI, and take Elizabeth as his own wife. Elizabeth, living at Hatfield House , would admit nothing. Her stubbornness exasperated her interrogator, Robert Tyrwhitt , who reported, "I do see it in her face that she
24300-468: Was made a treasonable offence, carrying the death penalty. From the 1570s missionary priests from continental seminaries went to England secretly in the cause of the "reconversion of England". Some were executed for treasonable conduct, engendering a cult of martyrdom . Regnans in Excelsis gave English Catholics a strong incentive to look to Mary as the legitimate sovereign of England. Mary may not have been told of every Catholic plot to put her on
24462-510: Was more often used ornamentally or as money. Since silver is more reactive than gold, supplies of native silver were much more limited than those of gold. For example, silver was more expensive than gold in Egypt until around the fifteenth century BC: the Egyptians are thought to have separated gold from silver by heating the metals with salt, and then reducing the silver chloride produced to
24624-431: Was mysteriously bedridden with an illness that caused her body to swell. In 1587, a young man calling himself Arthur Dudley was arrested on the coast of Spain under suspicion of being a spy. The man claimed to be the illegitimate son of Elizabeth and Robert Dudley, with his age being consistent with birth during the 1561 illness. He was taken to Madrid for investigation, where he was examined by Francis Englefield ,
24786-468: Was never heard from again. Modern scholarship dismisses the story's basic premise as "impossible", and asserts that Elizabeth's life was so closely observed by contemporaries that she could not have hidden a pregnancy. Elizabeth's first policy toward Scotland was to oppose the French presence there. She feared that the French planned to invade England and put her Catholic cousin Mary, Queen of Scots , on
24948-497: Was not universally accepted. Catholics accused Elizabeth of engaging in "filthy lust" that symbolically defiled the nation along with her body. Henry IV of France said that one of the great questions of Europe was "whether Queen Elizabeth was a maid or no". A central issue, when it comes to the question of Elizabeth's virginity, was whether the Queen ever consummated her love affair with Robert Dudley. In 1559, she had Dudley's bedchambers moved next to her own apartments. In 1561, she
25110-558: Was one of the eight traditional metal game pieces used to mark a player's position on the game board. However, this piece is being replaced in the new versions of the board game in August 2017 following public consultation. On December 3, 1979, a London dealer bid the sum of $ 18,000 USD for a dentil shaped Meissen porcelain thimble, circa 1740, at Christie's auction in Geneva, Switzerland. The thimble, just over 0.5 inches (13 mm) high,
25272-481: Was painted in a rare lemon-yellow color about the band. It also had tiny harbor scene hand painted within gold-trimmed cartouches. The rim was scalloped with fired gold on its bottom edge. The thimble now belongs to a Meissen collector in Canada. Elizabeth I Elizabeth I (7 September 1533 – 24 March 1603) was Queen of England and Ireland from 17 November 1558 until her death in 1603. She
25434-671: Was probably taught Cornish by William Killigrew , Groom of the Privy Chamber and later Chamberlain of the Exchequer . Henry VIII died in 1547 and Elizabeth's half-brother, Edward VI, became king at the age of nine. Catherine Parr, Henry's widow, soon married Thomas Seymour, Baron Seymour of Sudeley , Edward VI's uncle and the brother of Lord Protector Edward Seymour, Duke of Somerset . The couple took Elizabeth into their household at Chelsea . There Elizabeth experienced an emotional crisis that some historians believe affected her for
25596-400: Was taken to Stirling Castle to be raised as a Protestant. Mary escaped in 1568 but after a defeat at Langside sailed to England, where she had once been assured of support from Elizabeth. Elizabeth's first instinct was to restore her fellow monarch, but she and her council instead chose to play safe. Rather than risk returning Mary to Scotland with an English army or sending her to France and
25758-546: Was that her emissary read out her letters of disapproval publicly before the Dutch Council of State, Leicester having to stand nearby. This public humiliation of her "Lieutenant-General" combined with her continued talks for a separate peace with Spain irreversibly undermined Leicester's standing among the Dutch. The military campaign was severely hampered by Elizabeth's repeated refusals to send promised funds for her starving soldiers. Her unwillingness to commit herself to
25920-567: Was the last monarch of the House of Tudor . Elizabeth was the only surviving child of Henry VIII and his second wife, Anne Boleyn . When Elizabeth was two years old, her parents' marriage was annulled, her mother was executed, and Elizabeth was declared illegitimate . Henry restored her to the line of succession when she was 10, via the Third Succession Act 1543 . After Henry's death in 1547, Elizabeth's younger half-brother Edward VI ruled until his own death in 1553, bequeathing
26082-457: Was the usual Proto-Indo-European word for the metal, whose reflexes are missing in Germanic and Balto-Slavic. Silver was known in prehistoric times: the three metals of group 11, copper, silver, and gold, occur in the elemental form in nature and were probably used as the first primitive forms of money as opposed to simple bartering. Unlike copper, silver did not lead to the growth of metallurgy , on account of its low structural strength; it
26244-509: Was tied to a planned alliance against Spanish control of the Southern Netherlands . Elizabeth seems to have taken the courtship seriously for a time, wearing a frog-shaped earring that Francis had sent her. In 1563, Elizabeth told an imperial envoy: "If I follow the inclination of my nature, it is this: beggar-woman and single, far rather than queen and married". Later in the year, following Elizabeth's illness with smallpox ,
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